supported by the National Natural Science Foundation of China(Nos.22425107,92461303,22371140,and 92161102(Z.-M.S.))and(No.22301143(L.Q.)).
The reactions of K_(5)Pn_(4)(Pn=Sb and Bi)and CpRh(PPh_(3))_(2)(Cp=C_(5)H_(5),cyclopentadiene)in ethylenediamine(en)solutions resulted in a series of new Pn_(7)^(3−)−adducts,{Pn_(8)[Rh(PPh_(3))]_(2)}^(2−),{Sb_(7)[Rh(P...
The steam reforming of bio-oil can provide a sustainable means to produce hydrogen,while tar steam reforming can significantly enhance the efficiency of the biomass gasification process.Bio-oils and tars are highly co...
supported by the financial aid from National Science and Technology Major Project of China(No.2020YFE0204500);National Natural Science Foundation of China(Nos.22020102003,22025506 and 11975301);Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.2020286)。
The three-way catalyst(TWC),as a promising approach to control automobile exhaust emission,has been widely studied and applied.However,it still suffers from the high light-off temperature and poor stability.Herein,we ...
Natural Science Foundation of China(Grant No.NSFC-22072062,22202098)。
Designing highly active and stable electrocatalysts of oxygen evolution reaction(OER)is one of the crucial challenges.In this study,a novel OER electrocatalyst,NiFe-MIL-53 modified with ultra-low rhodium(Rh@NiFe-MIL-5...
supported by the National Natural Science Foun-dation of China(22125502,22071207,22121001,21971217 and 22272133);the Fundamental Research Funds for the Central Universities(20720220011,20720240053 and 20720240070).
Heterogeneous catalysts for parahydrogen-induced polarization(HET-PHIP)would be useful for producing highly sensitive contrasting agents for magnetic resonance imaging(MRI)in the liquid phase,as they can be removed by...
In the search for new drugs with more efficient active ingredients, various transition metals are being explored as potential metallopharmaceuticals. These compounds, which combine drugs with metals, have shown promis...
financial support from the National Natural Science Foundation of China(Grant Nos.22071188,22371217);Hubei Provincial Natural Science Foundation of China(2023AFA011).
The first asymmetric hydrogenation of acyclic tetrasubstitutedα,β-unsaturated amides has been achieved by using Rh/DuanPhos complex as a catalyst,delivering chiralβ-amino amides with two contiguous chiral centers i...
financial support from the National Key R&D Program of China(No.2022YFF1202600);the National Natural Science Foundation of China(Nos.22001172,22071155,and22371188);the Science and Technology Commission of Shanghai Municipality(Nos.20XD1403600 and 20400750300);the Shanghai Municipal Education Commission(No.2019-01-07-00-10-E00072);the Innovation Team and Talents Cultivation Program of National Administration of Traditional Chinese Medicine(No.ZYYCXTD-202004);the Shanghai Municipal Health Commission/Shanghai Municipal Administration of Traditional Chinese Medicine[No.ZY(2021-2023)-0501];Organizational Key R&D Program of SHUTCM(No.2023YZZ01)。
A rhodium(Ⅲ)-catalyzed hydrosilylation/cyclization reaction of cyclohexadienone-tetheredα,β-unsaturated aldehydes(1,6-dienes)with triethylsilane is described,providing a series of cishydrobenzofurans,cis-hydroindol...