IONIC_LIQUIDS

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Low-melting mixture solvents:extension of deep eutectic solvents and ionic liquids for broadening green solvents and green chemistry
《Green Chemical Engineering》2024年第4期409-417,共9页Yu Chen Zhiwu Yu 
supported by the National Natural Science Foundation of China(No.22233006)
Green solvents such as water and ionic liquids(ILs)are pillars of the great mansion of green chemistry and green processing.Initially proposed as a new family of ILs,deep eutectic solvents(DESs)have received fast deve...
关键词：Green solvents Deep eutectic solvents Low transition temperature mixture solvents Phase diagram EGaIn 
The role of hydrogen bonding in solubilizing camptothecin in hydrophilic and hydrophobic ionic liquids
《Green Chemical Engineering》2024年第4期489-500,共12页Xiaotong Zhu Liwen Mu Jiahua Zhu Xiaohua Lu Yuanhui Ji 
supported by the National Natural Science Foundation of China(Grant Nos.:22278070,21978047)
Utilizing ionic liquid(IL)-water mixtures as selective extraction solvents for raw materials from natural sources represents an efficacious approach;however,elucidating the underlying mechanisms inherent in various ty...
关键词：Ionic liquids Hydrogen bonding Molecular dynamics simulation Phase separation Quantum chemistry calculations 
A systematic COSMO-RS study on mutual solubility of ionic liquids and C6-hydrocarbons
《Green Chemical Engineering》2024年第1期97-107,共11页Chuxin Qi Zhen Song Hongye Cheng Lifang Chen Zhiwen Qi 
The financial support from the National Natural Science Foundation of China(22278134)
When considering the usage of ionic liquids(ILs)for reactions and separations involving non-polar or weak-polar hydrocarbons,the knowledge of the mutual solubility behaviors of ILs and hydrocarbons is of the utmost im...
关键词：C6-hydrocarbons Ionic liquids Mutual solubility COSMO-RS Structural effect analysis 
Efficient synthesis of cyclic carbonates under atmospheric CO_(2) by DMAP-based ionic liquids: the difference of inert hydrogen atom and active hydrogen atom in cation
《Green Chemical Engineering》2023年第3期285-293,共9页Zhengkun Zhang Jinya Li Guanyao Yu Chao Zeng Menglong Wang Susu Huang Li Wang Jinglai Zhang 
This work was supported by the National Natural Science Foundation of China(21975064,22178087);Program of Henan Center for Outstanding Overseas Scientists(GZS2020011);Henan University's First-Class Discipline Science and Technology Research Project(2018YLTD07,2018YLZDYJ11,2019YLZDYJ09);the Excellent Foreign Experts Project of Henan University.
The coupling reaction of carbon dioxide(CO_(2)) and epoxides is one of the most efficient pathways to achieve the carbon balance.However,to accomplish it under the mild conditions,especially under the atmospheric pres...
关键词：Carbon dioxide DMAP-based ionic liquids Inert hydrogen atom DFT calculations Atmospheric pressure 
Highly efficient separation of benzene+cyclohexane mixtures by extraction combined extractive distillation using imidazolium-based dicationic ionic liquids被引量：2
《Green Chemical Engineering》2023年第3期312-323,共12页Wanxiang Zhang Wuji Zhao Shuhang Ren Yucui Hou Weize Wu 
This work is financially supported by the National Key R&D Program of China(2017YFB0602401).
Benzene(BEN)and cyclohexane(CYH),which have very close boiling points and a binary azeotrope,are the most difficult binary components in the separation of aromatic and non-aromatic hydrocarbons.This study further expl...
关键词：Dicationic ionic liquids Benzeneþcyclohexane mixture LLE-ED process Quantum chemical calculation Molecular dynamics simulation 
Understanding the interfacial properties of benzene alkylation with 1-dodecene catalyzed by immobilized chloroaluminate ionic liquids using molecular dynamics simulation被引量：1
《Green Chemical Engineering》2023年第3期338-345,共8页Weizhong Zheng Jialei Sha Weizhen Sun Ling Zhao 
The financial support by State Key Laboratory of Heavy Oil Processing
Benzene alkylation catalyzed by immobilized ionic liquids(ILs)on solid carriers is considered as a heterogeneous reaction,in which the interfacial properties play an important role.Hence,the interfacial characteristic...
