云南高校图书馆联盟文献共享服务平台- CARBENE

CARBENE: 作品数：93被引量：50H指数：3; 导出分析报告; 相关作者：卢秀慧廉贞霞李永庆车昕蓝宇更多>>; 相关机构：济南大学重庆大学中山大学西南大学更多>>; 相关期刊：《Science China(Life Sciences)》《Science China Chemistry》《Chemical Research in Chinese Universities》《Chinese Journal of Catalysis》更多>>; 相关基金：国家自然科学基金国家重点基础研究发展计划中国博士后科学基金天津市自然科学基金更多>>

Organocatalytic radical aminoacylation of alkenes forβ-aminoketone synthesis: 《Science China Chemistry》2025年第3期1002-1008,共7页Ayisenbati Jialingbieke Xinying Hu Zuquan Liu Xiyun Lin Yiwen Yin Jibin Li Yatian Huang Ding Du; supported by the the National Natural Science Foundation of China (22371297)。; An NHC organocatalytic radical aminoacylation of alkenes has been developed by using aldehydes as the acylating reagents and activated aryloxy-amides as the N-radical precursors,providing a new platform for modular ac...; 关键词：difunctionalization of alkenes ORGANOCATALYSIS CARBENE radical relay AMINOACYLATION β-aminoketone synthesis

Emerging progress:photochemical transformation of nitroso compounds: 《Science China Chemistry》2025年第1期118-133,共16页Ze-Le Chen Qiang-Qiang Li Armido Studer Jun Xuan; supported by the National Natural Science Foundation of China(22301292,21971001);the Distinguished Young Research Project of Anhui Higher Education Institution(2023AH020003);Armido Studer thanks the Deutsche Forschungsgemeinschaft(DFG)for funding(STU 280/92-1)。; Nitroso compounds have emerged as highly valuable reaction partners or reagents in organic synthesis due to their rich reactivity.The versatile profile of these compounds allows them to function as electrophiles,nucle...; 关键词：nitroso compounds PHOTOCHEMISTRY radical reaction carbene transformation NITROSOARENES

Boosting CO_(2)Electroreduction by Preactivation Strategy over Carbene-Based Metal-Organic Framework: 《CCS Chemistry》2024年第12期3053-3064,共12页Zi-Yan Jing Duan-Hui Si Hui Guo Li-Li Han Rong Cao Yuan-Biao Huang; supported by the National Key Research and Development Program of China(grant nos.2023YFA1507904 and 2021YFA1501500);National Natural Science Foundation of China(grant nos.U22A20436,22071245,22220102005,and 22033008);Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China(grant no.2021ZZ103);Talent Plan of Shanghai Branch,Chinese Academy of Sciences(grant no.CASSHB-QNPD-2023-020);supported by the Open Science Promotion Plan 2023 of China Science and technology Cloud.The authors thank the Taiwan beamline BL-12B2 at SPring-8(Japan)and the beamline TPS 44A of the National Synchrotron Radiation Research Center for EXAFS measurements.; Developing nonmetallic active sites-based catalysts for efficient electrocatalytic CO_(2)reduction reaction(CO_(2)RR)remains challenging.Active N-heterocyclic carbenes(NHCs)as typical nonmetal catalysts have shown hig...; 关键词：metal-organic frameworks N-heterocyclic carbenes CO_(2)electrocatalysis UiO-66 CO

Recent Advances on the Synthesis and Application ofα,α-Difluoro-β-aminophosphonates: 《有机化学》2024年第12期3686-3701,共16页Du Youlong Wang Qian Mei Haiboa Pajkert Roman Röschenthaler Gerd-Volker Han Jianlin; 国家自然科学基金(No.21761132021)资助项目.; α,α-Difluoro-β-aminophosphonates can be looked as structural analogies withα-amino acids,which have attracted great attention in biological and medicinal chemistry during the past decades.Furthermore,these compoun...; 关键词：AMINOPHOSPHONATE α α-difluoro-β-aminophosphonate CARBENE diazo compound AMINE bioactive compound

