HYDROGENATION

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Unveiling the mechanism of selective CO_(2)hydrogenation to CO on amorphous black TiO_(X)in thermal and photo-assisted thermal catalysis:The role of defects in amorphous structure and light irradiation
《Nano Research》2025年第3期106-122,共17页Mohammad Fereidooni Mohammad Yazdanpanah Victor Márquez C.V.Paz Martin Salazar Villanueva Supareak Praserthdam Piyasan Praserthdam 
supported by the Second Century Fund(C2F)of Chulalongkorn University,Thailand.
Developing catalysts capable of efficiently utilizing both visible and near-infrared wavelengths of the solar spectrum for CO_(2)hydrogenation has led to growing interest in reduced TiO_(2)materials.Achieving efficien...
关键词：oxygen vacancy AMORPHOUS catalytic CO_(2)hydrogenation hydrogen mobility photo-thermal reaction mechanism analysis 
Hydrogen-Induced Phase Transition and Emergent Properties in SrFeO_(x)
《Chinese Physics Letters》2025年第3期118-130,共13页Ming-Tong Zhu Lu Wang Lei Gao Jin Liu Xiang-Yu Lyu Yu-Qian Wang Chao Lu Meng-Cheng Li Peng-Yu Liu Jia-Yi Song Hua-Yu Tao Ben-Bo Zhao Ai-Ling Ji Ze-Xian Cao Nian-Peng Lu 
supported by the National Key R&D Program of China(Grant Nos.2022YFA1403000 and 2024YFA1408302);the CAS Project for Young Scientists in Basic Research(Grant No.YSBR-047);the Strategic Priority Research Program of the Chinese Academy of Sciences of China(Grant No.XDB33000000)。
In recent years,ionic modulation,particularly hydrogen intercalation,has gained attention as a powerful method for tuning the properties of materials.Although the SrFeO_(x)system is similar to SrCoO_(x),which can be p...
关键词：PEROVSKITE HYDROGENATION TRANSITION 
Tailored design of novel Co^(0)-Co^(δ+)dual phase nanoparticles for selective CO_(2) hydrogenation to ethanol
《Journal of Environmental Sciences》2025年第3期598-615,共18页Subhasis Das Ganapati D.Yadav 
Catalytic hydrogenation of CO_(2)to ethanol is a promising solution to address the greenhouse gas(GHG)emissions,but many current catalysts face efficiency and cost challenges.Cobalt based catalysts are frequently exam...
关键词：CO_(2)hydrogenation ETHANOL Co-based catalysts Metal support ineraction DFT analysis 
Quantitative in situ Raman monitoring of formation of abundant formate during the hydrogenation of carbon dioxide
《Science Bulletin》2025年第4期500-503,共4页Shichuan Xi Ruifang Huang Zhendong Luan Zengfeng Du Lianfu Li Guozhi Xie Weidong Sun Xin Zhang 
supported by the Strategic Priority Research Program,CAS(XDA22050100);the National Natural Science Foundation of China(41873069 and 42206190);the Young Taishan Scholars Program(tsqn201909158);the National Key R&D Program of China(2023YFF0807101);Shenzhen Municipal Natural Science Foundation(JCYJ20220530113016038);the Key Programs of Guangzhou Nansha District Science and Technology Bureau(2023ZD018).
On the Hadean Earth immediately after the Magma Ocean period,the proto-atmosphere mainly consists of water(H2O),carbon dioxide(CO_(2)),and nitrogen(N2)[[1],[2],[3],[4]].Meanwhile,Earth’s surface was covered by ultram...
关键词：dioxide HYDROGENATION CARBON 
Solar-powered methanol synthesis from CO_(2) hydrogenation with high conversion and selectivity
《Science China Chemistry》2025年第2期513-519,共7页Lingzhen Zeng Yongfang Sun Tingting Wang Zeyan Cen Maolin Wang Oriol Angurell Meng Wang Ding Ma 
supported by National Key R&D Program of China(2022YFE0114900);New Cornerstone Science Foundation,it has also received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No 101022202.D.M.acknowledges support from the Tencent Foundation through the XPLORER PRIZE.Zeng would like to express gratitude to the China Postdoctoral Science Foundation(2021M700209,2024T170015)。
Methanol synthesis via CO_(2) hydrogenation stands as a pivotal avenue for CO_(2) conversion and fixation,garnering extensive investigation.Diverse reactor configurations and energy supplies,alongside a spectrum of ca...
