IRIDIUM

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Durable Acidic Oxygen Evolution Via Self‑Construction of Iridium Oxide/Iridium‑Tantalum Oxide Bi‑Layer Nanostructure with Dynamic Replenishment of Active Sites
《Nano-Micro Letters》2025年第7期270-284,共15页Qi Guo Rui Li Yanan Zhang Qiqin Zhang Yi He Zhibin Li Weihong Liu Xiongjun Liu Zhaoping Lu 
financially supported by the National Natural Science Foundation of China(Nos.52101202,52071024);the Funds for Creative Research Groups of China(No.51921001);the National Key Research and Development Program of China(No.2022YFB3707103);the Gusu Leading Talents Program(No.ZXL2021206);the Basic Research Program of Taicang(No.TC2023JC29);the Fundamental Research Fund for the Central Universities of China,GuangDong Basic and Applied Basic Research Foundation,and State Key Lab for Advanced Metals and Materials(No.2024-Z11).
Proton exchange membrane(PEM)water electrolysis presents considerable advantages in green hydrogen production.Nevertheless,oxygen evolution reaction(OER)catalysts in PEM water electrolysis currently encounter several ...
关键词：SELF-CONSTRUCTION NANOPOROUS Electronic interaction REPLENISHMENT Proton exchange membrane(PEM)water electrolysis 
Cyclometalated iridium(III) complex based on isoquinoline alkaloid synergistically elicits the ICD response and IDO inhibition via autophagydependent ferroptosis
《Acta Pharmaceutica Sinica B》2025年第1期424-437,共14页Yuan Lu Shan-Shan Wang Meng-Ya Li Rong Liu Meng-Fan Zhu Liang-Mei Yang Feng-Yang Wang Ke-Bin Huang Hong Liang 
supported by the National Natural Science Foundation of China(22177022,22267005);the Natural Science Foundation of Guangxi Province of China(AD22035193).
The development of anticancer drugs to treat triple-negative breast cancer(TNBC)is an ongoing challenge.Immunogenic cell death(ICD)has garnered considerable interest worldwide as a promising synergistic modality for c...
关键词：Organometallic complex Cyclometalated iridium complex Isoquinoline alkaloid ER stress Autophagy-dependent ferroptosis Immunogenic cell death IDO inhibition CHEMOIMMUNOTHERAPY 
B-embedded narrowband pure near-infrared(NIR)phosphorescent iridium(Ⅲ)complexes and solution-processed OLED application
《Chinese Chemical Letters》2025年第1期623-626,共4页Fuzheng Zhang Chao Shi Jiale Li Fulin Jia Xinyu Liu Feiyang Li Xinyu Bai Qiuxia Li Aihua Yuan Guohua Xie 
support from the National Natural Science Foundation of China(Nos.22171109,52373195 and 22001097);Natural Science Foundation of Jiangsu Province of China(No.BK20201003);the Postdoctoral Research Foundation of China(No.2021M701657);the Opening Project of Key Laboratory of Optoelectronic Chemical Materials and Devices,Ministry of Education,Jianghan University(No.JDGD-202301)。
Pure near-infrared(NIR)phosphorescent materials with emission peak larger than 700 nm are of great significance for the development of optoelectronics and biomedicine.We have designed and synthesized two new B-embedde...
关键词：Iridium complex B-embedded NEAR-INFRARED OLED PHOSPHORESCENCE 
Hexavalent iridium boosts oxygen evolution performance
《Green Carbon》2024年第4期403-404,共2页Mengtian Huo Yu Liang Kaichi Qin Guanzhi Wang Zihao Xing Jinfa Chang 
supported by the National Natural Science Foundation of China(22102105,22202037);the Fundamental Research Funds for the Central Universities(Nos.2412023QD019 and 2412024QD014)。
Green hydrogen production by proton exchange membrane water electrolysis(PEMWE)is considered a promising method for sustainable hydrogen production using renewable energy[1],[2].Currently,iridium-based oxides(IrOx)are...
关键词：IRIDIUM DURABILITY valent 
En Route to Diastereopure Polycyclic γ-Lactones by Iridium-Catalyzed Hydride Transfer
《Chinese Journal of Chemistry》2024年第23期3047-3055,共9页Yang Chen Jingyu Zhang Yecheng Wang Hongguang Du Jiaxi Xu Zhanhui Yang 
supported by the National Key Research and Development Program of China(No.2022YFF0709803);Natural Science Foundation of Beijing Municipality(No.2202041);the High Performance Computing Platform of Beijing University of Chemical Technology(BUCT).
