Supported by the National Natural Science Foundation of China(No50973100)
Dodecyl-benzophenone(DBP) and hexadecoxyl-benzophenone(HDBP) as type 11 photoinitiators used for radical photopolymerization systems were synthesized by Friedel-Crafts reaction, and characterized by 1H NMR and FTI...
Supported by the National Natural Science Foundation of China(No. 2 0 0 74 0 34)
The radiative curable dendritic acrylated aromatic/aliphatic polyesters based on pentaerythritol, 1,2,4 benzenetricaboxylic anhydride and epoxy propane modified with acryloyl chloride were synthesized via a diver...
A novel acrylic monomer bearing aromatic ethereality group N-(p -phenoxy-phenyl) methacrylamide(MAPOA) was synthesized and polymerized. The fluorescence spectra of MAPOA and its polymer were studied, showing that the ...
Supported by the National Natural Science Foundation of China
Toluidine blue(TB) is a good sensitizer for the polymerization of acrylnmide(AM) induced by He-Ne laser. With TB as a sensitizer and various alcoholamine as donors, the photoredox of TB and the polymerization kinetics...
Supported by the National Natural Science Foundation of China
Two iron-arene complex photoinitiators with different substituents in arene ligands were synthesized, their activities in initiating photopolymerization of cyclohexene oxide (CHO) were compared with that of IRGACURE 2...
Among sensitizing systems, the combination of benzophenone(BP) and tertiary amines(TA) has been deeply studied. Since the structure of O-acyl-oximes is similar to that of BP and their triplet state energies are nearly...