supported by the National Natural Science Foundation of China(No.92372123);Guangdong Basic and Applied Basic Research Foundation(No.2022A1515012057,2022B1515020005,2023B1515130004);Guangzhou Basic and Applied Basic Research Foundation(No.202201011342).
Porous organic cages(POCs)with permanent porosity and excellent host–guest property hold great potentials in regulating ion transport behavior,yet their feasibility as solid-state electrolytes has never been testifie...