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Hydrothermal Synthesis and Crystal Structure of a One-dimensional Coordination Polymer Constructed from Bicapped Pseudo-Keggin Cluster:(Et_3N)_(0.5)(en)_2[SiMo_(12)O_(40)(VO)_2]·4H_2O
《Chinese Journal of Structural Chemistry》2010年第1期151-156,共6页党东宾 高慧  金亚南 孙继德 牛景杨 
supported by the National Natural Science Foundation of China (No 20701012);the Key Project of Chinese Ministry of Education (No 207068);the Foundation of Henan Educational Committee of China (No 2007150003 and 2008B150002);the Foundation for University Youth Key Teacher of Henan Province
A new pseudo Keggin-type bicapped compound(Et3N)0.5(en)2[SiMo12O40(VO)2]·4H2O(Et3N=triethylamine,en=ethylenediamine) has been hydrothermally synthesized and characterized by IR,elemental analysis,TG and X-ray...
关键词:pseudo Keggin-type POLYOXOMETALATES hydrothermai synthesis crystal structure 
Synthesis and Structure of a POMs-based 3D Zeolike Ionic Crystal,{[Co(dpdo)_2(H_2O)_2(CH_3CN)]_2(SiMo_(12)O_(40))(H_2O)_2}_n
《Chinese Journal of Structural Chemistry》2009年第8期971-977,共7页魏梅林 段春迎 
supported by the Natural Science Foundation of Henan Province
A POMs-based 3D zeolike ionic crystal 1, {[Co(dpdo)2(CH3CN)(H2O)2]2(SiMo12O40)- (HEO)2}n (dpdo = 4,4'-bipyridine-N,N'-dioxide), was constructed via self-assembly by embedding Keggintype [SiMo12O40]^4- po...
关键词:ionic crystal crystal structure metal-organic framework POLYOXOMETALATE 
十一钼硅钴杂多蓝H_8[SiMo_(11)Co(H_2O)O_(39)]·20H_2O的合成与晶体结构
《Chinese Journal of Structural Chemistry》1998年第3期225-229,共5页刘杰 彭军 周云山 王恩波 邢彦 林永华 贾恒庆 
国家自然科学基金
采用电解法制备了未见文献报道的杂多蓝H8[SiMo11Co(H2O)O39]·20H2O,通过X-射线衍射测定了其晶体结构,该晶体属单斜晶系,空间群P21;。晶胞参数全矩阵最小二乘法修正至中心原子Si与4个氧形成四面体结构,配原子M(M=11/12Mo+1...
关键词:杂多蓝 合成 晶体结构 十一钼硅钴 
Synthesis and Structure of K_6H_7〔Dy(SiMo_6W_5O_(39))_2〕·10H_2O
《Chinese Journal of Structural Chemistry》1997年第3期233-238,共6页WANG Xiao-Guang(Department of Chemistry, Harbin Normal University, harbin, 150080)SHAN Yong-Kui CHU Wen-Ling  WU Yue XING Yan LIN Yong-Hua BAI Shi-Ying(Changchun Institute of Applied Chemistry, the Chinese Academy ofSciences, Changchun, 130022) 
K6H7 [Dy(SiMo6W5O39)2] 10H2O, Mr= 4878. 5, is triclinic, sapcegroup P1 with a= 22. 697(5) A; b= 12. 835(4) A; c= 18. 216(6) A; a= 90. 56(2); β= 98. 24(2); γ= 90. 51 (2)°;V= 5251 (2) A3; Z= 2, Dc= 3.08 g/cm3; F(00...
关键词:SYNTHESIS LANTHANIDE crystal structure heteropoly compound 
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