π-Facial stereoselectivety in Diels-alder reactions and their synthetic applications have attracted considerable attention in recent years. In the Diels-Alder reaction of the cyclopentadiene-quinone cycloadduct 1 wit...
Supported by the National Natural Science Foundation of China ; Youth Foundation of Tianjin
The present paper narrates the addition of 5-trimethylsilylcyclohex-3-enone to Grig-nard reagent to give 1-substituted 5-trimethylsilylcyclohex-3-enol in a good yield. The stereochemistry of the addition reaction and ...