关键词：Benzene alkylation Interfacial property Molecular dynamics simulation Immobilized ionic liquids 
Development of a correlation equation between the diesterification of maleic anhydride and the acidic ionic liquids nature被引量：1
《Green Chemical Engineering》2023年第1期57-63,共7页Yumei Liu Shengxin Chen Ran An Xingsheng Wang Ruixia Liu 
supported by the National Natural Science Foundation of China(21878315);the National Key Research and Development Program of China(2017YFA0206803);the Key Programs of the Chinese Academy of Sciences(KFZD-SW-413);the Key Programs of Innovation Academy for Green Manufacture,CAS(IAGM2020C17)。
The sustainable synthesis of dimethyl maleate via diesterification through the utilization of ionic liquid(IL)is of great importance.However,the relationship between the ILs nature and the reactivity of diesterificati...
关键词：Multiparameter correlation equation Diesterification Maleic anhydride Ionic liquids Kamlet-Taft solvent parameters 
Tailoring the partitioning of proteins using ionic liquids as adjuvants in polymer-polymer aqueous biphasic systems被引量：2
《Green Chemical Engineering》2022年第4期328-337,共10页Flavia F.Magalhaes Matheus M.Pereira Rita de Cassia Superbi de Sousa Ana P.M.Tavares Joao A.P.Coutinho Mara G.Freire 
funds through the FCT/MEC and when appropriate co-financed by FEDER under the PT2020 Partnership Agreement;supported by POCI-01-0145-FEDER-031268 funded by FEDER,through COMPETE2020-Programa Operacional Competitividadee Internacionalizaçao(POCI);by national funds(OE),through FCT/MCTES.Ana P.M.Tavares acknowledges FCT for the research contract CEECIND/2020/01867.Flavia Magalhaes acknowledges the SPQ/FCT PhD grant(SFRH/BD/150669/2020).
Aqueous biphasic systems(ABS)are promising for proteins purification;however,when dealing with samples comprising several proteins,the selectivity towards a target protein is difficult to achieve.In this work,the addi...
关键词：Aqueous biphasic systems Polymer-polymer systems Protein partition Ionic liquids ADJUVANTS 
Facilitated transport separation of CO_(2) and H_(2)S by supported liquid membrane based on task-specific protic ionic liquids被引量：2
《Green Chemical Engineering》2022年第3期259-266,共8页Lingling Peng Mingzhen Shi Xiaomin Zhang Wenjie Xiong Xingbang Hu Zhuoheng Tu Youting Wu 
This work was sponsored by the Natural Science Foundation of Jiangsu Province(BK20190310);China Postdoctoral Science Foundation(2021M691515);the Postdoctoral Science Foundation of Jiangsu Province(2021K211B);the National Natural Science Foundation of China(Nos.22078145 and 21878141)。
Selective separation of CO_(2) and H_(2)S from CH_(4) is of importance to the natural gas upgrading because of its cor-rosivity. As is well known, amine group can recognize reversibly CO_(2) and H_(2)S with a moderate...
关键词：Ionic liquids Carbon dioxide Membrane separation Facilitated transport Natural gas sweentening 
Recovery of natural active molecules using aqueous two-phase systems comprising of ionic liquids/deep eutectic solvents被引量：9
《Green Chemical Engineering》2022年第1期5-14,共10页Yicong Wang Shanshan Wang Leilei Liu 
supported by National Natural Science Foundation of China(No.21864012);Jishou University National and Local United Engineering Laboratory of Integrative Utilization of Eucommia ulmoides open item(No.DZL201801);Natural Science Innovation Project of Jishou University(No.Jdy20049)。
Due to environmental protection requirements,extraction of bioactive compounds from plant materials using environment-friendly green solvents has always been a research hotspot.And great efforts of scholars have been ...
关键词：Ionic liquids Deep eutectic solvents Aqueous two-phase system Natural active molecules Extraction and separation 
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