云南高校图书馆联盟文献共享服务平台- SILYLENE

SILYLENE: 作品数：12被引量：4H指数：2; 导出分析报告; 相关领域：理学更多>>; 相关作者：卢秀慧明静静王党生韩军锋廉贞霞更多>>; 相关机构：济南大学北京航空航天大学更多>>; 相关期刊：《Chinese Journal of Structural Chemistry》《Science China Chemistry》《Chinese Journal of Chemical Physics》《Chinese Journal of Chemistry》更多>>; 相关基金：国家自然科学基金国家重点基础研究发展计划更多>>

Generation,bonding and reactivity of transient zinc-substituted silylenes: 《Science China Chemistry》2024年第4期1256-1262,共7页Cheng Xu Thayalan Rajeshkumar Laurent Maron Xuebing Leng Yaofeng Chen; supported by the National Natural Science Foundation of China(21890721,21732007);the Shanghai Municipal Committee of Science and Technology;the Chinese Academy of Sciences President’s International Fellowship Initiative。; The metal-substituted silylenes are of high interest,as the theoretical studies indicated that the silylenes with electropositive substituents have a small ΔE_(S-T)(singlet-triplet energy gap)or even the ground-state...; 关键词：zinc complex SILYLENE C-C bond cleavage CYCLOADDITION DFT calculations

A silylene-stabilized distannavinylidene with a highly labile substituent: 《Science China Chemistry》2023年第12期3555-3561,共7页Zihao Qiao Ming Chen Zhenbo Mo; supported by the National Natural Science Foundation of China(22071124,22371130,22221002);the Frontiers Science Center for New Organic Matter at Nankai University(C029215001);the Fundamental Research Funds for the Central Universities(63206007);the Nankai University and Young Elite Scientists Sponsorship Program by Tianjin。; Vinylidene and its heavier analogues are fundamentally important in synthetic chemistry,but their stabilization and structural characterization remains extremely challenging.Herein we describe that the reduction of an...; 关键词：distannavinylidene SILYLENES stannacycles distannyne CARBORANES

Recent advances on carborane-based ligands in low-valent group 13 and group 14 elements chemistry: 《Chinese Chemical Letters》2022年第8期3672-3680,共9页Hao Wang; the National Natural Science Foundation of China(No.21901039);the Natural Science Foundation of Jiangsu Province(No.BK20190327)。; Carboranes are a class of polyhedral boron-carbon molecular clusters,they can serve as versatile ligands in stabilizing low-valent main group element compounds,due to their exceptionally thermal and chemical stabiliti...; 关键词：CARBORANE Borylene CARBENE SILYLENE Main group chemistry

Forging a Cage into a Chain:Stepwise Transformation of P_(4) by Silylenes to a Si_(3)P_(4) Motif: 《CCS Chemistry》2022年第6期1843-1849,共7页Xiaofei Sun Alexander Hinz Peter W.Roesky; supported by the Deutsche Forschungsgemeinschaft(DFG)[project no.470309834(Ro2008/21-1 and HI 2063/1-1)];the support by the state of Baden-Württemberg through bwHPC and DFG[grant no.INST 40/467-1 FUGG(JUSTUS cluster)].; We have discovered a route to access the longest low-valent molecular silaphospha-chain,a sevenmembered chain structure that incorporates three silicon and four phosphorus atoms by stepwise activation of white phospho...; 关键词：phosphorus P_(4)activation SILYLENE silicon main group synthesis

Ab initio Study on Formation Mechanism of Spiro-Si-Heterocyclic Ring Compound Involving Ge from H2Ge=Si： and Formaldehyde: 《Chinese Journal of Chemical Physics》2016年第2期193-198,I0001,共7页卢秀慧王党生明静静; H2Ge=Si： and its derivatives （X2Ge=Si：, X=H, Me, F, C1, Br, Ph, Ar, ...） are new species. Its cycloaddition reactions are new area for the study of silylene chemistry. The cycloaddition reaction mechanism of singl...; 关键词：H2Ge=Si： Four-membered Ge-heterocyclic ring silylene Spiro-Si-heterocyclicring compound Potential energy profile

Ab Initio Study of the Mechanism of Forming a Spiro-Si-heterocyclic Ring Compound Involving Ge from Cl_2Ge=Si:and Formaldehyde被引量：2: 《Chinese Journal of Structural Chemistry》2014年第9期1267-1274,共8页明静静韩军锋卢秀慧; supported by the National Natural Science Foundation of China(No.51102114); The X2Ge=Si：（X = H, Me, F, reaction is a new area for the study of silylene between singlet CI2Ge=Si： and formaldehyde CI, Br, Ph, At...） is a new species. Its cycloaddition chemistry. The mechanism of cycloaddit...; 关键词：CI2Ge=Si： four-membered Ge-heterocyclic ring silylene spiro-Si-heterocyclic ring compound potential energy profile

DFT Investigation on the Insertion Reaction of an Isocyanide into the(Silyl)(silylene)molybdenum Si-C Bond被引量：2: 《Chinese Journal of Structural Chemistry》2012年第4期473-478,共6页赵燕云程学礼李丽清李震; supported by the National Natural Science Foundation of China (No.11174215); The chemistry of silylene-transition-metal complexes LnM（=SiR2）SiR3 is one of the attractive synthetic targets in organometallic chemistry for such complexes are key intermediates in many transition metal-catalyzed ...; 关键词：（silyl）（silylene）molybdenum isocyanide insertion DFT electronic population PCM

Theoretical Study of the Mechanism of Cycloaddition Reaction between Silylene Silylene （H2Si=Si：） and Acetone: 《Chinese Journal of Chemistry》2012年第3期675-680,共6页汪智娜时乐义李永庆卢秀慧; The mechanism of the cycloaddition reaction between singlet silylene silylene （H2Si = Si：） and acetone has been investigated with the CCSD （T）//MP2/6-31 G＊ method, According to the potential energy profile, it c...; 关键词：silylene silylene （H2Si = Si：） cycloaddition reaction potential energy profile

Ab initio Study of Mechanism of Cycloaddition Reaction be- tween Germylene Silylene （H2Ge=Si：） and Acetone: 《Chinese Journal of Chemistry》2011年第9期1969-1974,共6页Lu, Xiuhui Han, Junfeng Li, Yongqing Wang, Zhina; The mechanism of the cycloaddition reaction between singlet germylene silylene （H2Ge =Si：） and acetone has been investigated with CCSD（T）/6-31G＊//MP2/6-31 G＊ method. From the potential energy profile, we could ...; 关键词：germylene silylene cycloacldition reaction potential energy surface

Ab Initio Study on the Mechanism of Cycloaddition Reaction between Silylene Carbene (H_2Si=C:) and Acetone被引量：2: 《Chinese Journal of Structural Chemistry》2010年第11期1618-1625,共8页卢秀慧向萍萍廉贞霞李永庆; The mechanism of cycloaddition reaction between singlet silylene carbene and acetone has been investigated with CCSD（T）//MP2/6-31G method. From the potential energy profile, it can be predicted that the reaction has...; 关键词：silylene carbine reaction mechanism potential energy surface

SILYLENE