RADICAL

作品数：941被引量：1273H指数：12
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相关领域：理学医药卫生更多>>
相关作者：任艳丽王尧黄萌萌王晨阳胡跃飞更多>>
相关机构：南开大学南京大学苏州大学山东大学更多>>
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相关基金：国家自然科学基金国家重点基础研究发展计划中国博士后科学基金广东省自然科学基金更多>>
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Effects of Bifidobacterium triple viable bacteria-assisted mirtazapine in managing depression in patients after radical surgery for gastric cancer
《World Journal of Gastrointestinal Surgery》2025年第4期102-109,共8页Heng Lu Wei-Dong Wu Li Ji Xiao-Yan Xu 
BACKGROUND Patients with gastric cancer may have a risk of depression after radical surgery,which affects recovery and requires intensive intervention.AIM To explore the role of Bifidobacterium triple viable bacteria-...
关键词：Bifidobacterium triple bacteria Oryzazapine Radical gastric cancer DEPRESSION NEUROENDOCRINE Intestinal flora Quality of life 
Modular assembly of complex C-alkyl glycoside enabled via cooperative NHC and photoredox catalysis
《Science China Chemistry》2025年第4期1412-1417,共6页Rui-Qiang Jiao Ming Li Xi Chen Mei-Ze Xu Tian Ding Xiao-Ping Gong Zhuo-Mei Li Xue-Yuan Liu Yong-Min Liang 
supported by the National Natural Science Foundation of China(22171114 and 22371097).
C-Alkyl glycosides are found in natural products and are indispensable in drug development programs;owing to their diverse range of medicinal properties. Two-component reactions involving glycosyl radical addition are...
关键词：C-alkyl glycosides THREE-COMPONENT NHC catalysis visible-light photoredox catalysis radical-radical coupling 
Perioperative risk factors for prognosis in patients undergoing radical esophagectomy:A retrospective study
《World Journal of Gastrointestinal Surgery》2025年第4期174-186,共13页Shu-Gang Liu Xin-Jian Xu Ming He Ji-Dong Zhao Lin Pei 
BACKGROUND Esophageal cancer constitutes one of the most aggressive malignant neoplasms associated with poor clinical outcomes.While surgical resection remains the cornerstone of curative intervention,optimization of ...
关键词：Radical esophagectomy Perioperative management Prognostic factors Postoperative analgesic use Survival analysis 
Risk factors influencing sphincter preservation in laparoscopic radical rectal cancer surgery
《World Journal of Gastrointestinal Surgery》2025年第3期240-248,共9页Jia-Rui Liu Jin Zhang Xiang-Long Duan 
Supported by The National Natural Science Foundation of China,No.82460107;Science and Technology Talent Support Program of Shaanxi Provincial People's Hospital,No.2021 LJ-05.
BACKGROUND The surgical management of rectal cancer is continuously advancing,with a current emphasis on minimising the need for a permanent stoma.Understanding the risk factors influencing sphincter preservation is c...
关键词：Rectal cancer Laparoscopic surgery Sphincter preservation Risk factors Preoperative evaluation 
Radical rejuvenates the click-clip reaction
《Science China Chemistry》2025年第3期803-805,共3页Jiong Zhou Miaomiao Yan Yuanxin Zhang 
With the widespread attention paid to the construction of functional molecular systems,chemical synthesis is increasingly pursuing the accurate and efficient combination and dissociation of molecular units to achieve ...
关键词：INFINITELY nates SYNTHESIS 
Organocatalytic radical aminoacylation of alkenes forβ-aminoketone synthesis
《Science China Chemistry》2025年第3期1002-1008,共7页Ayisenbati Jialingbieke Xinying Hu Zuquan Liu Xiyun Lin Yiwen Yin Jibin Li Yatian Huang Ding Du 
supported by the the National Natural Science Foundation of China (22371297)。
An NHC organocatalytic radical aminoacylation of alkenes has been developed by using aldehydes as the acylating reagents and activated aryloxy-amides as the N-radical precursors,providing a new platform for modular ac...
