ENANTIOSELECTIVITY

作品数：143被引量：108H指数：4
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相关领域：理学更多>>
相关作者：陈慧文岳中刘维屏更多>>
相关机构：浙江大学更多>>
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相关基金：国家自然科学基金国家重点基础研究发展计划湖北省自然科学基金江苏省杰出青年基金更多>>
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Chiral supramolecular catalysts of helical nanoribbon:More twist,higher enantioselectivity
《Chinese Chemical Letters》2025年第3期259-262,共4页Cong Gao Zijian Zhu Siwei Li Zheng Xi Qingqing Sun Jie Han Rong Guo 
support of this research by the National Natural Science Foundation of China(Nos.22202171,21922202,and 22272146);the Natural Science Foundation of Jiangsu Basic Research Program(No.BK20220559);the Natural Science Foundation of the Higher Education Institutions of Jiangsu Province(No.22KJD150009);the Jiangsu Specially-Appointed Professor Plan(Z.Xi)from the Jiangsu Education Department。
Rational tuning of chiral nanostructures of supramolecular assemblies as catalysts and investigating their chiral morphology-enantioselectivity dependence is rarely reported. Herein, we report a series of supramolecul...
关键词：Chiral supramolecular catalyst Helical nanoribbon Screw pitch ENANTIOSELECTIVITY Diels-Alder reaction 
Modular Access to Chiral 1,3-Substituted Fragments via Nickel-Catalyzed Arylboration Reaction
《Chinese Journal of Chemistry》2025年第3期261-267,共7页Yang Bao Tong Yao Weiyu Kong Yangyang Li Ying Fu Dong Wu Guoyin Yin 
supported by Guangdong Basic and Applied Basic Research Foundation(2024A1515011689).
Chiral 1,3-substituted fragments are ubiquitous in pharmaceutical molecules and natural products,prompting the development of numerous methods to access these structures.Nonetheless,devising synthetic routes for compl...
关键词：ALKENES Nickel Chiral 1 3-bis(boronates) Chain-walking Carboboration ENANTIOSELECTIVITY 
Synergistic BrΦnsted/Lewis acid catalyzed atroposelective synthesis of aryl-β-naphthol
《Chinese Chemical Letters》2025年第1期293-298,共6页Jiajun Lu Zhehui Liao Tongxiang Cao Shifa Zhu 
financial support from the National Natural Science Foundation of China(Nos.22071062,22001077 and 22271096);Guangdong Science and Technology Department(Nos.2021A1515012331,2023A1515011001);the Fundamental Research Funds for the Central Universities(No.2022ZYGXZR016);South China University of Technology for start-up funds。
Axially chiral binaphthol have achieved great success in asymmetric catalysis.Compared toα-binaphthol,axially chiral aryl-β-naphthol are far less reported.Here,we report a method of asymmetric catalysis to construct...
关键词：Synergistic catalysis ATROPISOMERISM Aryl-β-naphthol ENANTIOSELECTIVITY Tandem reaction 
Asymmetric Synthesis of Chiral Aliphaticα-Tertiary Aminonitriles via Organocatalytic Isomerization of Cyanoketimines
《Chinese Journal of Chemistry》2024年第24期3387-3392,共6页Ling Xu Jisheng Luo Li Deng 
the National Natural Science Foundation of China(U22A20389);Foundation of WestlakeUniversity.
Chiralα-tertiary aminonitriles are valuable synthetic intermediates.They are also found in various structures of biologically active molecules.Therefore,numerous reports of catalytic asymmetric synthesis of chiralα-...
关键词：ISOMERIZATION AMINONITRILES Cyanoketimine PROTONATION ORGANOCATALYSIS ENANTIOSELECTIVITY 
Chiral fluorescent sensor Tb^(3+)@Cd‑CP based on camphoric acid for the enantioselective recognition of R‑and S‑propylene glycol
《无机化学学报》2024年第12期2497-2504,共8页LI Junying CHEN Xinyan DIAO Xihui Yaseen Muhammad CHEN Chao WANG Hao QI Chuansong LI Wei 
北京市自然科学基金(No.2212006)资助。
Herein,a layered chiral coordination polymer,[Cd2(D‑cam)_(2)(2,2′‑bipy)_(2)]_(n)(Cd‑CP),was synthesized using a solvothermal method with camphoric acid(D‑H_(2)cam),2,2′‑bipyridine(2,2′‑bipy)and Cd^(2+),and Tb^(3+)@...
