Recent advances on carborane-based ligands in low-valent group 13 and group 14 elements chemistry  

作　　者：Hao Wang 

机构地区：[1]School of Chemistry and Chemical Engineering,Southeast University,Nanjing 211189,China

出　　处：《Chinese Chemical Letters》2022年第8期3672-3680,共9页中国化学快报（英文版）

基　　金：the National Natural Science Foundation of China(No.21901039);the Natural Science Foundation of Jiangsu Province(No.BK20190327)。

摘　　要：Carboranes are a class of polyhedral boron-carbon molecular clusters,they can serve as versatile ligands in stabilizing low-valent main group element compounds,due to their exceptionally thermal and chemical stabilities,easy modifications at the cage carbon vertices,as well as large spherical steric effects.These carborane-based ligands provide interesting opportunities for the synthesis of low-valent main group element compounds with novel structure and reactivity,which indeed enrich the chemistry of low-valent element main group compounds.This review summarizes the recent advances in the chemistry of lowvalent group 13 and group 14 element compounds supported by carborane-based ligands.Achievements and perspectives in this new and flourishing field are discussed in this review.

关 键 词：CARBORANE Borylene CARBENE SILYLENE Main group chemistry 

分 类 号：O641.4[理学—物理化学]