supported by the the National Natural Science Foundation of China (22371297)。
An NHC organocatalytic radical aminoacylation of alkenes has been developed by using aldehydes as the acylating reagents and activated aryloxy-amides as the N-radical precursors,providing a new platform for modular ac...
supported by the National Natural Science Foundation of China (22371057,32172459,32330087);the National Key Research and Development Program of China (2022YFD-1700300);the Science and Technology Department of Guizhou Province (Qiankehejichu-ZK (2021)Key033);the Frontiers Science Center for Asymmetric Synthesis and Medicinal Molecules,Department of Education,Guizhou Province (Qianjiaohe KY (2020)004);the Central Government Guides Local Science and Technology Development Fund Projects (Qiankehezhongyindi (2024)007, (2023)001);the Program of Major Scientific and Technological,Guizou Province (Qiankehechengguo (2024)zhongda007);the Program of Introducing Talents of Discipline to Universities of China (111 Program,D20023)at Guizhou University;the Yongjiang Plan for Innovation and Entrepreneurship Leading Talent Project in the City of Nanning (2021005);Guizhou University (China)。
N-heterocyclic carbene(NHC)organocatalytic reactions that have been developed for asymmetric construction of axial and planar chirality are systematically summarized and discussed in this review.The challenges and lim...
supported by the National Science Fund for Distinguished Young Scholars(No.T2225004);National Natural Science Foundation of China(No.52373092);Shccig-Qinling Program.
The alternating copolymer of CO_(2) with epoxide is a green plastic that can efficiently transform CO_(2) into valuable chemicals. Despite the significant advances made, the restricted practical application of CO_(2)-...
An organophosphoric acid catalyzed[3+3]cyclization of 2-arylidene-indan-1,3-diones with enaminones has been established,which afforded a series of structurally diverse indenoquinolinedione derivatives in moderate to e...
the National Natural Science Foundation of China(U22A20389);Foundation of WestlakeUniversity.
Chiralα-tertiary aminonitriles are valuable synthetic intermediates.They are also found in various structures of biologically active molecules.Therefore,numerous reports of catalytic asymmetric synthesis of chiralα-...
This work was financially supported by the National Natural Science Foundation of China(Nos.52022031 and 21734004).
Organocatalysis has shown special potency for simplifying the construction of complex polymer structures.We are reporting here a one-pot synthetic pathway using amine as a selectivity-switching agent in the two-compon...
supported by the Advanced Talents Incubation Program of Hebei University(521000981411);the National Nature Science Foundation of China(82273792),Science Research Project of Hebei Education Department(QN2021023);the Natural Science Interdisciplinary Research Program of Hebei_University(DXK201913);High-throughput Intelligent Integrated Lung Cancer Targeted Drug Development Innovation Team Project(IT2023c01);the Excellent Youth Research Innovation Team of Hebei University(QNTD202406).
An efficient and highly stereoselective synthetic method to access polycyclic chromanes has been achieved through organocatalyzed one-pot step-wise reactions involving 2-hydroxycinnamaldehydes,2-aminochalcones,and mal...
The authors gratefully acknowledge NSFC(grant nos.22222107,22171186);China Postdoctoral Science Foundation(2023M742365);Postdoctoral Fellowship Program of CPSF(GZC20231671);ShanghaiTech University start-up funding for financial support.Prof.Guangxin Liang was acknowledged for sharing the optical rotation polarimeter,and Mr.Huanchao Gu was acknowledged for the assistance with X-ray crystallographic analysis;support from Analytical Instrumentation Center(#SPST-AIC10112914),SPST,ShanghaiTech University.
Dibenzo[b,fi[1,5]diazocines are a class of eight-membered heterocycles,which exhibit unique rigid saddle-shaped structure and possess inherent chirality.In this study,we report a convenient and straightforward method ...
National Natural Science Foundation of China(Nos.22161008,22061003);Guangxi Science and Technology Base and Talent Project(High Level Innovative Talents and Team Training)(Guike No.AD23026094);Guangxi Natural Science Foundation of China(No.2021GXNSFFA220005)for financial support。
An efficient and scalable electrochemical asymmetric protocol with metal-free catalysts and even without additional oxidants for the cross-dehydrogenative coupling reaction(CDC)of two C(sp^(3))-H bonds is reported.A s...
Financial support was provided by the National Natural Science Foundation of China(grant nos.22222109,21921002,22101189,21897002,and 31972290);the Beijing National Laboratory for Molecular Sciences(grant no.BNLMS202101);the Natural Science Foundation of Sichuan Province(grant nos.2023NSFSC1921,2022NSFSC1181,and 24NSFSC6590);the Fundamental Research Funds from Sichuan University(grant no.2020SCUNL108);the Fundamental Research Funds for the Central Universities.
Chiral quaternary phosphonium ion-pair catalysis showcases a distinctive catalytic and stereoinductive mode arising from the synergy between ionic and noncovalent interactions.Over recent decades,this methodology has ...