关键词：camphoric acid coordination polymer ENANTIOSELECTIVITY propylene glycol 
Earth-Abundant Nickel-Catalyzed Asymmetric Hydrogenation
《Chinese Journal of Chemistry》2024年第23期3135-3156,共22页Peng Wang Zhao-Lin He Zi-Fei Xia Jun Wei Xiu-Qin Dong 
financial support from National Natural Science Foundation of China(22071187,22271226);Natural Science Foundation of Hubei Province(2021CFA069);National Youth Talent Support Program。
Transition metal-catalyzed asymmetric hydrogenation is an efficient and direct synthetic method to access chiral compounds,which features simplicity,easy working-up process,and high atomic economy.It typically relies ...
关键词：Transition metal Nickel HYDROGENATION ENANTIOSELECTIVITY Asymmetric catalysis Earth-abundant metal 
Palladium-catalyzed enantioselective decarboxylation of vinyl cyclic carbamates:Generation of amide-based aza-1,3-dipoles and application to asymmetric 1,3-dipolar cycloaddition
《Chinese Chemical Letters》2024年第12期454-461,共8页Xiaohui Fu Yanping Zhang Juan Liao Zhen-Hua Wang Yong You Jian-Qiang Zhao Mingqiang Zhou Wei-Cheng Yuan 
the National Natural Science Foundation of China(Nos.22271027,22171029,21901024,21871252,21801024,and 21801026);the Sichuan Science and Technology Program(No.2021YFS0315);the Talent Program of Chengdu University(Nos.2081919035 and 2081921038)。
The catalytic asymmetric dipolar cycloaddition reaction is efficient for the construction of various chiral valuable carbo-and heterocycles.Thus,the design and exploration of new dipoles and the subsequent control of ...
关键词：CYCLOADDITION Palladium ENANTIOSELECTIVITY Asymmetric catalysis DECARBOXYLATION 
Rhodium-Catalyzed Asymmetric Hydrogenation of Tetrasubstitutedα,β-Unsaturated Amides:Efficient Access to Chiralβ-Amino Amides
《Chinese Journal of Chemistry》2024年第21期2641-2646,共6页Bing Jiao Fangyuan Wang Hui Lv 
financial support from the National Natural Science Foundation of China(Grant Nos.22071188,22371217);Hubei Provincial Natural Science Foundation of China(2023AFA011).
The first asymmetric hydrogenation of acyclic tetrasubstitutedα,β-unsaturated amides has been achieved by using Rh/DuanPhos complex as a catalyst,delivering chiralβ-amino amides with two contiguous chiral centers i...
关键词：Asymmetric hydrogenation β-Amino amides Asymmetric catalysis Contiguous chiral centers RHODIUM AMINES Reduction ENANTIOSELECTIVITY 
Construction of Planar Chiral Ferrocenes by Cobalt-Catalyzed Enantioselective C–H Acyloxylation Enabled by Dual Ligands
《CCS Chemistry》2024年第11期2783-2793,共11页Fan-Rui Huang Peng Zhang Qi-Jun Yao Bing-Feng Shi 
supported by the National Key R&D Program of China(grant nos.2021YFF0701603 and 2022YFA1504302);the National Natural Science Foundation of China(grant nos.21925109,U22A20388,and 92256302);the Fundamental Research Funds for the Central Universities(grant nos.226-2023-00115 and 226-2022-00224);the College of Material Chemistry and Chemical Engineering,Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education,Hangzhou Normal University(grant no.KFJJ2023003).
Oxy-substituted planar chiral ferrocenes are of great importance in asymmetric synthesis and pharmaceuticals.However,enantioselective C–H activation of ferrocenes that form C–O bonds remains a huge challenge and has...
关键词：C–H acyloxylation COBALT dehydrogenative coupling ENANTIOSELECTIVITY FERROCENES 
Construction of Acyclic Quaternary Carbon Stereocenters via Enantioselective Nickel Catalysis
《Chinese Journal of Chemistry》2024年第20期2485-2498,共14页Jian Song Xuening Li Jinguo Long Hua Yang Xianjie Fang 
National Natural Science Foundation of China(Nos.22278265,U22B20137);Zhejiang Provincial Natural Science Foundation of China(No.LR24B020002);the start-up funding from Hangzhou Normal University(No.4095C50222204165);support.J.S.thanks the Natural Science Foundation of Hunan Province(2024JJ6485);support.J.L.thanks the National Natural Science Foundation of China(22302063);China Postdoctoral Science Foundation(2022M721086);the Natural Science Foundation of Hunan Province(2023JJ40124)for financial support.
The construction of acyclic quaternary carbon stereocenters,which are ubiquitous in many bioactive compounds,pharmaceuticals and natural products,has been a long persuit in synthetic organic chemistry.Among numerous m...
关键词：Nickel catalysis ENANTIOSELECTIVITY ALKENES ACYCLIC Quaternary carbon stereocenters Asymmetric catalysis CROSS-COUPLING Chirality 
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