ENAMINONE

作品数:14被引量:10H指数:2
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相关领域:理学化学工程更多>>
相关作者:万结平更多>>
相关机构:江西师范大学更多>>
相关期刊:《Chemical Research in Chinese Universities》《有机化学》《Chinese Journal of Chemistry》《Chinese Chemical Letters》更多>>
相关基金:国家自然科学基金中国科学院科研项目更多>>
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Organophosphoric Acid Catalyzed[3+3]Cyclization for the Synthesis of Indenoquinolinedione Derivatives
《有机化学》2024年第12期3727-3738,共12页Guo Xinyan Yu Haolei Wan Honglin Lu Yua Tan Wei Shi Feng 
国家自然科学基金(Nos.22125104,22301112);江苏省自然科学基金(No.BK20210916);本科生创新项目(Nos.202410320104Y,XSJCX14139);江苏省优秀科技创新团队资助项目.
An organophosphoric acid catalyzed[3+3]cyclization of 2-arylidene-indan-1,3-diones with enaminones has been established,which afforded a series of structurally diverse indenoquinolinedione derivatives in moderate to e...
关键词:organophosphoric acid [3+3]cyclization ORGANOCATALYSIS ENAMINONE 1 4-DIHYDROPYRIDINE 
Transition metal-free tunable synthesis of 3-(trifluoromethylthio)and 3-trifluoromethylsulfinyl chromones via domino C-H functionalization and chromone annulation of enaminones
《Chinese Chemical Letters》2024年第11期340-343,共4页Tao Zhou Jing Zhou Yunyun Liu Jie-Ping Wan Fen-Er Chen 
financially supported by National Natural Science Foundation of China(No.22161022)。
The new reactions between o-hydroxyphenyl enaminones and Langlois reagent(CF_(3)SO_(2)Na)for the tunable synthesis of 3-(trifluoromethylthio)chromones and 3-trifluoromethylsulfinyl chromones are reported herein.Both t...
关键词:ENAMINONE C-H functinalizaiton Tunable synthesis Trifluoromethylthiolation Trifluoromethylsulfination Transition metal-free Sulfur functionalized chromones 
Chemodivergent Synthesis of Benzofurans and 2,3-Dihydrobenzofurans via Tandem Oxidative Annulation of Enaminones and Salicylaldehydes
《Chinese Journal of Chemistry》2024年第15期1727-1733,共7页Xiyan Duan Hui Li Junqi Wang Kun Liu Meixin Shi Weidong Lian Ran Chen Pu Liu 
the Science and Technology Foundation of Henan Province(222102310580);Innovation and Entrepreneurship Training Program for College Students;Henan University of Science and Technology(2023180).
Chemodivergent synthesis of benzofurans and 2,3-dihydrobenzofurans has been realized.Under a reaction system consisting of DBDMH and K_(2)CO_(3) as promotors,controlled conditions enabled the formation of two sets of ...
关键词:Cross-coupling UMPOLUNG Domino reactions ENAMINONE BENZOFURANS 2 3-Dihydrobenzofurans 
Recent advances in visible light-mediated chemical transformations of enaminones被引量:3
《Chinese Chemical Letters》2024年第2期4-15,共12页Yu Han Liyun Zhou Chengyu Wang Shangti Feng Rong Ma Jie-Ping Wan 
the National Natural Science Foundation of China(No.21702088);the Natural Science Foundation of Shandong Province(No.ZR2022MB130)for the financial support.
Enaminones,which possesses both the nucleophilic enamine as well as electrophilic enone structures,are well known versatile building blocks in organic synthesis.Meanwhile,visible light-mediated reactions have emerged ...
关键词:ENAMINONE Visible light C-H functionalization C=C bond cleavage CYCLIZATION Multicomponent reactions 
Amine-catalyzed synthesis of N^(2)-sulfonyl 1,2,3-triazole in water and the tunable N^(2)-H 1,2,3-triazole synthesis in DMSO via metal-free enamine annulation
《Chinese Chemical Letters》2022年第2期855-858,共4页Yanhui Guo Yunyun Liu Jie-Ping Wan 
financially supported by the National Natural Science Foundation of China (No.21861019);Natural Science Foundation of Jiangxi Province (No.20202ACBL203006)。
The selective synthesis of N^(2)-sulfonyl and N^(2)-H 1,2,3-triazoles via organocatalytic annulation of enaminone/enaminoester with sulfonyl azide has been realized. The unconventional selectivity providing N^(2)-sulf...
