Z.-M.Chen thanks National Natural Science Foundation of China(22071149,21871178);Natural Science Foundation of Shanghai(23ZR1428200);financial support.H.Ke thanks Natural Science Foundation of Jiangxi Province(20202ACBL213005)for financial support.
Chiral BINAM-derived selenide/achiral acid co-catalyzed atroposelective electrophilic sulfenylation of pyrrole derivatives has been realized for the first time.A variety of C-N axially chiral sulfur-containing pyrrole...
supported by the National Natural Science Foundation of China(Nos.31871365 and 22177029);Fundamental Research Funds for the Central Universities.
Protein S-sulfenylation(protein sulfenic acid),as one of the most significant oxidative post-translational modifications(OxiPTMs),plays a vital role in regulating protein function.A variety of activity-based probes ha...
supported by a grant from the Southern University of Science and Technology.
This work describes a general method for the synthesis of a series of sulfenylated and selenylated carboranes at room temperature using readily available iodocarboranes as starting materials via boron-centered carbora...
funded by the Major Scientific and Technological Projects of Xinjiang Production and Construction Corps of China[2018AA005]and the 111 Project[B20051];supported by the PTM Biolabs lnc.[Hangzhou,China]for technical assistance.
Reactive oxygen species(ROS)play a key role in a variety of biological processes,such as the perception of abiotic stress,the integration of different environmental signals,and the activation of stress response networ...
supported by the National Natural Science Foundation of China(No.21302171);the Zhejiang Shuren University Basic Scientific Research Special Funds,the“Ten-thousand Talents Plan”of Zhejiang Province(No.2019R51012).
Using visible light as energy to form free radicals has important synthetic value.A novel and efficient visible-lightmediated strategy has been developed for the generation of thiobenzene radicals through cerium-catal...
the National Natural Science Foundation of China(NSFC)(nos.21871178,22071149,21901158,21702135)and the STCSM(no.19JC1430100)for their financial support.
Enantioselective intermolecular three-component oxysulfenylations of alkenes with phenols and alcohols as O-nucleophiles were achieved using chiral BINAM-derived sulfide/phosphoric acid as the cocatalyst.Notably,chira...
We thank the National Natural Science Foundation of China(21672217,21861132003 and 22031006);the Tsinghua University Initiative Scientific Research Program for financial support.
Enantioselective oxidative construction of a C(sp^(3))–S bond has been achieved using a chiral primary amine catalyst in the presence of tert-butyl hydroperoxide and a catalytic amount of tetrabutylammonium iodide.Th...
supported by the Youth Innovation Technology Project of Higher School in Shandong Province(No.2019KJC021);Qinghai Science and Technology Achievement Transformation Project(No.2019-SF-122);Qinghai Key Laboratory of Tibetan Medicine Research(No.2021-ZJ-Y03)。
Sulfur-containing organic compounds display wide applications in the field of materials science,synthetic chemistry,and pharmaceutical industry.Thus,numerous synthetic strategies have been developed for the synthesis ...
This work was supported by the National Natural Science Foundation of China(No.21302110);the Natural Science Foundation of Shandong Province(No.ZR2016JL012);the Scientific Research Foundation of Qingdao University of Science and Technology.
An efficient approach to sulfur-bridged imidazopyridines has been developed under metal-free conditions using inexpensive sulfur powder as the sulfur source.Most appealingly,the reaction can proceed smoothly without a...
support from the Natural Science Foundation of China and Shandong Province(Nos.21572118,21971149,ZR2018MB014,ZR2019ZD45);Tang scholar award and the Fundamental Research Funds of Shandong University.
Herein,we report a practical protocol for the synthesis of sulfur cycle fused 1,2,3-triazoles through a copper(I)-catalyzed tandem click/intramolecular sulfenylation reaction.The reaction proceeded via a copper-cataly...