CARBORANE

作品数：40被引量：25H指数：2
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相关领域：理学更多>>
相关作者：聂永王锦艳更多>>
相关机构：济南大学福州大学大连理工大学更多>>
相关期刊：《Science China Chemistry》《Chemical Research in Chinese Universities》《Chinese Journal of Polymer Science》《Journal of Donghua University(English Edition)》更多>>
相关基金：国家自然科学基金国家重点基础研究发展计划上海市教育委员会重点学科基金中国博士后科学基金更多>>
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Palladium-Catalyzed Direct B—H Oxygenation:Facile Synthesis of o-Carboranofuranones
《Chinese Journal of Chemistry》2024年第23期3083-3087,共5页Chenyang Guo Zaozao Qiu Zuowei Xie 
supported by the grants from the National Natural Science Foundation of China(Project Nos.22371290 and 92056106 to Z.Q.,Project No.22331005 to Z.X.);Shenzhen Science and Technology Program(Project No.QTD20221101093558015 to Z.X.);the Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis,CAS.
Recent advances in transition metal-catalyzed o-carborane B—H activation have led to the rapid development of various methodologies for cage boron functionalization.For catalytic cage B—H acyloxylation,intermolecula...
关键词：CARBORANE B-H activation OXYGENATION Catalysis Transition metal Palladium Cross-coupling Regioselectivity 
Enhancing blocking temperature using inverse hydrogen bonds for non-radical bridged dimeric Dy(Ⅲ)single-molecule magnets
《Science China Chemistry》2024年第10期3328-3338,共11页Peng-Bo Jin Qian-Cheng Luo Ye-Ye Liu Yan-Zhen Zheng 
supported by the National Natural Science Foundation of China(22375157);the State Key Laboratory of Electrical Insulation and Power Equipment(EIPE23402,EIPE23405);the Special Support Plan of Shaanxi Province for Young Top-notch Talent;the Fundamental Research Funds for Central Universities(xtr052023002,xzy012023024);the China Postdoctoral Science Foundation(2023M742783,GZB20240599);the Shaanxi Postdoctoral Science Foundation(2023BSHYDZZ12)。
Single-molecule magnets(SMMs)are a kind of nanosized magnetic materials that are capable of storing massive bytes of information.Strongly coupling the spin centers in a proper manner is a usual approach to promote the...
关键词：single-molecule magnets CARBORANE DYSPROSIUM ferromagnetic coupling inverse hydrogen bond 
Visible-Light-Promoted Palladium-Catalyzed Cross-Coupling of lodocarboranes with Disulfides and Phenylselenyl Chloride
《Chinese Journal of Chemistry》2024年第2期129-134,共6页Shimeng Li Yizhen Liu Zuowei Xie 
supported by a grant from the Southern University of Science and Technology.
This work describes a general method for the synthesis of a series of sulfenylated and selenylated carboranes at room temperature using readily available iodocarboranes as starting materials via boron-centered carbora...
关键词：CARBORANE SULFENYLATION Selenylation B-I activation RADICAL Photocatalysis Boron SELECTIVITY 
Nickel-catalyzed regioselective B(3,4,5,6)-H tetra-alkylation of o-carboranes
《Science China Chemistry》2023年第10期2836-2841,共6页Jianwei Zhao Zuowei Xie 
supported by the Research Grants Council of the Hong Kong Special Administration Region (SRFS20214S05)。
Though transition metal-catalyzed cage BH methylation has been well documented, catalytic alkylation of cage BH bonds remained elusive because transition metal alkyl complexes are prone to undergo β-H elimination. We...
关键词：nickel catalysis B-H activation CARBORANE ALKYLATION regioselectivity 
Octanuclear Palladacycles with B(3)-H Bond Activation of o-Carborane
《Chinese Journal of Chemistry》2023年第3期307-313,共7页Run-Ze Yuan Peng-Fei Cui Yue-Jian Lin Guo-Xin Jin 
supported by the National Natural Science Foundation of China (Nos.22031003,21720102004);the Shanghai Science Technology Committee (No.19DZ2270100).
Herein,we describe the synthesis of a carborane-supported octanuclear palladacycle complex,Pd_(8)(o-C_(2)B_(10)H_(10)CS_(2)CH_(3))_(4)Cl_(4)(CH_(3)CN)_(4)(complex 1),with B(3)-H activations on o-carborane ligand.The s...
