稀土改性ZSM-5分子筛在烃类催化裂解制低碳烯烃领域中的研究进展  被引量:3

Progress in the catalytic cracking of hydrocarbons over rare earth modified-ZSM-5 zeolites to produce light olefins

在线阅读下载全文

作  者:肖霞 王鹏 潘昱彤[1,2] 赵震 姜桂元 范晓强[1,2] 孔莲[1,2] 解则安 XIAO Xia;WANG Peng;PAN Yutong;ZHAO Zhen;JIANG Guiyuan;FAN Xiaoqiang;KONG Lian;XIE Zean(College of Chemistry and Chemical Engineering,Shenyang Normal University,Shenyang 110034,China;Institute of Catalysis for Energy and Environment,Shenyang Normal University,Shenyang 110034,China;State Key Laboratory of Heavy Oil Processing,China University of Petroleum,Beijing,102249,China)

机构地区:[1]沈阳师范大学化学化工学院,沈阳110034 [2]沈阳师范大学能源与环境催化研究所,沈阳110034 [3]中国石油大学重质油国家重点实验室,北京102249

出  处:《沈阳师范大学学报(自然科学版)》2022年第2期121-126,共6页Journal of Shenyang Normal University:Natural Science Edition

基  金:中石油卡脖子关键技术项目(HX20210232);国家自然科学基金资助项目(21802098,91845201)

摘  要:烃类催化裂解生产乙烯、丙烯已经引起了石化行业的广泛关注。ZSM-5分子筛由于其优异的孔道择形性、适宜的酸性质、良好的水热稳定性以及抗结焦能力等,是目前烃类催化裂解反应中最高效的催化剂之一。稀土元素因自身独特的4f电子层结构和镧系收缩特性,在催化反应过程中表现出良好的助催化性能。目前,稀土分子筛催化材料在石油化工领域发挥着重要作用。总结了La,Ce等稀土元素对分子筛催化剂结构、酸性质和稳定性等物化性质的影响,重点论述了稀土改性ZSM-5分子筛在烃类催化裂解反应中的研究进展及作用机理,提出了稀土分子筛催化材料未来的发展前景。The catalytic cracking of hydrocarbons to produce light olefins has attracted extensive attention in petrochemical industry.ZSM-5zeolites have been considered as one of the most effective catalysts because of its excellent shape selectivity,suitable acidity,good hydrothermal stability and anti-coking ability.Rare earth(RE)elements show good co-catalytic performance in catalytic reactions due to its unique 4felectron structure and lanthanide contraction characteristic.Currently,rare earth elements modified zeolites catalytic materials play an important role in the petrochemical industry.In this paper,we review the effects of rare earth elements such as lanthanum(La)and cerium(Ce)on the structure,acidity,and stability of the zeolites catalysts.And the research progress and reaction mechanisms of rare earth modified-ZSM-5zeolites in hydrocarbons catalytic cracking are summarized.Finally,the perspectives for future research directions of rare earth element modified zeolites are proposed.

关 键 词:稀土 ZSM-5分子筛 催化裂解 低碳烯烃 

分 类 号:TQ221.2[化学工程—有机化工] TQ426

 

参考文献:

正在载入数据...

 

二级参考文献:

正在载入数据...

 

耦合文献:

正在载入数据...

 

引证文献:

正在载入数据...

 

二级引证文献:

正在载入数据...

 

同被引文献:

正在载入数据...

 

相关期刊文献:

正在载入数据...

相关的主题
相关的作者对象
相关的机构对象