supported by the Key R&D projects of Jilin Provincial Science and Technology Development Plan(Nos.20230201140GX and 20230201125GX);the National Key Research and Development Program of China(No.2021YFB4000604);the Youth Innovation Promotion Association CAS(No.2022225);the Youth Growth science and technology Plan project of Jilin Province Science and Technology Development Plan(No.20220508001RC);the Independent Research Project of the State Key Laboratory of Rare Earth Resources Utilization(No.110000RL86);the Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,the National Natural Science Foundation of China(No.22103010);the Natural Science Foundation of Shandong Province(No.ZR2021QB104).
α-AlH_(3)is regarded as one of the most promising hydrogen storage materials due to its high hydrogen storage capacity(10.1 wt.%,148 kg·m^(-3)).However,in practical applications,the associated hydrogen release tempe...
supported by the National Natural Science Foundation of China(Nos.U22A20120,52071135,51871090,and U1804135);the Natural Science Foundation of Hebei Province for Innovation Groups Program(No.C2022203003);Fundamental Research Funds for the Universities of Henan Province(No.NSFRF220201).
Magnesium hydride(MgH_(2))is considered as an ideal hydrogen storage material with excellent hydrogen capacity,but the slow kinetics impedes its application.Herein,an efficient additive of V2C MXene-anchored PrF_(3) n...
support from Iowa State University(Herbert L.Stiles Professorship).Y.X.and T.K.M.appreciate the start-up funding from the College of Engineering and Science at Louisiana Tech University.Z.W.W.and J.T.M.were supported by the National Science Foundation under Cooperative Agreement(NSF/ERC CISTAR,No.EEC-164772);Use of the Advanced Photon Source,a US Department of Energy Office of Basic Energy Sciences,was supported under contract no.DE-AC02-06CH11357.
Atomically thin Pt nanolayers were synthesized on the surface of Mo2TiC2 MXenes and used for the catalytic dehydrogenation of ethane and propane into ethylene and propylene,two important chemicals for the petrochemica...
the National Natural Science Foundation of China(Nos.22179038,22272053,22072043,21773069,and 21703069);the Special Project for Peak Carbon Dioxide Emissions-Carbon Neutrality(No.21DZ1206700)from the Shanghai Municipal Science;Technology Commission,and the Key Basic Research Project(No.18JC1412100)from the Shanghai Municipal Science and Technology Commission.
The gas-phase dehydrogenation of 1,6-hexanediol(1,6-HDO)toε-caprolactone(ε-CL)over the high-performance Cu-based catalysts is highly desirable,but with grand challenges,because the Cu nanoparticles(NPs)are easy to b...
The authors acknowledged the National Key Research and Development Program of China(No.2021YFB4000604);Key R&D projects of Jilin Provincial Science and Technology Development Plan(Nos.20230201125GX,20230201140GX,and 20200401039GX);Special fund of Scientific and Technological Cooperation Program between Jilin Province and Chinese Academy of Sciences(No.2021SYHZ0045);Jilin Scientific and Technological Development Program(No.20200401039GX);State Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization(No.2021H2270);Youth Innovation Promotion Association CAS(No.2021225);Youth Growth Science and Technology Program of Jilin Province(No.20220508001RC).
Aluminum hydride is a promising chemical hydrogen storage material that can achieve dehydrogenation under mild conditions as well as high hydrogen storage capacity.However,designing an efficient and cost-effective cat...
This work was supported by the National Key R&D Program of China(No.2021YFB4000604);National Science and Technology Major Project(No.2020YFE0204500);Youth Growth Science and Technology Program of Jilin Province(No.20220508001RC);Major Science and Technology Project of Inner Mongolia(No.2021ZD0029);Youth Innovation Promotion Association CAS(Nos.2021225 and 2022225);Independent Research Project of the State Key Laboratory of Rare Earth Resources Utilization,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences(No.110000RL86).
Complex hydride LiAlH_(4),as a hydrogen storage material,possesses high theoretical hydrogen storage capacity(10.5 wt.%).However,highly efficient additives are urgently required to modify its thermal stability and slu...
supported by the National Key Research and Development Program of China(No.2021YFA1502802);the National Natural Science Foundation of China(Nos.21961160722,92145301,U21B2092,22072162,and 91845201);the Liaoning Revitalization Talents Program(No.XLYC1907055);Natural Science Foundation of Liaoning Province(No.2021-MS001);IMR Innovation Fund(No.2022-PY05);Dalian National Lab for Clean Energy(No.DNL Cooperation Fund 202001);the Sinopec China.N.W.hereby acknowledges the funding support from the Research Grants Council of Hong Kong(Nos.C6021-14E,N_HKUST624/19,and 16306818);The XAS experiments were conducted in Shanghai Synchrotron Radiation Facility(SSRF)。
The pursuit of energy conservation and environmental protection has always been a hot topic in the catalytic fields,which is inseparable from the rational designing of efficient catalysts and an in-depth understanding...
supported in part by the Natural Science Foundation of China(No.52172050);Natural Science Research Project of Jiangsu Higher Education Institutions(No.21KJA480002);six talent peaks project in Jiangsu province(No.XCL-078);the National Key Research,and Suzhou Key Laboratory for Advanced Carbon Materials and Wearable Energy Technologies.L.F.also thanks Beijing Synchrotron Radiation Facility(BSRF);Institute of High Energy Physics of the Chinese Academy of Sciences,for XANES measurements.
Green hydrogen(H_(2))is an import energy carrier due to the zero-carbon emission in the energy cycle.Nevertheless,green H_(2)production based on electrolyzer and photovoltaics(EZ/PV)remains limited due to the highly p...
supported by the Anhui Provincial Natural Science Foundation of China(2008085M47);“Key Program for International S&T Cooperation Projects of China”(No.2017YFE0124300);Anhui Provincial Science Fund for Excellent Young Scholars(gxyqZD2018034).
Rational design of earth-abundant transition metal oxides catalysts is highly desirable for developing sustainable chemical processes.Herein,we demonstrate a prospective interstitial nitrogen engineering for fabricati...
supported by the National Natural Science Foundation of China(Nos.21901007 and 21866032);we acknowledge the BL12B beamline of National Synchrotron Radiation Laboratory(NSRL)in Hefei and 1W1B station of Beijing Synchrotron Radiation Facility(BSRF).Our work is completed on the“Explorer 100”cluster system of Tsinghua HPC Platform.
Atomic non-noble metal materials show the potential to substitute noble metals in catalysis.Herein,melamine formaldehyde resin is developed to synthesize atomic iron on mesoporous nitrogen-doped carbon.The triazine un...