关键词：CARBORANE Palladacycle Regioselective B-H activation Polynuclear complex Dithioester chemistry 
Recent advances on carborane-based ligands in low-valent group 13 and group 14 elements chemistry
《Chinese Chemical Letters》2022年第8期3672-3680,共9页Hao Wang 
the National Natural Science Foundation of China(No.21901039);the Natural Science Foundation of Jiangsu Province(No.BK20190327)。
Carboranes are a class of polyhedral boron-carbon molecular clusters,they can serve as versatile ligands in stabilizing low-valent main group element compounds,due to their exceptionally thermal and chemical stabiliti...
关键词：CARBORANE Borylene CARBENE SILYLENE Main group chemistry 
Thermal Energy-Driven Solid-State Molecular Rotation Monitored by Real-Time Emissive Color Switching被引量：3
《CCS Chemistry》2022年第8期2711-2723,共13页Junfeng Li Chenxi Hou Qi Qi Lin Jiao Lanqing Dai Dong Chen Haigang Geng Wen-Yong Lai Wei Huang 
support from National Natural Science Foundation of China(nos.21975130,21835003,21404059,21674050,91833304,and 21422402);the National Basic Research Program of China(nos.2017 YFB0404501 and 2014CB648300);the Natural Science Foundation of Jiangsu Province(no.BE2019120);the Six Talent Peaks Project of Jiangsu Province(no.TDXCL-009);the 333 Project of Jiangsu Province(no.BRA2017402);the Leading Talent of Technological Innovation of National Ten-Thousands Talents Program of China;the Excellent Scientific and Technological Innovative Teams of Jiangsu Higher Education Institutions(no.TJ217038);Scientific Research Foundation of Nanjing University of Posts&Telecommunications(no.NY219060);the Fundamental Research Funds for the Central Universities;the open research fund of Key Laboratory of MEMS of Ministry of Education,Southeast University and the Big Data Center of Southeast University.
Inspired by nature’s molecular machines,the scientific research on solid-state molecular rotors is of great interest yet remains largely unexplored.Herein,we report a unique example of a thermal energydriven stimuli-...
关键词：molecular machines molecular rotation CARBORANE twisted intramolecular charge transfer emission emissive color switching 
Excimer Formation of Perylene Bisimide Dyes within Stacking-Restrained Folda-Dimers:Insight into Anomalous Temperature Responsive Dual Fluorescence
《CCS Chemistry》2022年第6期1949-1960,共12页Congdi Shang Gang Wang Yu-Chen Wei Qingwei Jiang Ke Liu Meiling Zhang Yi-Yun Chen Xingmao Chang Fengyi Liu Shiwei Yin Pi-Tai Chou Yu Fang 
the Natural Science Foundation of China(nos.21820102005,21527802,and 21673133);China 111 project(no.B14041);Program for Changjiang Scholars and Innovative Research Team in University(no.IRT-14R33).
We have fabricated a new perylene bisimide(PBI)folda-dimer(BPBI-CB-1)by tethering two PBI moieties to the ortho-carbon positions of a carborane unit.The synthesized compound adopted distinct configurations in differen...
关键词：perylene bisimide folda-dimer intramolecular aggregation positive temperature effect carborane derivative 
Rational design for thermochromic luminescence in amorphous polystyrene films with bis-o-carborane-substituted enhanced conjugated molecule having aggregation-induced luminochromism
《Aggregate》2021年第5期171-178,共8页Keisuke Wada Kazushi Hashimoto Junki Ochi Kazuo Tanaka Yoshiki Chujo 
Nakatani Foundation;Ministry of Education,Culture,Sports,Science,and Technology,Japan for Scientific Research,Grant/Award Number:JP21H02001;ScientificResearch on Innovative Areas“New Polymeric Materials Based on Element-Blocks”,Grant/Award Numbers:No.2401,JP24102013。
We designed the triad molecule,bis-o-carborane-substituted bis(thienylethynyl)benzene,as a filler for realizing thermochromic luminescent behaviors based on conventional polymer films,such as polystyrene.From the opti...
关键词：CARBORANE LUMINESCENCE POLYSTYRENE THERMOCHROMISM 
N-Heterocyclic Carbenes with a Nido-C_(2)B_(9) Carborane Backbone被引量：1
《Chinese Journal of Chemistry》2021年第9期2410-2416,共7页Zhongzheng Cui Beining Wang Junxia Li Ronglin Pang Yanrui Kang Xu-Qiong Xiao 
support from the National Natural Science Foundation of China(Grant No.21771048);the Natural Science Foundation of Zhejiang Provinee(Grant No.LY17B010002).
The steric and electronic properties of A/-heterocyclic carbenes(NHCs)can be modified by the exocyclic substituents at the nitrogen atoms,by 1-3 atoms'replacements of the five-membered imidazolium skeleton and by the ...
关键词：CARBORANES nido-Carborane anion Carbene ligands Density functional calculations Gold 
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