Supported by the NNSF for Distinguished Young Scholars of China (No. 20725101);the 973 program (No. 2006CB932900);the NNSFC (No. 20521101);the NSF of Fujian Province (No. E0510030);Key Project from CAS (No. KJCX2-YW-H01)
A novel hexa-NiⅡ substituted trilacunary Keggin polyoxometalate [{Ni6(μ3- OH)3(en)3(H2O)6}(B-α-PW9O34)]-6H2O 1 (en = ethylenediamine) has been hydrothermally synthesized and characterized by IR spectra, e...