Stereoselective Functionalization at C-2 and C-3 of the Gibberellin via an Intramolecular Free Radical Cyclization Approach  

作　　者：An Qi CHEN Christine L.WILLIS 

机构地区：[1]Department of Chemistry,Xiamen University,Xiamen,3610052School of Chemistry,University of Bristol,Bristol,UK BS81TS

出　　处：《Chinese Chemical Letters》2001年第5期397-398,共2页中国化学快报(英文版)

摘　　要：Stereoselective functionalization at C-2 and C-3 of the gibberellin skeleton was achieved via an intramolecular free radical cyclization approach using a tethered C-19 halomethyl ester as the radical precursor.Stereoselective functionalization at C-2 and C-3 of the gibberellin skeleton was achieved via an intramolecular free radical cyclization approach using a tethered C-19 halomethyl ester as the radical precursor.

关 键 词：GIBBERELLIN LACTONIZATION free radical cyclization. 

分 类 号：O621[理学—有机化学]