financially supported by the National Natural Science Foundation of China(11174215);Natural Science Foundation of Shandong Province(ZR2012BL10);the University Science and Technology Project of Shandong Province(No.J13LD05)
The reaction mechanisms of Ti(~3F) + CH2C12→CH2=TiCl2 and Ti(~3F) + CHC13→HC÷TiCl3 were investigated with Gaussian 03 program package at the B3PW91/6-311++G(d,p)level.The computational results revealed t...
Supported by Sichuan Application Basic Foundation (2009JY0075)
The title complex L3Y(L = [O-4,6-di-tBu-C6H2-2-CH{CH(iPr2NCHCHN) }]) has been synthesized by the reaction of LiY[N(iPr) 2]4 with H2LCl and LiBu in a 1:3:2 molar ratio at 0 ℃ in THF,and characterized by single...
The structures and spectra of 20 possible isomers of C78(CH2)3 have been studied by using AMI, INDO/CIS and DFT methods. The results show that the most stable isomer is 1,2,3,4,5,6-C78(CH2)3 (A) with annulene st...