SYNDIOSPECIFIC POLYMERIZATION OF STYRENE WITH Ar[O,O/NH]Cp ~*TiCl ACTIVATED WITH MMAO  

作　　者：陈劼 

机构地区：[1]Haerbin Institute of Technology Postdoctoral Station of School of Materials Science and Engineering [2]Daqing Oilfield Company Ltd.,Exploration and Development of Research Institute

出　　处：《Chinese Journal of Polymer Science》2009年第5期659-665,共7页高分子科学（英文版）

摘　　要：A series of titanium complexes Ar[O,E]Cp~*TiCl(Cp~*=C_5Me_5,Ar=1,2-phenylene,E=NH(1a);Ar=1,2- phenylene,E=O(1b);Ar=2.2'-diphenylene,E=O(1c);Ar=2,2'-dinaphthalene,E=O(1d)) has been prepared by the reaction of corresponding phenol derivatives with Cp~*TiCl_3 in the presence of excessive triethylamine.Under the conditions of low Al/Ti molar ratio(e.g.500) and high reaction temperatures(>70℃),all the titanium complexes display higher catalytic activities towards the syndiospecific polymerization of styrene,in t...A series of titanium complexes Ar[O,E]Cp~*TiCl(Cp~*=C_5Me_5,Ar=1,2-phenylene,E=NH(1a);Ar=1,2- phenylene,E=O(1b);Ar=2.2'-diphenylene,E=O(1c);Ar=2,2'-dinaphthalene,E=O(1d)) has been prepared by the reaction of corresponding phenol derivatives with Cp~*TiCl_3 in the presence of excessive triethylamine.Under the conditions of low Al/Ti molar ratio(e.g.500) and high reaction temperatures(>70℃),all the titanium complexes display higher catalytic activities towards the syndiospecific polymerization of styrene,in t...

关 键 词：Ziegler-Natta polymerization CATALYSTS SYNDIOTACTIC Polystyrene. 

分 类 号：O631.3[理学—高分子化学]