The authors greatly acknowledge the financial support from the China Postdoctoral Science Foundation(Nos.2019M661247 and 2020T130091);Postdoctoral Science Foundation of Heilongjiang Province(LBH-Z19047);Scientific Research Foundation for Returned Scholars of Heilongjiang Province of China(719900091);Key Laboratory of Functional Inorganic Material Chemistry(Heilongjiang University),Ministry of Education.
Chemoselective hydrodeoxygenation of vanillin is of great importance in converting biomass into high value-added chemicals.Herein,we describe a facile photochemical route to access palladium single atoms and clusters ...