相关期刊:《Chemical Research in Chinese Universities》《Frontiers of Chemical Science and Engineering》《Science China Chemistry》《Open Journal of Polymer Chemistry》更多>>
This work was financially supported by the National Key R&D Program of China(No.2022YFB3704700).
In this study,a novel iron-based catalyst system,Fe(acac)3/(isocyanoimino)triptenylphosphorane(IITP)/AlR3,was employed for the synthesis of syndiotactic 1,2-polybutadiene in hexane.This catalyst system exhibits remark...
financially supported by the National Natural Science Foundation of China (Nos. 51773193 and 21634007);department of science and technology of Jilin province (No.20180101171JC);the "973" project (No. 2015CB654702)
Salt metathesis reactions between pyridyl-methylene-cyclopentadienyl lithium salt and LnCl_3 followed by the addition of two equivalents of LiCH_2SiMe_3 afforded a series of constrained-geometry-configuration rare-ear...
financially supported by the National Natural Science Foundation of China (Nos. 20974014, 21274012, 21322401 and 21774014);the 111 project (No. B07012)
The syndiotactic polymerization of styrene(St) and the copolymerization of St with ethylene(E) were carried out by using a series of chiral half-sandwich rare-earth metal dialkyl complexes(Cp^x*) as the catalys...
supported by the National Basic Research Program of China(2012CB821704);the National Natural Science Foundation of China(20972129);the Innovative Research Team Program(IRT1036,J1310024)
Synthesis and anionic polymerization of the fluorine-substituted phenyl methacrylates are herein reported. A series of monodi-, and multi-substituted fluorophenyl methacrylates H2C=C(CH3)C(O)OC6H4F-4 (M^1a), H2...
The crystallization and crystalline structure of syndiotactic-polypropylene (sPP) and syndiotactic-poly(1-butene) (sPB) blend containing 10 (Bl-10), 25 (Bl-25), 50 (Bl-50), 75 (Bl-75), and 90 (Bl-90) wt% of sPB, have ...
sponsored by the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry of China,the Science and Technology Innovation Program of the China National Petroleum Corporation,and the Key Laboratory of Advanced Polymer Materials of Shanghai(Grant No.08DZ2230500);the Science and Technology Innovation Program of China National Petroleum Corporation.
Two types of salicylaldiminato-based nickel complexes,mono-ligated Ni(II)complexes([O-C_(6)H_(4)-o-C(H)=N-Ar]Ni(PPh_(3))(Ph)(5),[O-(3,5-Br_(2))C_(6)H_(2)-o-C(H)=N-Ar]Ni(PPh_(3))(Ph)(6),[O-(3-t-Bu)C_(6)H_(3)-o-C(H)=N-A...
supported by the National Natural Science Foundation of China(No.50603029);the Innovation Foundation of Center for Molecular Science,Chinese Academy of Sciences(CMS-Y200724)
Syndiotactic polypropylene (sPP) as-spun fiber (sPP1) and drawn fiber (sPP2) were prepared by melt-spinning and melt-spinning/hot-drawing, respectively. The structure transition of the two fibers induced by anne...
A series of titanium complexes Ar[O,E]Cp~*TiCl(Cp~*=C_5Me_5,Ar=1,2-phenylene,E=NH(1a);Ar=1,2- phenylene,E=O(1b);Ar=2.2'-diphenylene,E=O(1c);Ar=2,2'-dinaphthalene,E=O(1d)) has been prepared by the reaction of correspon...
the Natural Science Foundation of Heilongjiang Province,China(No.B2005-09).
Morphologies,crystallization behavior and mechanical properties of polypropylene(PP)/syndiotactic 1,2-polybutadiene(s-1,2 PB)blends were investigated.Morphology observation shows the well dispersed domains of s-1,...
Project supported by the Major State Basic Research Development Program (No. G1999064801); and the National Natural Science Foundation of China (Nos. 20072004 and 29871010).
Yan-LongBALA, Muhammad D. XIE, Xiao-Min(HUANG, Ji-Ling*Laboratory of Organometallic Chemistry, East China University of Science and Technology, Shanghai 200237, China Benzyl-substituted cyclopentadienyl lanthanide...