BIRADICAL

作品数:13被引量:6H指数:2
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相关领域:理学更多>>
相关作者:王立敏储德清苏鹏更多>>
相关机构:天津工业大学更多>>
相关期刊:《Science China Chemistry》《Organic Chemistry Frontiers》《Chemical Research in Chinese Universities》《Chinese Journal of Chemistry》更多>>
相关基金:国家自然科学基金国家重点基础研究发展计划更多>>
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On the oxidation states of metal elements in MO-3(M=V,Nb,Ta,Db,Pr,Gd,Pa)anions被引量:3
《Science China Chemistry》2016年第4期442-451,共10页Jing Su Shuxian Hu Wei Huang Mingfei Zhou Jun Li 
supported by the National Basic Research Program of China(2013CB834603);the National Natural Science Foundation of China(21173053,21433005,91426302,21221062,21201106)
Relativistic quantum chemistry investigations are carried out to tackle the puzzling oxidation state problem in a series of MO3 trioxide anions of all d- and f-block elements with five valence electrons. We have shown...
关键词:oxidation state non-innocent ligand BIRADICAL LANTHANIDE trioxide anion 
Effect of configuration and conformation on the spin multiplicity in xylylene type biradicals被引量:2
《Science China Chemistry》2000年第5期524-530,共7页张景萍 张宏 王立敏 王荣顺 王利祥 
The singlet-triplet splitting energy gap ΔEs-T= Es - ET is calculated for the ortho-, meta-, and para-xylylenes and their heteroatomic analogous by means of AM1-CI approach. It is shownthat when the radical centers R...
关键词:high-spin molecule BIRADICAL xylylene AM1-CI twisted conformation 
Synthesis, structure, magnetic properties and molecular mechanics study on the dinuclear copper (II) with biradical被引量:1
《Science China Chemistry》2000年第1期105-112,共8页孙柏旺 赵琦华 廖代正 姜宗慧 阎世平 王耕霖 姚心侃 王宏根 王磊光 陈海建 
Dinuclear copper complex with biradicals [Cu(hfac)2]2PhBNM(PhBNM = 2,5-bimethyl-1,4-bis(4,4,5,5-tetramethyllimidazoline-1-oxyl-3-oxide)phenyl,hfac=hexafluoroacetylacetonate) has been synthesized and characterized. It ...
关键词:BIRADICAL crystal STRUCTURE MAGNETISM molecular mechanics. 
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