AZAARENES

作品数:10被引量:1H指数:1
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相关期刊:《Chinese Journal of Catalysis》《Chinese Journal of Chemistry》《Organic Chemistry Frontiers》《Science China Chemistry》更多>>
相关基金:国家自然科学基金中国博士后科学基金河南省科技攻关计划更多>>
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Ligand-controlled NiH-catalyzed regiodivergent hydroalkylation of 2-alkenylazaarenes被引量:1
《Science China Chemistry》2024年第6期1935-1940,共6页Ya-Ping Shao Zhuo-Min Chi Yong-Min Liang 
supported by the Dalian Institute of Chemical Physics,the Chinese Academy of Sciences;the National Natural Science Foundation of China(21472186,21272231)。
A nickel-hydride(Ni H)-catalyzed migratory and nonmigratory hydroalkylation reaction of 2-alkenyl azaarenes with alkyl iodines has been established through strategic modulation of N-or P-donor ligands.This method enab...
关键词:NIH regiodivergent HYDROALKYLATION AZAARENES interrupted chain-walking 
Direct enantioselective reduction of C=C bond of β-polyfluoro-alkylated enones via asymmetric photoredox catalysis
《Science China Chemistry》2024年第6期2016-2021,共6页Linghong Zhang Jin Ma Xu Ban Xiaowei Zhao Yanli Yin Zhiyong Jiang 
supported by the National Natural Science Foundation of China(22171072,21925103,22301061);Henan Normal University。
Direct enantioselective reduction of the C=C bond ofβ-polyfluoro-alkylated enones is an important but long-pending subject in asymmetric catalysis.Here,we report on the viability of visible light-driven cooperative p...
关键词:photoredox catalysis Br?nsted acids asymmetric reduction enantioselective protonation AZAARENES 
Divergent asymmetric synthesis of azaarene-functionalized cyclic alcohols through stereocontrolled Beckwith-Enholm cyclizations
《Science China Chemistry》2021年第9期1522-1529,共8页Zhanghong Guo Xiaowei Chen Hao Fang Xiaowei Zhao Zhiyong Jiang 
supported by the National Natural Science Foundation of China(21925103,21901062);Key Technologies R&D Program of Henan(202102310005);Henan Normal University;Henan University。
The first enantioselective Beckwith-Enholm cyclization reaction is reported herein.Under cooperative photoredox and chiral hydrogen-bonding catalysis mediated by visible light,cyclization of carbonyls with azaarene-ba...
关键词:photoredox catalysis asymmetric catalysis Beckwith-Enholm cyclizations AZAARENES antioxidant stress 
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