Supporting information for this article is available on the WWW under http://dx.doi.org/10.1002/cjoc.201280027 or from the author. Acknowledgment We gratefully acknowledge the financial support from the National Natural Science Foundation of China (No. 10776002) and China Academy of Engineering Physics (No. 20911120033), the project of State Key Laboratory of Science and Technology (Nos. QNKT11-06, YBKT10-03), and the Program for New Centu17 Excellent Talents in University (No. NCET-09-005I). Our thanks are due to Professor Gustavo E. Scuseria for providing the development version of Gaussian program.
The geometric conformation and electronic structure of bis-(5-nitro-2H-tetrazolato-N2)tetraammine cobalt(Ⅲ) perchlorate and its Ni/Fe/Cu/Zn analogues are studied under the TPSS (Tao-Perdew-Staroverov-Scuseria) ...
Project supported by the National Natural Science Foundation of China (No. 20673050).
A coordination compound of erbium perchlorate with L-α-glutamic acid, [Er2(Glu)2(H2O)6](ClO4)4·6H2O(s), was synthesized. By chemical analysis, elemental analysis, FTIR, TG/DTG, and comparison with relevant l...
Project supported by the National Natural Science Foundation of China (No. 20471008).
The Temperature-jump/FTIR (T-jump/FTIR) spectroscopy was introduced to resolve the decomposition kinetics parameters of [Cd(CHZ)3](ClO4)2 (CdCP) at high temperature following very rapid heating process. The in...
The heat capacities of the two complexes, [La 2(Gly) 6(H 2O) 4]^(ClO 4) 6 and [Ho 2(Gly) 6(H 2O) 4](ClO 4) 6·2H 2O (Gly=glycine), were measured by adiabatic calorimetry in the temperature range from 78 t...
Based on the phase equilibrium study of the system Sm(ClO4)3-4-monochloroace-tylantipyrine (C13H13ClN2O2)-H2O at 30℃, we have synthesized the title complex [Sm(C13H13Cl. N2O2)3(H2O)4](C1O4)3.4H2O. The single crystal...