METHYLALUMINOXANE

作品数:12被引量:8H指数:2
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相关领域:理学更多>>
相关作者:徐京城王艳花童建颖更多>>
相关机构:浙江树人大学上海理工大学更多>>
相关期刊:《合成化学》《Frontiers of Chemical Science and Engineering》《Science China Chemistry》《Chemical Research in Chinese Universities》更多>>
相关基金:国家自然科学基金河北省自然科学基金更多>>
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Tandem Catalysis of One Metallocene Catalyst Combined with Two Different Cocatalysts for Preparing Branched Polyethylene
《Chinese Journal of Polymer Science》2016年第3期298-306,共9页杨敏 qin li xiang-liu li bo-wen hu xiao-fang dong jia-yan qu 刘宾元 xi wang xiao-yu hao 
financially supported by the Natural Science Foundation of Hebei Province(No.B2015202049);the National Natural Science Foundation of China(Nos.21004017 and 50573018)
Tandem catalytic systems, consisting of ethylene bis(indenyl) zirconium dichloride with two different cocatalysts, alkylaluminum(diethylaluminium chloride or trialkylaluminum) and methylaluminoxane, were employed ...
关键词:Tandem catalysis Branched polyethylene Metallocene Alkylaluminum Methylaluminoxane 
Theoretical Study on Molecular Structures of Methylaluminoxane Nanotubes
《Chinese Journal of Chemical Physics》2015年第2期179-183,I0001,共6页王艳花 王晓巍 童建颖 徐京城 
Density functional theory was used to optimize structures of different methylaluminoxane nanotubes with general formula [(AIOMe)2]n, [(AlOMe)3]n and [(A1OMe)4]n cycle unit, where n ranges from 1 to 10. To explor...
关键词:METHYLALUMINOXANE NANOTUBES Density functional theory 
Polymerization of methyl methacrylate catalyzed by mono-/bis-salicylaldiminato nickel(Ⅱ) complexes and methylaluminoxane被引量:3
《Frontiers of Chemical Science and Engineering》2011年第1期19-25,共7页Jihong LU Danfeng ZHANG Qian CHEN Buwei YU 
sponsored by the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry of China,the Science and Technology Innovation Program of the China National Petroleum Corporation,and the Key Laboratory of Advanced Polymer Materials of Shanghai(Grant No.08DZ2230500);the Science and Technology Innovation Program of China National Petroleum Corporation.
Two types of salicylaldiminato-based nickel complexes,mono-ligated Ni(II)complexes([O-C_(6)H_(4)-o-C(H)=N-Ar]Ni(PPh_(3))(Ph)(5),[O-(3,5-Br_(2))C_(6)H_(2)-o-C(H)=N-Ar]Ni(PPh_(3))(Ph)(6),[O-(3-t-Bu)C_(6)H_(3)-o-C(H)=N-A...
关键词:late transition metal catalyst methyl methacrylate POLYMERIZATION salicylaldiminato nickel complexes METHYLALUMINOXANE syndiotactic structure 
The effect of polymerization conditions on crystalline of polybutene-1 catalyzed by metallocene catalyst被引量:3
《Chinese Chemical Letters》2007年第2期217-220,共4页Qi Gu Huang Ya Ping Sheng Kun Xue Deng Li Fu Ma Yi Xian Wu Wan Tai Yang 
Polybutene-1 was synthesized stereoselectively with the precursor η(5)-(pentamethyl-cyclopentadienyl) tribenzyloxide titanium (Cp*Ti(OBz)3) and methylaluminoxane (MAO). The effects of polymerization conditions, trime...
关键词:Metallocene catalyst METHYLALUMINOXANE POLYBUTENE-1 Structure 
Synthesis of Modified Methylaluminoxane
《合成化学》2004年第z1期39-39,共1页Zhu Bo-chao Zhao Xu-tao Yin Yuan-qi Wei Shao-yi 
Supported by Petrochina(200909-01)
关键词:SYNTHESIS modified methylaluminoxane TRIMETHYLALUMINIUM tri-isobutylaluminium 
Synthesis of Methylaluminoxane
《Chemical Research in Chinese Universities》2001年第z1期122-,共1页ZHU BoChao 
Methylaluminoxane (MAO) is the most important cocatalyst of metallocene catalysts. In order to raise the hydrolysis reactions repeatability and the yield,we used the pretreated A12(SO4)3 18H2O to synthesize MAO. A few...
Syndiospecific Polymerization of Styrene Catalyzed by IndTiCl_2(OR)/Methylaluminoxane System被引量:1
《催化学报》2001年第1期3-4,共2页马海燕 陈斌  
SupportedbyNNSFCandSINOPEC (2 973414 5 ) ;NNSFC (2 98710 10 ) ;andSpecialFundsforMajorStateBasicResearchProjects (G19990 6 4
关键词:苯乙烯 间规聚合 聚苯乙烯 钛催化剂 催化聚合 
COPOLYMERIZATION OF ETHYLENE AND PROPYLENE WITH (CpCH_2CH_2CH=CH_2)_2MCl_2(M=Zr,Hf)AND Cp_2ZrCl_2 CATALYSTS被引量:1
《Chinese Journal of Polymer Science》2000年第2期169-175,共7页Hui Yao Shi-jing Xiao Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China 
(CpCH_2CH_2CH = CH_2)_2MCl_2(M=Zr, Hf)/MAO and Cp_2ZrCl_2/MAO (Cp=cyclopentadienyl; MAO=methylaluminoxane) catalyst systems have been compared for ethylene copolymerization to investigate the influence of theligand an...
关键词:Metallocene catalyst Ethylene/propylene copolymerization METHYLALUMINOXANE 
Synthesis of Syndiotactic Polystyrene with Novel Titanocene Catalysts Activated by Modified Methylaluminoxane
《Chinese Chemical Letters》1999年第2期171-174,共4页Fang Ming ZHU Qun Fang WANG Yu Tang FANG Shang An LIN(Institute of Polymer Science, Zhongshan University. Guangzhou 510275) 
Novel highly active eta(5)-pentamethylcyclopentadienyltribenzyloxy titanium catalyst activated by modified methylaluminoxane (m-MAO) was prepared for styrene syndiospecific polymerization. The influences of the conten...
关键词:METALLOCENE syndiotactic polystyrene METHYLALUMINOXANE 
COPOLYMERIZATION OF ETHYLENE WITH 1-OCTENE USING Et(Ind)_2ZrCl_2/MAO CATALYST
《Chinese Journal of Polymer Science》1998年第1期32-37,共6页姚晖 肖士镜 陆宏兰 
Copolymerization of ethylene/1-octene was carried out in toluene withvarious concentrations of comonomer in the feed using Et(Ind)_2ZrCl_2/MAO (methyl alu-minoxane) as catalyst. It was found that with the increase of ...
关键词:COPOLYMERIZATION ETHYLENE 1-OCTENE METHYLALUMINOXANE Et(Ind)_2ZrCl_2 
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