financial supports from the National Natural Science Foundation of China(Grant No.NSFC52473104);National Key R&D Program of China(Grant No.2022YFC2104500);Zhejiang Provincial Natural Science Foundation of China(Grant No.Y24B040002);Ningbo 2025 Key Scientific Research Programs(Grant No.2022Z160);the China Postdoctoral Science Foundation(Grant No.2023M733601);the Ningbo Natural Science Foundation(Grant No.2023I333&2023J409).
Renewable 2,5-furandicarboxylic acid-based polyesters are one of the most promising materials for achieving plastic replacement in the age of energy and environmental crisis.However,their properties still cannot compe...
The direct deoxygenative homo-coupling of benzyl alcohols holds great promise to build up bibenzyl motifs in organic synthesis,yet it remains a grand challenge in selectivity and activity control.Herein,we first disco...
supported by the National Key R&D Program of China(2021YFA1500100,A.L.);the National Natural Science Foundation of China(22031008,A.L.);the Science Foundation of Wuhan(2020010601012192,A.L.).
Electrooxidation strategies for synthesizing readily oxidizable products face notable challenges,especially when the oxidation potential of the products is lower than that of the reactants or when high current densiti...
the National Key Research and Development Program of China(No.2022YFB4102000);the National Natural Science Foundation of China(NSFC,Nos.22102018 and 52171201);the Huzhou Science and Technology Bureau(No.2022GZ45);the Hefei National Research Center for Physical Sciences at the Microscale(No.KF2021005);the China Postdoctoral Science Foundation-Funded Project(No.2022M710601);the Huzhou Science and Technology Bureau(No.2023GZ02);the Natural Science Foundation of Sichuan Province(No.24NSFSC5779)。
As hydrogen energy technologies gain momentum,the role of renewable energy in facilitating sustainable hydrogen production is becoming increasingly critical.As a hydrogen production method,water electrolysis has attra...
Financial support from National Natural Science Foundation of China(Nos.22201202,22171206 and 22371201);Natural Science Foundation of Zhejiang Province(No.LZ23B020001);Open Foundation of Hunan Provincial Key Laboratory of Controllable Preparation and Functional Application of Fine Polymers(No.E22307);Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University(No.2020ZD04);Open Research Fund of Key Laboratory of the Ministry of Education for Advanced Catalysis Materials and Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces,Zhejiang Normal University。
A photoredox-catalyzed synthesis ofα,α-difluoromethyl sulfones from sulfur dioxide with readily available gem–difluoroalkenes is reported.This protocol features mild reaction conditions,broad substrate scope and go...
supported by the Leading Talents of Industrial Technology in Yunnan Province[grant number 618820190024];the Yunnan Province Nonferrous Metal Vacuum Metallurgy Top Team[grant number 202305AS350012].
The increasing demand for magnesium as a next-generation structural material highlights the significance of incorporating CaF_(2)as a catalyst to enhance the efficiency of vacuum carbothermal reduction of magnesium(VC...
supported by the National Key Research and Development Project of China(No.2022YFE0113800);the National Natural Science Foundation of China(No.22102013);Natural Science Foundation of Chongqing(No.cstc2021jcyj-msxmX0945);Venture and Innovation Support Program for Chongqing Overseas Returnees(No.cx2020107);Thousand Talents Program for Distinguished Young Scholars,Postdoctoral Fellowship Program of CPSF(No.GZB20230910)。
Propane dehydrogenation(PDH)is a vital industrial process for producing propene,utilizing primarily Cr-based or Pt-based catalysts.These catalysts often suffer from challenges such as the toxicity of Cr,the high costs...
Asymmetric allylic C—H functionalization is a valuable and challenging research area. Different from the conventional direct allylic C—H cleavage strategy, transition metal-catalyzed migratory allylic substitution o...
supported by the National Natural Science Foundation of China(Nos.82130103,82151525 and 81903465);the Central Plains Scholars and Scientists Studio Fund(2018002);the Natural Science Foundation of Henan Province(No.212300410051);the Science and Technology Major Project of Henan Province(No.221100310300)。
Herein,we report the dynamic kinetic resolution asymmetric acylation ofγ-hydroxy-γ-perfluoroalkyl butenolides/phthalides catalyzed by amino acid-derived bifunctional organocatalysts,and a series of ketals were obtai...
Synthetic electrochemistry has been selected as one of the Top Ten Emerging Technologies in Chemistry in 2023 by International Union of Pure and Applied Chemistry(IUPAC)^([1]).It has emerged as a sustainable platform ...