The reductive lactonization strategy provides an efficient access to diastereoenriched polycyclicγ-lactones.However,it is still a formidable challenge to develop an efficient and versatile protocol with excellent lev...
关键词：Iridium catalysis Hydride transfer Reductive lactonization Diastereoselectivity control Polycyclic y-lactones Methodology and reactions Sterichindrance Reduction 
Microtubule polymerization induced by iridium-fullerene photosensitizers for cancer immunotherapy via dual-reactive oxygen species regulation strategy
《Aggregate》2024年第6期272-283,共12页Xiao-Xiao Chen Kun Peng Xi Chen Zheng-Yin Pan Qing-Hua Shen Yu-Yi Ling Jian-Zhang Zhao Cai-Ping Tan 
National Natural Science Foundation of China,Grant/Award Number:22177142;Basic and Applied Basic Research Foundation of Guangdong Province,Grant/Award Numbers:2022A1515111089,2023A1515010625,2024B1515040028。
Microtubules(MTs)are key players in cell division,migration,and signaling,and they are regarded as important targets for cancer treatment.In this work,two fullerene(C_(60))-functionalized Ir(Ⅲ)complexes(Ir-C_(60)1 an...
关键词：ANTICANCER FULLERENE iridium complexes MICROTUBULE photo-immunotherapy 
Hierarchical structures on platinum-iridium substrates enhancing conducting polymer adhesion
《Bio-Design and Manufacturing》2024年第6期889-898,共10页Linze Li Changqing Jiang Luming Li 
supported by the National Key Research and Development Program of China(No.2021YFC2400201);the National Natural Science Foundation of China(No.81830033);the Natural Science Foundation of Fujian Province,China(No.2023J05097);the Young and Middle-aged Teacher Education Research Project of the Education Department of Fujian Province,China(No.JAT220004)。
Conducting polymers(CPs),including poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)(PEDOT:PSS),are promising coating materials for neural electrodes.However,the weak adhesion of CP coatings to substrates such a...
关键词：Hierarchical structures Femtosecond laser Conducting polymers Neural electrodes Stability 
Spontaneous Symmetry Breaking of Iridium and Ruthenium Metallophosphors for the Constructions of Chiral Light-Harvesting Systems
《CCS Chemistry》2024年第11期2713-2726,共14页Chun-Yun Ding Yu-Wu Zhong Jiannian Yao 
a result of a generous grant from the National Key R&D Program of China(grant no.2023YFE0125200);the National Natural Science Foundation of China(NSFC;grant nos.21925112 and 22090021).
Symmetry breaking for chirality generation and lightharvesting for solar energy conversion are two momentous topics in natural systems.The construction of a chiral light-harvesting system completely based on symmetry ...
关键词：chiral symmetry breaking metallophosphors circularly polarized luminescence chirality transfer energy transfer chirality amplification 
Enantioselective iridium-catalyzed allylic substitution with a Reformatsky reagent: direct construction of β-stereogenic homoallylic esters
《Science China Chemistry》2024年第11期3791-3797,共7页Debasis Pal Kirana DVeeranna Yuk Fai Wong PAndrew Evans 
the National Sciences and Engineering Research Council (NSERC) for a Discovery Grant;supporting a Tier 1 Canada Research Chair (P.A.E);the Huxiang High-Level Talent Gathering Project from the Science and Technology Department of Hunan Province (Grant No. 2020RC5001)。
The Reformatsky reagent derived from ethyl bromoacetate circumvents the challenge associated with the direct regio-and enantioselective iridium-catalyzed allylic alkylation with an unstabilized aliphatic ester enolate...
关键词：allylic substitution asymmetric catalysis mechanistic studies natural product synthesis Reformatsky reagent 
Efficient synthesis of IrPtPdNi/GO nanocatalysts for superior performance in water electrolysis
《Nano Research》2024年第11期10208-10215,共8页Sanha Jang Young Hwa Yun Jin Gyu Lee Kyung Hee Oh Shin Wook Kang Jung-Il Yang MinJoong Kim Changsoo Lee Ji Chan Park 
conducted within the framework of a research and development program at the Korea Institute of Energy Research(Nos.C3-2420 and C4-2403).
Traditional iridium (Ir) oxide catalysts have faced significant limitations in water electrolysis, particularly under acidic conditions where instability and degradation severely restrict the efficiency of the oxygen ...
关键词：multicomponent nanoparticles rapid synthesis water electrolysis alloy iridium cat 
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