SILYLENES

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Generation,bonding and reactivity of transient zinc-substituted silylenes
《Science China Chemistry》2024年第4期1256-1262,共7页Cheng Xu Thayalan Rajeshkumar Laurent Maron Xuebing Leng Yaofeng Chen 
supported by the National Natural Science Foundation of China(21890721,21732007);the Shanghai Municipal Committee of Science and Technology;the Chinese Academy of Sciences President’s International Fellowship Initiative。
The metal-substituted silylenes are of high interest,as the theoretical studies indicated that the silylenes with electropositive substituents have a small ΔE_(S-T)(singlet-triplet energy gap)or even the ground-state...
关键词：zinc complex SILYLENE C-C bond cleavage CYCLOADDITION DFT calculations 
A silylene-stabilized distannavinylidene with a highly labile substituent
《Science China Chemistry》2023年第12期3555-3561,共7页Zihao Qiao Ming Chen Zhenbo Mo 
supported by the National Natural Science Foundation of China(22071124,22371130,22221002);the Frontiers Science Center for New Organic Matter at Nankai University(C029215001);the Fundamental Research Funds for the Central Universities(63206007);the Nankai University and Young Elite Scientists Sponsorship Program by Tianjin。
Vinylidene and its heavier analogues are fundamentally important in synthetic chemistry,but their stabilization and structural characterization remains extremely challenging.Herein we describe that the reduction of an...
关键词：distannavinylidene SILYLENES stannacycles distannyne CARBORANES 
Forging a Cage into a Chain:Stepwise Transformation of P_(4) by Silylenes to a Si_(3)P_(4) Motif
《CCS Chemistry》2022年第6期1843-1849,共7页Xiaofei Sun Alexander Hinz Peter W.Roesky 
supported by the Deutsche Forschungsgemeinschaft(DFG)[project no.470309834(Ro2008/21-1 and HI 2063/1-1)];the support by the state of Baden-Württemberg through bwHPC and DFG[grant no.INST 40/467-1 FUGG(JUSTUS cluster)].
We have discovered a route to access the longest low-valent molecular silaphospha-chain,a sevenmembered chain structure that incorporates three silicon and four phosphorus atoms by stepwise activation of white phospho...
关键词：phosphorus P_(4)activation SILYLENE silicon main group synthesis 
Stripping off the Halogens: From Silylenes to Metal Silicides to Nanocarbons
《Chemical Research in Chinese Universities》2001年第z1期1-,共1页LIU ChaoShiuan 
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