Supported by the Natural Science Foundation of Tianjin (No.16JCYBJC19700);the National Natural Science Foundation of China (No.21771138)。
A new Cu(Ⅱ) complex,[Cu_(4)Cl_(6)O(1-TrTz)_(4)]where 1-TrTz is 1-trityl-1H-[1,2,4]triazole,was synthesized by the reaction of 1-trityl-1H-[1,2,4]triazole with two hydrated cupric chlorides,and its structure was chara...
Supported by the team of syngas catalytic conversion of Shaanxi University of Technology,the National Natural Science Foundation of China(No.21373132,21603133);Key scientific research project of education department of Shaanxi province(18JS023);Shaanxi provincial science and technology department project(2018JM2043,2019JQ149,2019JM471);the Science Foundation of Shaanxi University of Technology(No.SLGQD2017-14)。
A new Cu(II) coordination polymer, {[Cu(1,3-BIP)(TFBDC)]·DMF}n(1,1,3-BIP is a 1,3-bis(imidazole)propane, and H2TFBDC is 2,3,5,6-tetrafluoroterephthalic acid) was prepared under solvothermal conditions and characteriz...
Supported by the National Natural Science Foundation of China(No.21171040);National Undergraduates Innovation Project(201510371010)
A new complex, [Cu(HL)(phen)(H2O)]·4H2O(1, H3L·HCl = 5-((4-carboxypiperidin-1-yl)methyl)isophthalic acid hydrochloride, phen = 1,10-phenanthroline), has been hydrothermally prepared and characterized by ...
Supported by NNSFC(No.21171129 and 21173157);the Program for Innovative Research Team in University of Tianjin(TD12-5038);the National Training Programs of Innovation and Entrepreneurship for Undergraduates(201410065025)
Two 4,5-dichlorophthalate-based metal complexes, {[Cu(bipy)(dcpa)].H2O}n, (1) and {[Cu2Coipy)2(Hdcpa)3]·H2O·C2H5OH.Hdcpa} (2, H2dcpa = 4,5-dichlorophthalic acid and bipy = 2,2'-bipyridine), were synthesi...
supported by the K.C.Wong Magna Fund in Ningbo University
The complexes of [Cu(bpy)(H2O)(CBA)2]n 1 and [Cu(phen)(H2O)(CBA)2]·H2O 2 based on p-cyanobenzoic acid (HCBA) have been synthesized in aqueous ethanolic solution at room temperature. The single-crystal X...
Supported by Chongqing Postdoctoral Science Foundation (No. XM2012002)
An organic ligand and its Cu(II) complex formulated as (C13HloN203)·5H2O (H2L·5H2O, 1) and Cu(HL)2(phen)·0.125H2O (2, H2L = 4-carboxyl-4′-hydroxy azobenzene, phen = 1,10-phenanthroline) have been synth...
supported by the Natural Science Foundation of Guangxi Province (No. 0640207)
A Cu(II) complex of tetra(3,5-diphenyl pyrazole) [Cu(C15H12N2)2Cl2]2 (1) was synthesized, and its structure was determined by single-crystal X-ray diffraction and further characterized by elemental analysis, N...
Supported by the National Natural Science Foundation of China (No. 10947162);the Natural Science Foundation of Henan Province (No. 2010A140009);the International Technology Cooperation Project of Science and Technology Department of Henan Province (No. 104300510044)
The title compound [Cu(bbpy)(H2bptc)]n (bbpy = 4,4'-dimethyl-2,2'-bipyridine and H4bptc = 1,1'-biphenyl-2,2?,3,3'-tetracarboxylic acid) has been synthesized by hydrothermal reaction, and its structure was d...
supported by the Natural Science Foundation of the Educational Commission of Hubei Province (No. Q20082202)
A new copper(II) complex 3, Cu(C17H13F3O3)2·C5H5N, has been synthesized and characterized by single-crystal X-ray diffraction. It crystallizes in monoclinic, space group C2/c with a = 17.8511(7), b = 17.4136(7...
the State Key Basic Research and Development Plan of China (001CB108906);the Knowledge Innovation Program of the Chinese Academy of Sciences, the NSF (E0620005);the Major Special Foundation of Fujian Province (2005HZ1027, 2005HZ01-1);the Natural Science Foundation of Fujian Province (2006F3042)
A new mellitate complex [Cu3(μ2-mellitate)(μ2-H2O)(H2O)2·H2O]n 1 has been synthesized by the reaction of mellitic acid and Cu(CH3COO)2·H2O in the presence of base. Crystallographic data for 1: C12H8O16Cu3...