以高分子金属络合物为催化剂从CO_2合成DMC的研究  

Synthesis of Dimethyl Carbonate from Carbon Dioxide By Metal Complex of High Polymer Catalyst

作　　者：聂芊[1] 吴春[1] 吴艳华[1] 

机构地区：[1]哈尔滨商业大学化学中心,黑龙江哈尔滨150076

出　　处：《哈尔滨商业大学学报（自然科学版）》2002年第1期113-114,116,共3页Journal of Harbin University of Commerce：Natural Sciences Edition

摘　　要：制备了PAA-AM-Mn高分子金属络合物,以此为催化剂,在环氧氯丙烷存在下,由甲醇和二氧化碳在热压下反应合成碳酸二甲酯。研究了配位体配比、金属离子对催化剂活性的影响,并研究了反应物甲醇与环氧氯丙烷配比及催化剂用量对DMC产率的影响。The metal complex of high polymer catalyst was prepared.Dimethyl carbonate was synthesized from carbon dioxide and methanol by metal complex of high polymer catalyst in the presence of chloroepoxy propane.The effects of the proper ratio of ligand,metal iron on the catalyst were investigated.The proper ratio of the methanol and chloroepoxy propane,the content of catalyst on DMC rate were also studied.

关 键 词：碳酸二甲酯 高分子金属络合物 甲醇 二氧化碳 

分 类 号：O621.3[理学—有机化学]