关键词:ENAMINONE ANNULATION N^(2)-sulfonyl 1 2 3-triazole Selectivity Green synthesis Sulfonyl azide 
Metal-free C(sp^(2))-H perfluoroalkylsulfonylation and configuration inversion:Stereoselective synthesis ofα-perfluoroalkylsulfonyl E-enaminones
《Chinese Chemical Letters》2021年第11期3514-3517,共4页Qing Yu Yunyun Liu Jie-Ping Wan 
financially supported by National Natural Science Foundation of China(No.21861019);Natural Science Foundation of Jiangxi Province(No.20202ACBL203006).
The perfluoroalkylsulfonylation(CF_(3)SO_(2),C_(2)F_(5)SO_(2)and CHF_(2)SO_(2))in the enaminone C-H bonds has been developed simply via the promotion of molecular iodine by using stable and cheap sodium perfluoroalkyl...
关键词:C-H Functionalization ENAMINONE Perfluoroalkyl sulfonylation METAL-FREE Configuration inversion 
Base-Promoted Synthesis of 3-Alkenyl-2-pyridones from N-Propargyl-β-enaminones and Aryl Aldehydes
《Chinese Journal of Chemistry》2021年第10期2781-2788,共8页Qingyu Tian Shangyun Xiao Guolin Cheng 
supported by the NSF of China(No.22071068).
Main observation and conclusion In this article,we report a base-promoted sequential cyclization/aldol-type condensation/isomerization cascade reaction of N-propargyl-β-enaminones with aryl aldehydes.The key step in ...
关键词:Domino reactions Aldehydes ALKENES ENAMINONE PYRIDONES 
Synthesis of Enaminone-Pd(Ⅱ)Complexes and Their Application in Catalysing Aqueous Suzuki-Miyaura Cross Coupling Reaction被引量:6
《Chinese Journal of Chemistry》2020年第3期254-258,共5页Leiqing Fu Xiaoji Cao Jie-Ping Wan Yunyun Liu 
the National Natural Sci-ence Foundation of China(No.21861019);the Education Department of Jiangxi Province(No.GJJ170213).
A series of Pd(Ⅱ)-enaminone complexes,termed Pd(eao)2,have been synthesized and characterized.The investigation on the catalytic activities of these new Pd(Ⅱ)-reagents has proved that the Pd(ea0)2-1 possesses excell...
关键词:SUZUKI Pd(Ⅱ) BORON 
Highly Efficient and Recyclable Catalyst HBF_4·SiO_2 Catalyzed Synthesis of β-Enamino Compounds Under Solvent-free Conditions被引量:1
《Chemical Research in Chinese Universities》2011年第5期792-794,共3页GAO Han JIA Xu-dong DUAN Hai-feng LIN Ying-jie GAO Jun-gang LIANG Da-peng WU Mao-cheng 
Fluoroboric acid adsorbed on silica-gel(HBF4·SiO2) has been found to be an extremely efficient and recyclable catalyst for the preparation of β-enaminones and β-enamino esters under solvent-free conditions.
关键词:β-Enaminone β-Enamino ester HBF4·SiO2 Solvent-free condition 
A solvent-free synthesis of 1,2,3,5-tetrasubstituted pyrroles from enaminones and α-haloketones
《Chinese Chemical Letters》2011年第10期1219-1222,共4页Issa Yavari Maryam Ghazvini Leila Azad Tayebeh Sanaeishoar 
A simple synthesis of 1,2,3,5-tetrasubstituted pyrrole derivatives from the reaction of enaminone withα-haloketones,under solvent-free conditions,is described.
关键词:1H-Pyrrole ENAMINONE ar-Haloketone 1 3-Dicarbonyl compound SOLVENT-FREE 
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