An organophosphoric acid catalyzed[3+3]cyclization of 2-arylidene-indan-1,3-diones with enaminones has been established,which afforded a series of structurally diverse indenoquinolinedione derivatives in moderate to e...
financially supported by National Natural Science Foundation of China(No.22161022)。
The new reactions between o-hydroxyphenyl enaminones and Langlois reagent(CF_(3)SO_(2)Na)for the tunable synthesis of 3-(trifluoromethylthio)chromones and 3-trifluoromethylsulfinyl chromones are reported herein.Both t...
the Science and Technology Foundation of Henan Province(222102310580);Innovation and Entrepreneurship Training Program for College Students;Henan University of Science and Technology(2023180).
Chemodivergent synthesis of benzofurans and 2,3-dihydrobenzofurans has been realized.Under a reaction system consisting of DBDMH and K_(2)CO_(3) as promotors,controlled conditions enabled the formation of two sets of ...
the National Natural Science Foundation of China(No.21702088);the Natural Science Foundation of Shandong Province(No.ZR2022MB130)for the financial support.
Enaminones,which possesses both the nucleophilic enamine as well as electrophilic enone structures,are well known versatile building blocks in organic synthesis.Meanwhile,visible light-mediated reactions have emerged ...
financially supported by the National Natural Science Foundation of China (No.21861019);Natural Science Foundation of Jiangxi Province (No.20202ACBL203006)。
The selective synthesis of N^(2)-sulfonyl and N^(2)-H 1,2,3-triazoles via organocatalytic annulation of enaminone/enaminoester with sulfonyl azide has been realized. The unconventional selectivity providing N^(2)-sulf...
financially supported by National Natural Science Foundation of China(No.21861019);Natural Science Foundation of Jiangxi Province(No.20202ACBL203006).
The perfluoroalkylsulfonylation(CF_(3)SO_(2),C_(2)F_(5)SO_(2)and CHF_(2)SO_(2))in the enaminone C-H bonds has been developed simply via the promotion of molecular iodine by using stable and cheap sodium perfluoroalkyl...
Main observation and conclusion In this article,we report a base-promoted sequential cyclization/aldol-type condensation/isomerization cascade reaction of N-propargyl-β-enaminones with aryl aldehydes.The key step in ...
the National Natural Sci-ence Foundation of China(No.21861019);the Education Department of Jiangxi Province(No.GJJ170213).
A series of Pd(Ⅱ)-enaminone complexes,termed Pd(eao)2,have been synthesized and characterized.The investigation on the catalytic activities of these new Pd(Ⅱ)-reagents has proved that the Pd(ea0)2-1 possesses excell...
Fluoroboric acid adsorbed on silica-gel(HBF4·SiO2) has been found to be an extremely efficient and recyclable catalyst for the preparation of β-enaminones and β-enamino esters under solvent-free conditions.
A simple synthesis of 1,2,3,5-tetrasubstituted pyrrole derivatives from the reaction of enaminone withα-haloketones,under solvent-free conditions,is described.