HALF-SANDWICH

作品数：19被引量：13H指数：2
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Size-controlled synthesis and near-infrared photothermal response of Cp^(*)Rh-based metalla[2]catenanes and rectangular metallamacrocycles
《Chinese Chemical Letters》2024年第6期337-343,共7页Ying Zhao Yin-Hang Chai Tian Chen Jie Zheng Ting-Ting Li Francisco Aznarez Li-Long Dang Lu-Fang Ma 
supported by the National Natural Science Foundation of China(Nos.22101108 and 22171123);the Shanghai Science and Technology Committee(No.19DZ2270100);training Plan for Young Core Teachers in Higher Education of Henan Province(No.2021GGJS131);Natural Science Foundation of Henan Province(No.232300421232)。
A variety of research reports on novel supramolecular topologies have been published over the last years.However,it is still a great challenge to tap into the inner functional properties of these complexes.Herein,two ...
关键词：Catenanes Photothermal materials Supramolecular topologies Half-sandwich fragment 3 3'-N-donor analogues 
The cycloaddition reaction of ethylene and methane mediated by Ir^(+) to generate a half-sandwich structure Ir HCp^(+)
《Chinese Chemical Letters》2023年第1期192-197,共6页Wei Li Hechen Wu Xunlei Ding Xiaonan Wu 
supported by Beijing Natural Science Foundation(No.2214064);the National Natural Science Foundation of China(Nos.21603037,21688102,92161115,21973016,91545122);the Fundamental Research Funds for the Central Universities(Nos.JB2015RCY03,JB2019MS052)supported by the fund of North China Electric Power University。
The cycloaddition reactions of methane and ethylene mediated by Ir^(+) have been designed and studied by the techniques of mass spectrometry in conjunction with theoretical calculations.Studies have shown that Ir^(+) ...
关键词：Cycloaddition reaction Mass spectrometry Theoretical calculation Half-sandwich structure 
Rational Design and Synthesis of Interlocked[2]Catenanes Fea-turing Half-Sandwich Cp^(*)Rh/Ir Units and Pyrene-Based Ligands被引量：2
《Chinese Journal of Chemistry》2021年第12期3303-3308,共6页Yue-Rong Shen Xiang Gao Zheng Cui Guo-Xin Jin 
This work was supported by the National Natural Science Foundation of China(Nos.22031003 and 21720102004);the Shanghai Science Technology Committee(No.19DZ2270100).
The construction of interlocked topologies by metal-cation-template methods has been extensively explored.However,construction of these species using template-free chemical self-assembly methods is hard to rationally ...
关键词：Self-assembly Piinteractions Stacking interactions Half-sandwiched Cp^(*)-Rh/lr catenane 
Regioselective B—H/C—H Bond Activation at Azo-Substituted Carboranes Induced by Half-Sandwich Iridium(III)Complex
《Chinese Journal of Chemistry》2021年第2期281-287,共7页Peng-Fei Cui Yang Gao Shu-Ting Guo Guo-Xin Jin 
This work was supported by the National Natural Science Foun-dation of China(Nos.21531002,21720102004,22031003);the Shanghai Science Technology Committee(No.13JC1400600).
We report herein a practical approach for regio-selective B—H/C—H bond activation at azo-substituted carboranes. The reaction proceeded through Iridium(III)-induced selective B—H/C—H bond activations based on an a...
关键词：CARBORANE B-H bond activation HALF-SANDWICH IRIDIUM POLYNUCLEAR 
Control of Heterometallic Three-Dimensional Macrocycles with Aromatic Stacks in Tunable Host Cavities被引量：3
《Chinese Journal of Chemistry》2018年第7期594-598,共5页Wen-Xi Gao Qi-Jia Fan Yue-Jian Lin Guo-Xin Jin 
This work was supported by the National Natural Science Foundation of China （Nos. 21531002, 21720102004） and the Shanghai Science Technology Committee （No. 13JC1400600）. Guo-Xin Jin thanks the Alexander yon Humboldt Foundation for a Humboldt Research Award.
Using coinage metal （Cu（Ⅱ）, Ag（Ⅰ）） hinges, two sets of heterometallic molecular capsules with analogous open-ended cavities were prepared based on the half-sandwich rhodium fragments. In the case of [Rh4Cu4] c...
