RHODIUM

作品数:162被引量:179H指数:7
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相关领域:理学更多>>
相关作者:王佰全李存耀丁云杰姜淼刘佳更多>>
相关机构:南开大学中国科学院大学中国科学院华东师范大学更多>>
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相关基金:国家自然科学基金国家重点基础研究发展计划中国博士后科学基金国家高技术研究发展计划更多>>
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New deltahedral architectures of rhodium-mediated Pn_(7)^(3−)(Pn=Sb and Bi)cages
《Nano Research》2025年第3期666-673,共8页Lei Qiao Chuan-Ling Chen Zhong-Ming Sun 
supported by the National Natural Science Foundation of China(Nos.22425107,92461303,22371140,and 92161102(Z.-M.S.))and(No.22301143(L.Q.)).
The reactions of K_(5)Pn_(4)(Pn=Sb and Bi)and CpRh(PPh_(3))_(2)(Cp=C_(5)H_(5),cyclopentadiene)in ethylenediamine(en)solutions resulted in a series of new Pn_(7)^(3−)−adducts,{Pn_(8)[Rh(PPh_(3))]_(2)}^(2−),{Sb_(7)[Rh(P...
关键词:group 15 clusters heterometallic clusters nanoclusters-based materials electronic structures coordination modes 
Comparative analysis of aromatic compounds steam reforming over Rh supported onγ-Al_(2)O_(3)
《Frontiers of Chemical Science and Engineering》2025年第3期51-68,共18页Marinela D.Zhurka Panagiotis N.Kechagiopoulos 
The steam reforming of bio-oil can provide a sustainable means to produce hydrogen,while tar steam reforming can significantly enhance the efficiency of the biomass gasification process.Bio-oils and tars are highly co...
关键词:HYDROQUINONE benzyl alcohol TOLUENE steam reforming hydrogen production RHODIUM 
卓尔不凡铑神剑信号线Supra Cables Sword Excalibur Rhodium ISL
《家庭影院技术》2025年第2期37-37,共1页Ball 
分别动用彩色纸箱和黑色木盒进行包装,突显高人一等身份的Sword Excalibur Rhodium ISL(铑神剑)信号线,属于瑞%典Supra Cables(苏霸)最新面世的旗舰级杰作,其软硬适中8mm水晶蓝色聚氯乙烯透明线身,使用时倍觉得心应手。制造工艺方面,每...
关键词:信号线 磁场干扰 聚酯膜 集肤效应 铜导体 软硬适中 卓尔不凡 制造工艺 
Investigation on Cu promotion effect on Ce-based solid solution-anchored Rh single atoms for three-way catalysis
《Chinese Chemical Letters》2025年第2期546-550,共5页Jianing He Xiao Wang Zijian Wang Ruize Jiang Ke Wang Rui Zhang Huilin Wang Baokang Geng Hongyi Gao Shuyan Song Hongjie Zhang 
supported by the financial aid from National Science and Technology Major Project of China(No.2020YFE0204500);National Natural Science Foundation of China(Nos.22020102003,22025506 and 11975301);Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.2020286)。
The three-way catalyst(TWC),as a promising approach to control automobile exhaust emission,has been widely studied and applied.However,it still suffers from the high light-off temperature and poor stability.Herein,we ...
关键词:Three-way catalysts(TWC) Solid solution CO-PRECIPITATION Rhodium(Rh)catalyst Oxygen vacancies 
Deciphering the role of ultra-low-loaded rhodium in NiFe-MIL-53 for superior oxygen evolution reaction
《Journal of Energy Chemistry》2025年第1期77-86,共10页Jinzhi Jia Jinhua Zhang Kailu Guo Lanyue Zhang Gening Du Hao You Junfeng Huang Mudong Tu Hua Li Yong Peng Wei Dou Cailing Xu 
Natural Science Foundation of China(Grant No.NSFC-22072062,22202098)。
Designing highly active and stable electrocatalysts of oxygen evolution reaction(OER)is one of the crucial challenges.In this study,a novel OER electrocatalyst,NiFe-MIL-53 modified with ultra-low rhodium(Rh@NiFe-MIL-5...
关键词:NiFe-MIL-53 RH Electrochemical reconstruction Catalytic mechanism Oxygen evolution reaction 
Tailoring rhodium-based metal-organic layers for parahydrogen-induced polarization:achieving 20%polarization of^(1)H in liquid phase
《National Science Review》2025年第1期247-258,共12页Jiawei Chen Qi Zhang Tao Chen Zeyu Zheng Yuhang Song Huichong Liu Ziqiao Chen Jing Wang Haoshang Wang Huijun Sun Xinchang Wang Zhong Chen Cheng Wang Zhongqun Tian 
supported by the National Natural Science Foun-dation of China(22125502,22071207,22121001,21971217 and 22272133);the Fundamental Research Funds for the Central Universities(20720220011,20720240053 and 20720240070).