关键词：CO_(2) hydrogenation PHOTOTHERMAL methanol synthesis 
Theoretical Study on CO_(2)Hydrogenation on In_(2)O_(3)(111)Supported Single-Atom Catalysts:Horiuti-Polanyi versus Non-Horiuti-Polanyi Mechanism
《Chinese Journal of Chemical Physics》2025年第1期54-62,I0055,I0056,共11页Xiang Li Gang Fu 
supported by the National Key Research and Development Program of Ministry of Sci-ence and Technology of China(No.2022YFA1504601);the National Natural Science Foundation of China(Nos.92045303,22132004,22121001,22072116,22072117,and 21773192).
In the field of catalytic hydro-genation,two primary mecha-nistic pathways,namely the Ho-riuti-Polanyi(HP)mechanism and the non-HP mechanism,have been extensively investi-gated.Current understandings suggested that th...
关键词：Reduced single-atom catalysts CO_(2)hydrogenation Density functional theory calculation Heterolytic dissociation of H_(2) Molecular adsorption of H_(2) 
Room temperature aqueous-phase hydrogenation coupling with green hydrogen: Sustainable technologies innovating by efficient Co-CoO_(x)@NC catalyst derived from N-induced interfacial electron rearrangement
《Nano Research》2025年第2期141-152,共12页Yue Shen Chun Chen Zidan Zou Wenchao Li Yunxia Zhang Haimin Zhang Zhixin Yu Huijun Zhao Guozhong Wang 
This work was financially supported by the National Natural Science Foundation of China(Nos.52072371 and 51871209);Key Technologies Research and Development Program of Anhui Province(No.202004a06020056);Special Foundation of President of HFIPS(No.YZJJ202102),HFIPS Director’s Fund(Nos.GGZX GTCX-2023-07 and YZJJ-GGZX-2022-01);HFIPS Director’s Fund(No.2023YZGH05).
Utilization and storage are the two main themes of green hydrogen.In hydrogen-involved system,development of highly active catalysts to achieve catalytic hydrogenation under mild conditions is a prerequisite for coupl...
关键词：green hydrogen N-DOPING dual active sites interface HYDROGENATION 
Synthesis of methanol via CO_(2) hydrogenation catalyzed by La_(2)O_(2)CO_(3)/Cu catalysts
《Nano Research》2025年第2期153-163,共11页Jun He Chenglong Yu Zhijuan Zhao Bo Guan Bin Zhang Yanru Zhang Longbo Zhang Yanyan Wang Ying Wang Yahui Wu Jia Guo Yang Li Tianbin Wu Qingli Qian Hongxing Wang Buxing Han 
The work was financially supported by the National Key Research and Development Program of China(No.2024YFE0206500);the National Science Foundation of China(Nos.22033009,22072156,22073104 and 22121002).
The development of efficient Cu-based heterogeneous catalysts for CO_(2) hydrogenation to methanol has been an appealing subject.Inspired by the concept of inverse catalysts,a series of La_(2)O_(2)CO_(3)/Cu nanorod co...
关键词：CO_(2)hydrogenation METHANOL heterogeneous catalysts Cu-La_(2)O_(2)CO_(3)(LOC)interaction 
Exploring catalyst developments in heterogeneous CO_(2) hydrogenation to methanol and ethanol:A journey through reaction pathways
《Journal of Energy Chemistry》2025年第2期345-384,I0008,共41页Rasoul Salami Yimin Zeng Xue Han Sohrab Rohani Ying Zheng 
the Canadian NRCan OERD Energy Innovation Program;the Natural Sciences and Engineering Research Council of Canada,and the Carbon Solution Program for their financial support.
The pursuit of alternative fuel generation technologies has gained momentum due to the diminishing reserves of fossil fuels and global warming from increased CO_(2)emission.Among the proposed methods,the hydrogenation...
关键词：CO_(2)hydrogenation METHANOL ETHANOL Catalytic mechanism Operando techniques Single atom catalyst Tandem catalyst 
Enhanced methanol production from photothermal CO_(2) reduction via multilevel interface design
《Nano Research》2025年第2期235-241,共7页Hongmin Wang Bo Shang Chungseok Choi Sungho Jeon Yuanzuo Gao Tyler Wang Nia J.Harmon Mengxia Liu Eric A.Stach Hailiang Wang 
Photothermal CO_(2) hydrogenation is a promising route to produce methanol as a sustainable liquid solar fuel.However,most existing catalysts require a combination of solar irradiation and additional heat input to ach...
关键词：photothermal catalysis CO_(2)hydrogenation methanol production solar fuel multilevel interface Cu/ZnO/Al_(2)O_(3)(CZA)catalyst 
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