financially supported by National Key R&D Program of China(2016YFB0700600);Soft Science Research Project of Guangdong Province(2017B030301013);Shenzhen Science and Technology Research Grant(ZDSYS201707281026184).
An octahedral Nb6 structural unit with space aromaticity is identified for the first time in a transition–metal monoxide crystal Nb3O3 by ab initio calculations.The strong Nb–Nb metallic bonding facilitates the form...
supported by the National Basic Research Program of China(2011CBA00508 and 2015CB932301);the National Natural Science Foundation of China(21131005,21333008,and J1310024);the Natural Science Foundation of Fujian Province of China(2014J01058)
In this paper, we reported a solvothermal method for the synthesis of octahedral Pt-Cu bimetallic alloy nanocrystals (NCs) with tunable composition. Inspired by the result from our previous exploration on octahedral...
This work was supported by the National Key Basic Research Program(Grant No.2001CCA02400);the National Natural Science Foundation of China(Grant No.49972017).
The Xiangtan manganese deposit (XTM) used to be considered a supergene oxide manganese ore in South China. We reported a new identification of the naturally outcropping cryptomelane by examining the physical, chemical...
Recently, in the investigation on the oxidation zone of Yinnan Gold Deposit in Ningxia, we found a large amount of tiny gold spheroids, which are rare in the world and have not been reportedly discovered in China. Gol...
Rock strength is a basic problem of rock mechanics and the theory of rock strength is a portion of the constitutive law for intact rocks and is important in the investigation of rock mechanics. Many criterions have be...
Ⅰ. INTRODUCTION The M(?)ssbauer effect has been widely used to study minerals since 1965. Over 300 minerals containing irons have been measured by using the M(?)ssbauer effect. In general, it is assumed that Fe2+...
Ⅰ. INTRODUCTION The M?ssbauer spectra (MS) of a Ca2+, In2+ and Ge4+ substituted yttrium iron garnet (YIG)-Y2.78Ca0.25In0.60Ge0.25Fe4.11O12(Y—Ca—In—GeIG) cannot be resolved simply into two sets of octahedral...
The Mo(Ⅲ) ion has a 4d3 electronic configuration, a nd the expected octahedral 6 coordination has been confirmed by some X-ray structural studies such as K3Mo (NCS)6. H2O·CH3COOH, MoCl3(py)3 and MoCl3(tu)3, ...
A series of thiourea complexes of molybdenum have been prepared by one of which is the rather stable MoCl3(Tu)3. On the basis of magnetic measurements, has proposed that in the complex the molybdenum (Ⅲ) atom has...