关键词：difunctionalization of alkenes ORGANOCATALYSIS CARBENE radical relay AMINOACYLATION β-aminoketone synthesis 
Photoredox-catalyzed synthesis of α,α-difluoromethyl-β-alkoxysulfones from sulfur dioxide
《Chinese Chemical Letters》2025年第3期248-252,共5页Minjun Yin Yuhui Lin Manli Zhuang Wei Xiao Jie Wu 
Financial support from National Natural Science Foundation of China(Nos.22201202,22171206 and 22371201);Natural Science Foundation of Zhejiang Province(No.LZ23B020001);Open Foundation of Hunan Provincial Key Laboratory of Controllable Preparation and Functional Application of Fine Polymers(No.E22307);Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University(No.2020ZD04);Open Research Fund of Key Laboratory of the Ministry of Education for Advanced Catalysis Materials and Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces,Zhejiang Normal University。
A photoredox-catalyzed synthesis ofα,α-difluoromethyl sulfones from sulfur dioxide with readily available gem–difluoroalkenes is reported.This protocol features mild reaction conditions,broad substrate scope and go...
关键词：Sulfur dioxide gem-Difuloroalkenes Photoredox catalysis α α-Difluoromethyl-β-alkoxysulfones Arylsulfonyl radical 
Copper-catalyzed 1,4-silylcyanation of 1,3-enynes:A silyl radical-initiated approach for synthesis of difunctionalized allenes
《Chinese Chemical Letters》2025年第3期277-281,共5页Qi Li Zi-Lu Wang Yun-He Xu 
support of this work by the funding of the National Natural Science Foundation of China(No.22371269);the State Key Laboratory of Elementoorganic Chemistry Nankai University(No.202001);the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB0450301);the Open Project of Key Laboratory of Organosilicon Chemistry,and Material Technology of Ministry of Education,Hangzhou Normal University(No.KFJJ2022013)。
Herein,we developed the first example of copper-catalyzed silicon radical-initiated 1,4-silylcyanation of unactivated 1,3-enynes,which provided an efficient method to access CN-bearing tri-and tetrasubstituted homoall...
关键词：Copper-catalyst Unactivated enynes 1 4-Difunctionalization Radical silylation CYANATION 
Is intraperitoneal isoperistaltic side-to-side anastomosis a safe surgical procedure in radical colon cancer surgery
《World Journal of Gastrointestinal Oncology》2025年第3期133-143,共11页Bin Wu Jing-Tao Zhu He-Xin Lin Yu-Hua Dai Tian-Sheng Lin An-Le Huang Yi-Nan Chen Yong-Wen Li Hai-Bin Wang Yi-Fu Chen Dong-Han Chen Huang-Dao Yu Jun You Qing-Qi Hong 
Bethune Charitable Foundation Project,No.HZB-20190528-10;Natural Science Foundation of Fujian Province,No.2020J011230.
BACKGROUND Colorectal cancer,one of the most common malignancies,is primarily treated through surgery.With the widespread use of laparoscopy,gastrointestinal reconstruction remains a key area of research.The choice be...
关键词：Colon cancer Laparoscopic surgery Intraperitoneal anastomosis Extraperitoneal anastomosis Isoperistaltic sideto-side anastomosis Hand-sewn 
Perioperative neurocognitive dysfunction and role of dexmedetomidine in radical colon cancer surgery in elderly patients
《World Journal of Gastrointestinal Surgery》2025年第3期6-13,共8页Chandra K Pandey Abhishek Kumar 
This article explored the application of dexmedetomidine(Dex),a highly selective alpha-2 agonist,in managing postoperative cognitive dysfunction(POCD)in elderly patients undergoing radical colon cancer surgery.Aging i...
关键词：Colon cancer DEXMEDETOMIDINE General anesthesia ELDERLY Radical colon cancer surgery Cognitive function 
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