Heterogeneous catalysts for parahydrogen-induced polarization(HET-PHIP)would be useful for producing highly sensitive contrasting agents for magnetic resonance imaging(MRI)in the liquid phase,as they can be removed by...
关键词:metal-organic layers heterogeneous catalysts parahydrogen-induced polarization HYPERPOLARIZATION nuclear magnetic resonance 
卓尔不凡铑神剑信号线 Supra Cables Sword Excalibur Rhodium ISL
《视听前线》2025年第1期56-56,共1页
分别采用彩色纸箱和黑色木盒进行包装、突显高端产品身份的Sword Excalibur Rhodium ISL铐神剑信号线,属于瑞典苏霸Supra Cables最新面世的旗舰级杰作。其软硬适中8mm水晶蓝聚氯乙烯透明线身,用户使用时倍感得心应手。制作上,每条Sword ...
关键词:磁场干扰 神剑 集肤效应 信号线 软硬适中 铜导体 卓尔不凡 旗舰级 
Synthesis, Characterization, and Cell Viability Evaluation of Coordination Compounds with Rhodium(III) Ion and Nitrogen-Containing Heterocyclic Ligands
《Advances in Biological Chemistry》2025年第1期1-17,共17页Vanessa Souza da Silva Rans Miler Pereira Dantas Maria José Santos Mesquita Bruna Alves Rodrigues Sara Cristina Bernardes Correia Dayanne Oliveira da Silva Mendes Aron Carlos de Melo Cotrim Joyce Laura da Silva Gonçalves Wagner Batista dos Santos 
In the search for new drugs with more efficient active ingredients, various transition metals are being explored as potential metallopharmaceuticals. These compounds, which combine drugs with metals, have shown promis...
关键词:RHODIUM N-Heterocyclics 4 4-Met-2 2-Bipyridine ISONICOTINAMIDE 3-Pina Metallopharmaceuticals Thermoanalytics 
Rhodium-Catalyzed Asymmetric Hydrogenation of Tetrasubstitutedα,β-Unsaturated Amides:Efficient Access to Chiralβ-Amino Amides
《Chinese Journal of Chemistry》2024年第21期2641-2646,共6页Bing Jiao Fangyuan Wang Hui Lv 
financial support from the National Natural Science Foundation of China(Grant Nos.22071188,22371217);Hubei Provincial Natural Science Foundation of China(2023AFA011).
The first asymmetric hydrogenation of acyclic tetrasubstitutedα,β-unsaturated amides has been achieved by using Rh/DuanPhos complex as a catalyst,delivering chiralβ-amino amides with two contiguous chiral centers i...
关键词:Asymmetric hydrogenation β-Amino amides Asymmetric catalysis Contiguous chiral centers RHODIUM AMINES Reduction ENANTIOSELECTIVITY 
Rhodium(Ⅲ)-catalyzed diastereo-and enantioselective hydrosilylation/cyclization reaction of cyclohexadienone-tetheredα,β-unsaturated aldehydes
《Chinese Chemical Letters》2024年第9期160-164,共5页Yi-Fan Wang Hao-Yun Yu Hao Xu Ya-Jie Wang Xiaodi Yang Yu-Hui Wang Ping Tian Guo-Qiang Lin 
financial support from the National Key R&D Program of China(No.2022YFF1202600);the National Natural Science Foundation of China(Nos.22001172,22071155,and22371188);the Science and Technology Commission of Shanghai Municipality(Nos.20XD1403600 and 20400750300);the Shanghai Municipal Education Commission(No.2019-01-07-00-10-E00072);the Innovation Team and Talents Cultivation Program of National Administration of Traditional Chinese Medicine(No.ZYYCXTD-202004);the Shanghai Municipal Health Commission/Shanghai Municipal Administration of Traditional Chinese Medicine[No.ZY(2021-2023)-0501];Organizational Key R&D Program of SHUTCM(No.2023YZZ01)。
A rhodium(Ⅲ)-catalyzed hydrosilylation/cyclization reaction of cyclohexadienone-tetheredα,β-unsaturated aldehydes(1,6-dienes)with triethylsilane is described,providing a series of cishydrobenzofurans,cis-hydroindol...
关键词:Rhodium(Ⅲ)catalysis Hydrosilylation/cyclization 1 6-Dienes Silyl enol ether Diastereo-and enantioselectivity 
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