Crystalline cyclic(alkyl)(amino)stannylene via transient stannyne: 《Science China Chemistry》2024年第12期4212-4217,共6页Xin-Feng Wang Chaopeng Hu Zhihao Lu Liu Leo Liu; supported by the National Natural Science Foundation of China(22350004,22101114,22271132);the ShenzhenScienceandTechnologyInnovationProgram(20231120110042001);the High Level of Special Funds(G03050K003);the Guangdong Innovation and Entrepreneurial Research Team Program(2021ZT09C278)。; We demonstrate that a bulky cyclic amino ligand,specifically 1,1,3,3-tetraphenylisoindolinyl,can facilitate the formation of a transient stannyne,endowed with adjacent ambiphilic carbon and tin centers.This stannyne,m...; 关键词：stannyne CARBENE ambiphilicity stannylene

Computational Insights into the Mechanism of the Mo-Catalyzed Deoxygenative Coupling of Aromatic Aldehydes: 《有机化学》2024年第11期3518-3525,共8页Qinghao Sun Xiaoguang Bao; 国家自然科学基金((No.22373073)资助项目。; Mo/o-quinone complexes have shown great capability in promoting deoxygenation of carbonyl groups in the presence of appropriate reducing agents,which yields key Mo-carbene complexes and subsequently undergoes further ...; 关键词：Mo catalysis deoxygenative coupling CARBENE reaction mechanism density functional theory(DFT)calculation

Who is Who in the Carbene Chemistry of N-Sulfonyl Hydrazones: 《Chinese Journal of Chemistry》2024年第17期2071-2108,共38页Paramasivam Sivaguru Yongzhen Pan Nan Wang Xihe Bi; the financial support from the National Natural Science Foundation of China(22331004)。; Over the past few decades,N-sulfonyl hydrazones have been recognized as alternative precursors for hazardous diazo compounds in organic synthesis,allowing for diverse innovative and original chemical transformations t...; 关键词：N-Sulfonyl hydrazones Carbene chemistry Cross-coupling Cycloaddition Asymmetric reactions

Structural insight into palladium-nickel clusters over mordenite zeolite for carbene-insertion reaction: 《Frontiers of Chemical Science and Engineering》2024年第9期89-99,共11页Guangchao Li Ping-Luen Baron Ho Bryan Kit Yue Ng Tai-Sing Wu Pawel Rymarz Shik Chi Edman Tsang; support from the Department of Applied Biology and Chemical Technology(PolyU P0049034);The synchrotron radiation experiments were performed at BL02B2 in SPring-8 with the approval of the Japan Synchrotron Radiation Research Institute(JASRI).; The advancement of heterogeneous catalysts incorporating metal clusters in the nanometric size range has garnered significant attention due to their extraordinary catalytic activity and selectivity.The detailed charac...; 关键词：ZEOLITE metal cluster synchrotron X-ray diffraction carbene-mediated reaction

Supramolecular polymer network constructed by a functionalized polyimidazolium salt derived from metal-carbene template approach被引量：1: 《Science China Chemistry》2024年第4期1224-1228,共5页Ming-Ming Gan Zi-En Zhang Yi-Fan Zhang Heng Zhang Li-Ying Sun Ying-Feng Han; supported by the National Natural Science Fund for Distinguished Young Scholars of China(22025107);Shaanxi Fundamental Science Research Project for Chemistry&Biology(22JHZ003);the National Youth Top-notch Talent Support Program of China;Xi’an Key Laboratory of Functional Supramolecular Structure and Materials;the FM&EM International Joint Laboratory of Northwest University。; In this study,we present a supramolecular templating approach for constructing polyimidazolium salt containing crown ether and cyclobutane moieties.This strategy involves the formation of metal-carbene templates,photo...; 关键词：metal-carbene template crown ether polyimidazolium salt host-guest chemistry

Rhodium-catalyzed Doyle-Kirmse rearrangement reactions of sulfoxoniun ylides: 《Chinese Chemical Letters》2024年第4期363-366,共4页Ying-Di Hao Zhi-Qian Lin Xiao-Yu Guo Jiao Liang Can-Kun Luo Qian-Tao Wang Li Guo Yong Wu; supported by Sichuan Science and Technology Program (No.2020YJ0221)。; Doyle-Kirmse rearrangement reactions have received continuous attention as an important method for constructing complex chemical structures. Herein, we disclosed an efficient rhodium-catalyzed DoyleKirmse rearrangemen...; 关键词：Sulfoxonium ylides Rhodium(Ⅱ)-catalyzed CARBENE Rearrangement reactions One-pot process

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