Project supported by the National Natural Science Foundation of China (21805048,22005069);the Natural Science Foundation of Guangdong Province (2022A1515011145,2023A1515010602);the Science and Technology Research Project of Guangzhou (202102080023,202201020166);the Project for Key Areas of Ordinary Colleges and Universities of Guangdong Province(2022ZDZX4035);the "Climbing Program" Special Funds of Guangdong Province (pdjh 2023b0389)。
By using a rigid bulky carboxylic ligand a-cyanocinnamic acid(CCA),a dinuclear dysprosium(Ⅲ) complex [Dy_(2)(CCA)_(6)(MeOH)_(4)](1) was synthesized.Single crystal X-ray crystallography reveals that the two eight-coor...
Project supported by the National Natural Science Foundation of China(22131011,22071274,21821003);the Pearl River Talent Plan of Guangdong(2017BT01C161)。
On account of the complicated magnetic exchange interactions between lanthanide ions,binuclear lanthanide complexes have broad application prospect in the field of single-molecule magnets.Therefore,it is necessary to ...
Project supported by the National Natural Science Foundation of China(21671029);Innovation andEntrepreneurship Team of Inorganic Optoelectronic Functional Materials for Chongqing Yingcai(cstc2021ycjh-bgzxm0131);MajorProject of the Science and Technology Research Program of Chongqing Education Commission of China(KJZD-M202100501);theInnovation Program for Chongqing’s Overseas Returnees(cx2019037);Natural Science Foundation of Chongqing,China(cstc2021jcyj-msxmX0380);Chongqing Normal University(21XLB034)。
Lanthanide complex-based materials with magnetic and luminescent properties have received a great deal of attention,owing to their importantly potential applications in diverse fields.In this work,the 9-anthracenecarb...
Project supported by the National Natural Science Foundation of China (21901200);the Natural Science Foundation of Shaanxi Province(2019JQ-489,2019JZ-44);the Scientific Research Program of Shaanxi Provincial Education Department (18JK0607);the Young Talent Fund of Xi’an Association for Science and Technology (095920201319);the 111 project (B12015);the Postgraduate Innovation and Practice Training Program of Xi’an Shiyou University(YCS202121001)。
Dysprosium complexes based on [F-Dy] or near-linear [F-Dy-F] unit are of great concern in the field of single-molecule magnets due to their large magnetic anisotropy.Here,the crystal structure and the magnetic relaxat...
Project supported by the National Natural Science Foundation of China(91963123);the State Key Laboratory of Solidification Processing in NWPU(SKLSP202020);the Ten Thousand Talents Plan of Zhejiang Province of China(2018R52003);the Fundamental Research Funds for the Provincial University of Zhejiang(GK199900299012-022)。
Three binuclear rare earth based complexes combining RE ions with semirigid tricarboxylic ligand(H_(3)L).namely,[RE_(2)(L)_(2)(DMF)_(4)][RE=Gd,Tb,and Dy;H_(3)L=5-((4-Carboxybenzyl)oxy)isophthalic acid;DMF=N,N-dimethyl...
Project supported by the National Natural Science Foundation of China (21372112,21701039);the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi (201802099)。
Two isostructural tetranuclear lanthanide clusters named [Ln_(4)(L)_(4)(CH_(3) O)_(4)]·CH_(3) OH(Ln=Gd(Ⅲ) for 1,Dy(Ⅲ) for 2,H_(2) L=N’-(2-hydroxy-3-methoxybenzylidene)-6-(hydroxymethyl) picolinohydrazide) were suc...