supported by the Dalian Institute of Chemical Physics,the Chinese Academy of Sciences;the National Natural Science Foundation of China(21472186,21272231)。
A nickel-hydride(Ni H)-catalyzed migratory and nonmigratory hydroalkylation reaction of 2-alkenyl azaarenes with alkyl iodines has been established through strategic modulation of N-or P-donor ligands.This method enab...
supported by the National Natural Science Foundation of China(22171072,21925103,22301061);Henan Normal University。
Direct enantioselective reduction of the C=C bond ofβ-polyfluoro-alkylated enones is an important but long-pending subject in asymmetric catalysis.Here,we report on the viability of visible light-driven cooperative p...
supported by the National Natural Science Foundation of China(21925103,21901062);Key Technologies R&D Program of Henan(202102310005);Henan Normal University;Henan University。
The first enantioselective Beckwith-Enholm cyclization reaction is reported herein.Under cooperative photoredox and chiral hydrogen-bonding catalysis mediated by visible light,cyclization of carbonyls with azaarene-ba...