Recent advances in visible light-mediated chemical transformations of enaminones  

作　　者：Yu Han Liyun Zhou Chengyu Wang Shangti Feng Rong Ma Jie-Ping Wan 

机构地区：[1]College of Chemistry and Chemical Engineering,Jiangxi Normal University,Nanchang 330022,China [2]School of Chemistry and Chemical Engineering,Linyi University,Linyi 276000,China [3]Linyi Sanfeng Chemical Co.,Ltd.,Linyi 276000,China

出　　处：《Chinese Chemical Letters》2024年第2期4-15,共12页中国化学快报（英文版）

基　　金：the National Natural Science Foundation of China(No.21702088);the Natural Science Foundation of Shandong Province(No.ZR2022MB130)for the financial support.

摘　　要：Enaminones,which possesses both the nucleophilic enamine as well as electrophilic enone structures,are well known versatile building blocks in organic synthesis.Meanwhile,visible light-mediated reactions have emerged as useful synthetic strategy with enhanced sustainability.Around the last decade,various photochemical transformations of enaminones have been developed to construct cyclic or acyclic compounds.In this review,we describe the recent advances in visible light-mediated chemical transformations of enaminones.Detailed discussion on the reaction mechanism of the related reactions is given to provide guide to the reader.Finally,a summary on the existing challenges and the future outlook towards the development of practical photocatalytic reactions of enaminones is also presented.

关 键 词：ENAMINONE Visible light C-H functionalization C=C bond cleavage CYCLIZATION Multicomponent reactions 

分 类 号：O621.251[理学—有机化学]