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This work was supported by the National Natural Science Foundation of China(NSFC)(Nos.2089012,20721063,20821140537,20871030);State Key Basic Research Program of PRC(Nos.2006CB932302 and 2009AA033701);Shanghai Leading Academic Discipline Project(No.B108);Science&Technology Com-mission of Shanghai Municipality(No.08DZ2270500);C.S.Ha also thanks the National Research Foundation(NRF)of Korea for support through the Korea-China Joint Research Center Program on Mesoporous Thin Films(No.K20803001459-10B1200-00310);the Acceleration Research Program(No.2010-0000790).
Porous carbon nitride(CN)spheres with partially crystalline frameworks have been successfully synthesized via a nanocasting approach by using spherical mesoporous cellular silica foams(MCFs)as a hard template,and ethy...