supported by the National Key Technologies R&D Program of China(2011BAC01B03);the Natural Science Foundation of Yunnan Province(2013FZ035);support by Kunming University of Science and Technology through the Fund for Testingand Analyzing(No.2010213)
A series of CuO-ZnO-Al2O3-La2O3/HZSM-5 biftmctional catalysts with various La loadings for dimethyl ether (DME) directly synthesized from CO2 hydrogenation were prepared. The catalysts were characterized with N2 ads...
The reaction of the THF solution of (C5H5)2NdCl· 2LiCl with n-butyllithium was studied and the neodymium hydride complex, [ Li ( DME )3 ] [ (C5H5)3Nd (μ-H) Nd ( C5H5 )3 ] 1 was isolated from the reaction s...
Reaction of (C5H4Me)3Sm with AgBPh4 in THFDME provides a route to cationic organosamarium complex of . The product is characterized by elemental analysis, infrared spectra and Xray crystallography. Crystallographic ...
The reaction of MeCpLnCl·2LiCl·nTHF with 2 equivalent of LiNPh_2 in THF,hexane and toluene mixture solution gives the new complex[Li(DME)_2][(η~5-MeCp)Ln(NPh_2)_3](Ln=La,Pr,Nd)by extraction with DME.They have been ...
The project supported by the National Natural Science Foundation of China
The reaction of NdCl_3 with NaC_5Me_5 generates a novel complex (C_5Me_5)_2Nd(μ-Cl)_2Na(DME)_2 (1). Then (1) reacts with 1 mol ratio Na and a little methyl-naphthalene generating another novel complex (C_5Me_5)_2Nd(...
The crystal structure of title complex has been determined by the method of X-ray single crystal diffraction.The crystal belongs to monoclinic space group C_(2/c)with the unit parameters a=2.8907(7), b=2.0431(5),c=1.5...