INTERMEDIATES

作品数：164被引量：255H指数：8
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相关机构：中国科学院浙江大学湖南大学中国农业科学院兰州兽医研究所更多>>
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Reaction mechanism and kinetics of Criegee intermediate and hydroperoxymethyl formate
《Journal of Environmental Sciences》2021年第7期128-137,共10页Meifang Chen Shengrui Tong Zhen Wang Weiran Li Yanyong Xu Sufan Wang Maofa Ge 
supported by the National Key Research and Development Program of China(No.2016YFC0202200);the Na-tional Natural Science Foundation of China(No.42022039);Beijing National Laboratory for Molecular Sciences(No.BNLMS-CXXM-202011);Beijing Nova Program(No.2018113);the Youth Innovation Promotion Association CAS(No.2017042).
The reaction mechanism and kinetics of the simplest Criegee intermediate CH_(2)OO reaction with hydroperoxymethyl formate(HPMF)was investigated at high-level quantum chemistry calculations.HPMF has two reactive functi...
关键词：Criegee intermediates Hydroperoxymethyl formate Mechanism KINETICS POLYMERIZATION 
Activation and surface reactions of CO and H2 on ZnO powders and nanoplates under CO hydrogenation reaction conditions
《Journal of Energy Chemistry》2020年第11期351-357,共7页Liyuan Zhang Xuanyu Zhang Kun Qian Zhaorui Li Yongqiang Cheng Luke LDaemen Zili Wu Weixin Huang 
the National Key R&D Program of Ministry of Science and Technology of China(2017YFB0602205);the National Natural Science Foundation of China(21525313,91745202,91945301);the Chinese Academy of Sciences;the Changjiang Scholars Program of Ministry of Education of China;the financial support of the China Scholarship Council;supported by the Scientific User Facilities Division,Office of Basic Energy Sciences,US DOE,under Contract No.DE-AC0500OR22725 with UT Battelle,LLC;supported by the U.S.Department of Energy,Office of Science,Office of Basic Energy Sciences,Chemical Sciences,Geosciences,and Biosciences Division,Catalysis Science Program。
Activation and surface reactions of CO and H2 on ZnO powders and nanoplates under CO hydrogenation reaction conditions were(quasi) in situ studied using temperature programmed surface reaction spectra, diffuse reflect...
关键词：Active species Surface intermediates Reaction mechanism TPSR DRIFTS INS EPR 
Synergistic effects of crystal structure and oxygen vacancy on Bi2O3 polymorphs:intermediates activation,photocatalytic reaction efficiency,and conversion pathway被引量：12
《Science Bulletin》2020年第6期467-476,M0004,共11页Ben Lei Wen Cui Jianping Sheng Hong Wang Peng Chen Jieyuan Li Yanjuan Sun Fan Dong 
supported by the National Natural Science Foundation of China (21822601, 21777011, and 21501016);the Innovative Research Team of Chongqing (CXQT19023);the Natural Science Foundation of Chongqing (cstc2017jcyj BX0052);the Plan for “National Youth Talents” of the Organization Department of the Central Committee, the Innovative Project from Chongqing Technology and Business University (yjscxx2019-101-67);the Fundamental Research Funds for the Central Universities (ZYGX2019Z021)。
This work unraveled the synergistic effects of crystal structure and oxygen vacancy on the photocatalytic activity of Bi2O3 polymorphs at an atomic level for the first time. The artificial oxygen vacancy is introduced...
关键词：Crystal structur Oxygen vacancy Reaction mechanism Synergistic effect In situ FT-IR 
Chlorobenzene degradation by electro-heterogeneous catalysis in aqueous solution:intermediates and reaction mechanism被引量：10
《Journal of Environmental Sciences》2008年第11期1306-1311,共6页WANG Jiade MEI Yu LIU Chenliang CHEN Jianmeng 
the Science and Technology Department of Zhejiang Province (No.2006C13120).
This study was performed to investigate the variables that influence chlorobenzene (CB) degradation in aqueous solution by electro-heterogeneous catalysis.The effects of current density,pH,and electrolyte concentratio...
关键词：electro-heterogeneous catalysis ELECTROCHEMICAL CHLOROBENZENE INTERMEDIATES 
REACTION MECHANISM OF BENZOPHENONE-PHOTOINITIATED CROSSLINKING OF POLYETHYLENE
《Chinese Journal of Polymer Science》2002年第4期291-307,共17页Bao-jun Qu State Key Laboratory of Fire Science and Department of Polymer Science and Engineering University of Science and Technology of China Hefei 230026 China 
The project was successively supported by the National Natural Science Foundation of China (No. 50073022, No 59773030, No. 59543002 and No. 5880104).
The radical intermediates, the crosslink microstructures, and the reaction mechanism of benzophenone (BP)-photoinitiated crosslinking of low-density polyethylene (LDPE) and model compounds (MD) have been reviewed in d...
关键词：photocrosslinking mechanism polymer radical intermediates crosslink microstructures photolytic products of benzophenone POLYETHYLENE model compound 
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