DEHYDROGENATION

作品数:258被引量:471H指数:9
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相关领域:理学更多>>
相关作者:杨新征李伟作郭新闻王小丽魏晓伟更多>>
相关机构:中国科学院中航工业北京航空制造工程研究所西华大学大连理工大学更多>>
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相关基金:国家自然科学基金中国博士后科学基金国家重点基础研究发展计划天津市自然科学基金更多>>
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Hollow structured Fe@C nanorods for boosting dehydrogenation properties of α-AlH_(3)
《Nano Research》2024年第9期8184-8191,共8页Yuan Zhao Qingshuang Wang Dongming Yin Xiaoli Wang Shouliang Li Chunli Wang Long Liang Shaolei Zhao Limin Wang Yong Cheng 
supported by the Key R&D projects of Jilin Provincial Science and Technology Development Plan(Nos.20230201140GX and 20230201125GX);the National Key Research and Development Program of China(No.2021YFB4000604);the Youth Innovation Promotion Association CAS(No.2022225);the Youth Growth science and technology Plan project of Jilin Province Science and Technology Development Plan(No.20220508001RC);the Independent Research Project of the State Key Laboratory of Rare Earth Resources Utilization(No.110000RL86);the Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,the National Natural Science Foundation of China(No.22103010);the Natural Science Foundation of Shandong Province(No.ZR2021QB104).
α-AlH_(3)is regarded as one of the most promising hydrogen storage materials due to its high hydrogen storage capacity(10.1 wt.%,148 kg·m^(-3)).However,in practical applications,the associated hydrogen release tempe...
关键词:Fe@C α-AlH_(3) DEHYDROGENATION CATALYST 
Catalytic effects of V-and O-species derived from PrF_(3)/V_(2)C for efficient hydrogen storage in MgH_(2)被引量:1
《Nano Research》2024年第8期7117-7125,共9页Zhenluo Yuan Yuhang Wang Xiuxiu Zhang Shuyan Guan Xiaojiao Wang Liqiang Ji Qiuming Peng Shumin Han Yanping Fan Baozhong Liu 
supported by the National Natural Science Foundation of China(Nos.U22A20120,52071135,51871090,and U1804135);the Natural Science Foundation of Hebei Province for Innovation Groups Program(No.C2022203003);Fundamental Research Funds for the Universities of Henan Province(No.NSFRF220201).
Magnesium hydride(MgH_(2))is considered as an ideal hydrogen storage material with excellent hydrogen capacity,but the slow kinetics impedes its application.Herein,an efficient additive of V2C MXene-anchored PrF_(3) n...
关键词:hydrogen storage materials MgH_(2) DEHYDROGENATION REVERSIBILITY cyclic stability 
Two-dimensional atomically thin Pt layers on MXenes: The role of electronic effects during catalytic dehydrogenation of ethane and propane被引量:1
《Nano Research》2024年第3期1251-1258,共8页Zhe Li Tobias K.Misicko Fan Yang Xiaopeng Liu Zhenwei Wu Xiaoyang Gao Tao Ma Jeffrey T.Miller Daniela S.Mainardi Collin D.Wick Zhenhua Zeng Yang Xiao Yue Wu 
support from Iowa State University(Herbert L.Stiles Professorship).Y.X.and T.K.M.appreciate the start-up funding from the College of Engineering and Science at Louisiana Tech University.Z.W.W.and J.T.M.were supported by the National Science Foundation under Cooperative Agreement(NSF/ERC CISTAR,No.EEC-164772);Use of the Advanced Photon Source,a US Department of Energy Office of Basic Energy Sciences,was supported under contract no.DE-AC02-06CH11357.
Atomically thin Pt nanolayers were synthesized on the surface of Mo2TiC2 MXenes and used for the catalytic dehydrogenation of ethane and propane into ethylene and propylene,two important chemicals for the petrochemica...
