Non-metallocene catalysts have emerged as a promising alternative to traditional metallocene catalysts for olefin polymerization,offering unique advantages regarding polymer structure control and product diversity.Rec...
financially supported by the National Natural Science Foundation of China (Nos. 51973037 and 52173056);PetroChina Company Limited,China。
The melt memory effect is a widely observed phenomenon in semi-crystalline polymers. In practical applications, various additives are usually introduced into polymers, which may affect their melt memory behavior. In t...
In this work, homopolymerization of propylene for synthesis of different molecular weights polypropylene was done using an isospecific metallocene catalyst by changing the polymerization conditions such as Al/Zr (Alum...
The author is grateful to the Department of Chemistry of Morgan State University for its support of this work.
Nano-emulsion,a kinetically stable system of nanosized oil droplets in water has been numerously used as a medium for biological and medicinal processes.It is also used as a solubilizing medium for compounds or molecu...
Polymerization of mixed alpha-olefins originating from the Fischer-Tropsch synthesis catalyzed by theBu)_3/[Me_2NHPh]^+[B(C_6F_5)_4]^-,was studied.The effects of the Zr/olefin mole ratio,Al/Zr mole ratio,reaction temp...
supported by the National Natural Science Foundation of China(21473142 and 21673191);the National Innovative Research Team of China(IRT_14R31 and J1310024)
Various bond modes of the M-C(C5 ring) exist in metallocene compounds of group 14 heavier elements,mostly due to an intricate interaction between the lone electron pairs at the M center and the 6 p-electrons of the ...
financially supported by the Natural Science Foundation of Hebei Province(No.B2015202049);the National Natural Science Foundation of China(Nos.21004017 and 50573018)
Tandem catalytic systems, consisting of ethylene bis(indenyl) zirconium dichloride with two different cocatalysts, alkylaluminum(diethylaluminium chloride or trialkylaluminum) and methylaluminoxane, were employed ...
supported by the National Natural Science Foundation of China (Nos. 20734002, 51103163,51003106 and 51003105);Chinese Academy of Sciences (Directional key project on high performance polypropylene alloy resin development)
In this paper, we review our recent progress in the synthesis and application of styryl-capped polypropylene (PP-t- St), an excellent reactive polyolefin that is both convenient and efficient in synthesis and facile...
the Korea Ministry of Commerce,Industry,and Energy(Grant RTI04-01-04,Regional Technology Innovation Program).
Polymerization of isobutyl vinyl ether(IBVE)has been studied with mononuclear half-titanocene,CpTiCl_3[1]and dinuclear half-titanocenes,[(C_5H_4)_2(CH_2)_n][(TiCl_3)_2][2(n=3),3(n=6)],and[(C_5H_4)_2(CH_2)_n[(TiCl_2OR_...
National Basic Research Program of China(No.2005CB623804);the National Natural Science Foundation of China(No.20476090).
i-PP/m-EPR reactor alloy were prepared through ethylene/propylene slurry copolymerization catalyzed by metallocene(rac-Et(Ind)_2ZrCl_2)supported on porous iPP particles.Polar monomer(dihydromyrcene alcohol)treated wit...