Rhodium-catalyzed Doyle-Kirmse rearrangement reactions of sulfoxoniun ylides  

作　　者：Ying-Di Hao Zhi-Qian Lin Xiao-Yu Guo Jiao Liang Can-Kun Luo Qian-Tao Wang Li Guo Yong Wu 

机构地区：[1]Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry and Department of Medicinal Chemistry,Sichuan Engineering Laboratory for Plant-Sourced Drug and Sichuan Research Center for Drug Precision Industrial Technology,West China School of Pharmacy,Sichuan University,Chengdu 610041,China

出　　处：《Chinese Chemical Letters》2024年第4期363-366,共4页中国化学快报（英文版）

基　　金：supported by Sichuan Science and Technology Program (No.2020YJ0221)。

摘　　要：Doyle-Kirmse rearrangement reactions have received continuous attention as an important method for constructing complex chemical structures. Herein, we disclosed an efficient rhodium-catalyzed DoyleKirmse rearrangement reaction, which can simultaneously construct C–C bonds and C–X(X = S/Se) bonds using sulfoxonium ylides as starting materials to obtain sulfur-or selenium-containing compounds. This strategy is characterized by the safer and greener carbene precursor, high yields and broad substrate scope, possessing a wide range of application.

关 键 词：Sulfoxonium ylides Rhodium(Ⅱ)-catalyzed CARBENE Rearrangement reactions One-pot process 

分 类 号：O621.251[理学—有机化学]