关键词:MXene CATALYSIS ALKANE DEHYDROGENATION NANOLAYERS 
Core-shell Cu@SiO_(2)/SiO_(2) catalyst for 1,6-hexanediol dehydrogenation toε-caprolactone:High activity and stability from core-shell nanostructure被引量:1
《Nano Research》2023年第10期12270-12280,共11页Fengyang Jiang Tian Lan Jiaqiang Sun Guofeng Zhao Yong Lu 
the National Natural Science Foundation of China(Nos.22179038,22272053,22072043,21773069,and 21703069);the Special Project for Peak Carbon Dioxide Emissions-Carbon Neutrality(No.21DZ1206700)from the Shanghai Municipal Science;Technology Commission,and the Key Basic Research Project(No.18JC1412100)from the Shanghai Municipal Science and Technology Commission.
The gas-phase dehydrogenation of 1,6-hexanediol(1,6-HDO)toε-caprolactone(ε-CL)over the high-performance Cu-based catalysts is highly desirable,but with grand challenges,because the Cu nanoparticles(NPs)are easy to b...
关键词:core–shell nanostructure Cu-based catalyst 1 6-hexanediol DEHYDROGENATION Ε-CAPROLACTONE 
Heterojunction synergistic catalysis of MXene-supported PrF_(3)nanosheets for the efficient hydrogen storage of AlH_(3)被引量:2
《Nano Research》2023年第7期9546-9552,共7页Long Liang Shaolei Zhao Chunli Wang Dongming Yin Shaohua Wang Qingshuang Wang Fei Liang Shouliang Li Limin Wang Yong Cheng 
The authors acknowledged the National Key Research and Development Program of China(No.2021YFB4000604);Key R&D projects of Jilin Provincial Science and Technology Development Plan(Nos.20230201125GX,20230201140GX,and 20200401039GX);Special fund of Scientific and Technological Cooperation Program between Jilin Province and Chinese Academy of Sciences(No.2021SYHZ0045);Jilin Scientific and Technological Development Program(No.20200401039GX);State Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization(No.2021H2270);Youth Innovation Promotion Association CAS(No.2021225);Youth Growth Science and Technology Program of Jilin Province(No.20220508001RC).
Aluminum hydride is a promising chemical hydrogen storage material that can achieve dehydrogenation under mild conditions as well as high hydrogen storage capacity.However,designing an efficient and cost-effective cat...
关键词:hydrogen storage aluminium hydride CATALYSIS synergistic effect DEHYDROGENATION 
Dehydrogenation behavior and mechanism of LiAlH_(4) adding nano-CeO_(2)with different morphologies被引量:3
《Nano Research》2023年第7期9426-9434,共9页Chunmin Zhang Long Liang Shaolei Zhao Zhijian Wu Shaohua Wang Dongming Yin Qingshuang Wang Limin Wang Chunli Wang Yong Cheng 
This work was supported by the National Key R&D Program of China(No.2021YFB4000604);National Science and Technology Major Project(No.2020YFE0204500);Youth Growth Science and Technology Program of Jilin Province(No.20220508001RC);Major Science and Technology Project of Inner Mongolia(No.2021ZD0029);Youth Innovation Promotion Association CAS(Nos.2021225 and 2022225);Independent Research Project of the State Key Laboratory of Rare Earth Resources Utilization,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences(No.110000RL86).
Complex hydride LiAlH_(4),as a hydrogen storage material,possesses high theoretical hydrogen storage capacity(10.5 wt.%).However,highly efficient additives are urgently required to modify its thermal stability and slu...
关键词:hydrogen storage LiAlH_(4) nano-CeO_(2) MORPHOLOGY 
Fully-exposed Pt clusters stabilized on Sn-decorated nanodiamond/graphene hybrid support for efficient ethylbenzene direct dehydrogenation被引量:2
《Nano Research》2022年第12期10029-10036,共8页Linlin Wang Xuetao Qin Ting Sun Xiangbin Cai Mi Peng Zhimin Jia Xiaowen Chen Ning Wang Jiangyong Diao Hongyang Liu Ding Ma 
supported by the National Key Research and Development Program of China(No.2021YFA1502802);the National Natural Science Foundation of China(Nos.21961160722,92145301,U21B2092,22072162,and 91845201);the Liaoning Revitalization Talents Program(No.XLYC1907055);Natural Science Foundation of Liaoning Province(No.2021-MS001);IMR Innovation Fund(No.2022-PY05);Dalian National Lab for Clean Energy(No.DNL Cooperation Fund 202001);the Sinopec China.N.W.hereby acknowledges the funding support from the Research Grants Council of Hong Kong(Nos.C6021-14E,N_HKUST624/19,and 16306818);The XAS experiments were conducted in Shanghai Synchrotron Radiation Facility(SSRF)。
The pursuit of energy conservation and environmental protection has always been a hot topic in the catalytic fields,which is inseparable from the rational designing of efficient catalysts and an in-depth understanding...
