The exact short time propagator, in a form similar to the Crank-Nicholson method but in the spirit of spectrally transformed Hamiltonian, was proposed to solve the triatomic reactive time-dependent schrodinger equatio...
This work was supported by the National Basic Research Program of China (No.2013CB922200), the National Natural Science Foundation of China (No.21222308, No.21103187, and No.21133006), the Chinese Academy of Sciences, and the Key Research Program of the Chinese Academy of Sciences.
In quantum calculations a transformed Hamiltonian is often used to avoid singularities in a certain basis set or to reduce computation time. We demonstrate for the Fourier basis set that the Hamiltonian can not be arb...