Financial support from the National Natural Science Foundation of China(21877043,21702068,22025102);Wuhan Creative Talent Development Fund,and Fundamental Research Funds for the Central Universities(2017KFYXJJ150)is greatly appreciated;We also thank Analytical and Testing Center of HUST for NMR tests.
Based on the redox reactions of Togni-Ⅱreagent and thiols,a thiol-tuned selective functionalization of unactivated olefins was disclosed.In combination with aryl thiols,stoichiometric amount of Togni-Ⅱreagent prompt...
The hydrothiolations of alkynes/alkenes with thiols is an atom-economic and thus attractive method for the constructions of C‒S bonds.Here Ir_(2)S_(3)/ZnIn_(2)S_(4)nanocomposites with varied Ir_(2)S_(3)loadings were o...
Natural Science Foundation of Hunan(No.2009NK3162);National Natural Science Foundation of China(No.21003040,20372020) for financial support
In the presence of catalytic amount of cesium hydroxide the hydrothiolation of alkynyl selenides occurred at room temperature in DMF under nitrogen atmosphere to give exclusive(Z)-1-organoseleno-2-arylthio-1-alkene ...
Project supported by the National Natural Science Foundation of China (Nos. 21071152, 20372020).
In the presence of catalytic amount of cesium hydroxide, the hydrothiolation of alkynyl sulfides occurred at room temperature in DMF under nitrogen atmosphere to afford exclusive (Z)-1,2-diorganothio-1-alkene in exc...