关键词:Pt cluster ethylbenzene dehydrogenation fully-exposed catalyst heterogeneous catalysis 
Ru/NC heterointerfaces boost energy-efficient production of green H_(2)over a wide pH range被引量:2
《Nano Research》2022年第6期5134-5142,共9页Qifeng Yang Botao Zhu Feng Wang Cunjin Zhang Jiahao Cai Peng Jin Lai Feng 
supported in part by the Natural Science Foundation of China(No.52172050);Natural Science Research Project of Jiangsu Higher Education Institutions(No.21KJA480002);six talent peaks project in Jiangsu province(No.XCL-078);the National Key Research,and Suzhou Key Laboratory for Advanced Carbon Materials and Wearable Energy Technologies.L.F.also thanks Beijing Synchrotron Radiation Facility(BSRF);Institute of High Energy Physics of the Chinese Academy of Sciences,for XANES measurements.
Green hydrogen(H_(2))is an import energy carrier due to the zero-carbon emission in the energy cycle.Nevertheless,green H_(2)production based on electrolyzer and photovoltaics(EZ/PV)remains limited due to the highly p...
关键词:energy-efficient hydrogen production hydrazine oxidation HETEROINTERFACE DEHYDROGENATION photovoltaicselectrochemistry coupling 
Jahn-Teller distortion assisted interstitial nitrogen engineering:Enhanced oxygen dehydrogenation activity of N-doped Mn_(x)Co_(3-x)O_(4) hierarchical micro-nano particles被引量:2
《Nano Research》2021年第8期2637-2643,共7页Yangxin Jin Fengfeng Li Peixin Cui Yun Yang Qingping Ke Minh Ngoc Ha Wangcheng Zhan Fei Ruan Chao Wan Zhao Lei Van Noi Nguyen Wei Chen Jun Tang 
supported by the Anhui Provincial Natural Science Foundation of China(2008085M47);“Key Program for International S&T Cooperation Projects of China”(No.2017YFE0124300);Anhui Provincial Science Fund for Excellent Young Scholars(gxyqZD2018034).
Rational design of earth-abundant transition metal oxides catalysts is highly desirable for developing sustainable chemical processes.Herein,we demonstrate a prospective interstitial nitrogen engineering for fabricati...
关键词:transition metal oxides Jahn-Teller effect interstitial nitrogen engineering MnxCo_(3-x)O_(4) DEHYDROGENATION 
Atomic iron on mesoporous N-doped carbon to achieve dehydrogenation reaction at room temperature被引量:7
《Nano Research》2020年第11期3075-3081,共7页Zheng Chen Wenjuan Yang Yue Wu Chao Zhang Jun Luo Chen Chen Yadong Li 
supported by the National Natural Science Foundation of China(Nos.21901007 and 21866032);we acknowledge the BL12B beamline of National Synchrotron Radiation Laboratory(NSRL)in Hefei and 1W1B station of Beijing Synchrotron Radiation Facility(BSRF).Our work is completed on the“Explorer 100”cluster system of Tsinghua HPC Platform.
Atomic non-noble metal materials show the potential to substitute noble metals in catalysis.Herein,melamine formaldehyde resin is developed to synthesize atomic iron on mesoporous nitrogen-doped carbon.The triazine un...
关键词:atomic dispersion non-noble metal nitrogen-doped carbon mesoporous structure DEHYDROGENATION 
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