supported by the National Basic Research Program of China (2007CB815306);the National Natural Science Foundation of China (20771105, 20871122);the Key Project of Ministry of Education (108103);the Natural Science Foundation of Guangdong Province (9351027501000003)
Three Ru(Ⅱ) complexes [Ru(bpy)2(1-IQTNH)](ClO4)2 (1), [Ru(bpy)2(2-QTNH)](ClO4)2 (2) and [Ru(bpy)2(3-IQTNH)](ClO4)2 (3) (bpy = 2,2′-bipyridine, 1-IQTNH = 6-(isoquinolin-1-yl)-1,3,5-triazine-2,4-diamine, 2-QTNH = 6-(q...
supported by 973 Program (2006CB932900);the National Natural Science Foundation of China (20571074)
The reaction of 2,4,6-tris(2-pyridyl)-1,3,5-triazine (tptz) and K2PdCl4 in THF/H2O (10:1) results in the hydrolysis of tptz to bis(2-pyridylcarbonyl)amide anion (bpca), and affords complex Pd(bpca)Cl 1, w...