关键词：host-guest chemistry open-ended cavity heterometallic capsule half-sandwich rhodium fragments 
Syndiotactic Polymerization of Styrene and Copolymerization with Ethylene Catalyzed by Chiral Half-sandwich Rare-earth Metal Dialkyl Complexes被引量：1
《Chinese Journal of Polymer Science》2018年第2期222-230,共9页De-Qian Peng Xin-Wen Yan Shao-Wen Zhang Xiao-Fang Li 
financially supported by the National Natural Science Foundation of China (Nos. 20974014, 21274012, 21322401 and 21774014);the 111 project (No. B07012)
The syndiotactic polymerization of styrene（St） and the copolymerization of St with ethylene（E） were carried out by using a series of chiral half-sandwich rare-earth metal dialkyl complexes（Cp^x＊） as the catalys...
关键词：HALF-SANDWICH Rare-earth metal complex Syndiotacti cpolymerization COPOLYMERIZATION STYRENE ETHYLENE 
Half-sandwich Ruthenium Complexes with Naphthalene-based Schiff Base Ligands:Syntheses,Characterization and Catalytic Activities for the Reduction of Nitroarenes
《Chinese Journal of Structural Chemistry》2017年第11期1896-1903,共8页贾卫国 章慧 王之保 
financially supported by the National Nature Science Foundation of China(21102004);Natural Science Foundation of Anhui Province(1708085MB44);the Natural Science Foundation of the Anhui Higher Education Institutions(KJ2016A845)
Three half-sandwich ruthenium（II） p-cymene complexes containing naphthalenebased Schiff base ligands [Ru（p-cymene）LCl]（2 a～2 c） have been synthesized and characterized. Both Schiff-base ligands and ruthenium co...
关键词：ruthenium  reduction  complex  crystal structure 
New Half-sandwich Zirconium(Ⅳ) Complexes Containing Salicylaldimine Ligands： Synthesis, Characterizations and Catalytic Properties被引量：2
《Chemical Research in Chinese Universities》2014年第5期825-830,共6页LIU Kefeng YAO Gang WU Wenlei GAO Bo 
Supported by the National Natural Science Foundation of China（No.21204082）.
Two new half-sandwich zirconium（IV） complexes bearing salicylaldimine ligands of the type Cp＊Zr[2-tBu-4-R-6-（CH=NiPr）C6H2O]C12[R=H（1）, tBu（2）] were prepared by the reaction of Cp＊ZrC13 with the corresponding...
关键词：Zirconium complex Metallocene catalyst Ethylene polymerization Olefin copolymerization 
Ethylene (co-)polymerization by long-lifetime half-sandwich zirconium catalyst bearing a [SSO]-carborane ligand被引量：1
《Science China Chemistry》2014年第8期1137-1143,共7页HU Ping LI ZhenHua JIN GuoXin 
supported by the National Natural Science Foundation of China (91122017, 21374019);the Shanghai Science and Technology Committee (13JC1400600, 13DZ2275200);the Program for Changjiang Scholars and Innovative Research Team in University (IRT1117)
Half-sandwich zirconium complex 3 containing tridentate carborane [S,S,O] ligand 2 [(HOC6H2R2-4,6)(CH2)SC(B10H10) C(Ph)2P=S, R=tBu] was synthesized by the reaction of CpZrCl3(Cp=η5-C5H5) with sodium salt of ligand 2....
关键词：half-sandwich zirconium complex ethylene （co-）polymerization carborane ligand 
Cyclocopolymerization of 1,6-heptadiene with ethylene by half-sandwich scandium catalysts
《Science China Chemistry》2014年第8期1150-1156,共7页GUO Fang NISHIURA Masayoshi LI Yang HOU ZhaoMin 
supported by Grant-in-aid for Scientific Research (B) (24350030 to M.N.);a Grant-in-Aid for Scientific Research (S) ( 21225004 to Z.H.) from JSPS;the National Natural Science Foundation of China (21204008);the Fundamental Research Funds for the Central Universities (DUT12RC(3)94)
The cyclocopolymerization of 1,6-heptadiene （HPD） with ethylene （E） by a series of half-sandwich scandium alkyl catalysts bearing various auxiliary ligands have been examined. Significant ligand influence on the c...
关键词：SCANDIUM 1 6-heptadiene ETHYLENE CYCLOPOLYMERIZATION COPOLYMERIZATION 
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