LACTONIZATION

作品数:20被引量:14H指数:2
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相关领域:理学更多>>
相关作者:王蓉更多>>
相关机构:陕西师范大学更多>>
相关期刊:《Science China Chemistry》《Natural Products and Bioprospecting》《Chemical Research in Chinese Universities》《International Journal of Organic Chemistry》更多>>
相关基金:国家自然科学基金福建省自然科学基金更多>>
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Highly enantioselective carbene-catalyzedδ-lactonization via radical relay cross-coupling
《Chinese Chemical Letters》2025年第1期253-257,共5页Yuhan Liu Jingyang Zhang Gongming Yang Jian Wang 
financial supports for this work are provided by the National Natural Science Foundation of China(Nos.21871160,21672121,22071130)。
An N-heterocyclic carbene(NHC)catalyzed enantioselective cyclisation and trifluoromethylation of olefins with cinnamaldehydes via radical relay cross-coupling in the presence of Togni reagent is reported andδ-lactone...
关键词:Carbene organocatalysis Radical relay cross-coupling TRIFLUOROMETHYLATION CYCLISATION δ-Lactone 
En Route to Diastereopure Polycyclic γ-Lactones by Iridium-Catalyzed Hydride Transfer
《Chinese Journal of Chemistry》2024年第23期3047-3055,共9页Yang Chen Jingyu Zhang Yecheng Wang Hongguang Du Jiaxi Xu Zhanhui Yang 
supported by the National Key Research and Development Program of China(No.2022YFF0709803);Natural Science Foundation of Beijing Municipality(No.2202041);the High Performance Computing Platform of Beijing University of Chemical Technology(BUCT).
The reductive lactonization strategy provides an efficient access to diastereoenriched polycyclicγ-lactones.However,it is still a formidable challenge to develop an efficient and versatile protocol with excellent lev...
关键词:Iridium catalysis Hydride transfer Reductive lactonization Diastereoselectivity control Polycyclic y-lactones Methodology and reactions Sterichindrance Reduction 
Lactonization of dyes promoted by a coordination cage facilitates cavity-induced chromism as ion mobile detector
《Science China Chemistry》2024年第5期1554-1560,共7页Liangliang Zhang Yu Liang Zhifeng Xiao Yuxuan Meng Jinyi Huang Xi Lin Ji Li Hong-Cai Zhou Yu Fang 
supported by the Fujian Province Natural Science Foundation (2023J01294);the Natural Science Basic Research Program of Shaanxi (2023-JC-YB-088);the National Natural Science Foundation of China (21501133, 22371067);the China Hunan Provincial Science&Technology Department (2020RC3020, 2021JJ20021,2023JJ40119)。
Dye molecules often change colors(so-called “chromism”) according to the environment variation. However, they are rarely induced by a catalytic amount of cavity. Through encapsulation in the cavity of a porous coord...
关键词:porous coordination cage Zwitterion intermediate CAVITY Rhodamine B chromism 
Difluoroalkylation/Lactonization of Alkenes with BrCF_(2)CO_(2)K via Photoredox Catalysis:Access toα,α-Difluoro-γ-lactones被引量:2
《Chinese Journal of Chemistry》2023年第21期2819-2824,共6页Min Zhang Qiang Li Jin-Hong Lin Ji-Chang Xiao 
We thank the National Key Research and Development Program of China(2021YFF0701700);the National Natural Science Foundation of China(21971252,21991122,22271181);the Science and Technology Commission of Shanghai Municipality(22ZR1423600)for financial support.
Due to its unique electronic properties,the difluoromethylene group(CF2)has served as a valuable unity in the design of biologically active molecules.Sinceγ-lactones display a broad range of biological properties,α,...
关键词:PHOTOREDOX Catalysis Fluorine LACTONES ALKENES 
Oxidative lactonization of C(sp^(3))–H bond in methyl aromatic alcohols enabled by proton-coupled electron transfer被引量:1
《Science China Chemistry》2022年第8期1526-1531,共6页Shanyi Chen Qihong Lai Chao Liu Hui Liu Mingqiang Huang Shunyou Cai 
supported by the National Natural Science Foundation of China(21502086);the Natural Science Foundation of Fujian Province(2019J01744);the Key Project of Foundation of Fujian Province(2020J02044);the Natural Science Foundation of Zhangzhou City(ZZ2021J13)。
Direct functionalization of inert C(sp^(3))–H bonds in pharmaceutically significant compounds is very important in modern synthetic organic chemistry.In this article,we disclose a practical and efficient method for t...
关键词:photoredox catalyst metal free singlet oxygen bromine radical dehydrogenated lactonization 
Preparation of a ε-caprolactonic diterpenoid derivate by unexpected oxidative cleavage/lactonization of 2-oxoaustroeupatol
《Natural Products and Bioprospecting》2022年第1期265-269,共5页Pablo A.Chacón-Morales Juan M.Amaro-Luis Luis Beltrán Rojas Fermín Rémi Jacquet Denis Deffieux Laurent Pouységu Stéphane Quideau 
supported by the National Fund of Science,Technology and Innovation (FONACIT) (Grant N°201300288)within the framework of the project PCP France-Venezuela;by the CDCHTA-ULA (Grant N°C-1935-15-08-ED).
From aerial parts of Austroeupatorium inulifolium was isolated the ent-nor-furano triol labdane austroeupatol 1.The compound 1 was treated with IBX showing an unexpected selectivity at the potentially oxidizable sites...
关键词:Oxidative cleavage Austroeupatol NaIO4 IBX LACTONIZATION NMR 
Synthesis of A-B-C-ring Tricyclic Core of iso-Merrilactone A
《Chemical Research in Chinese Universities》2019年第5期817-822,共6页TONG Jie LIU Chang WANG Bo 
Supported by the National Natural Science Foundation of China(No.21672203).
A desymmetrization approach for the synthesis of the A-B-C tricycle intermediate of iso-merrilactone A was described. The key steps of this synthesis to efficiently access the tetracyclic Illicium sesquiterpenes core ...
关键词:SESQUITERPENE Regio-isomer Cyclorearrangement LACTONIZATION 
Lactonization of C(sp2)-H Bonds in Enamides with CO2被引量:5
《Chinese Journal of Chemistry》2018年第5期430-436,共7页Zhen Zhang Chun-Jun Zhu Meng Miao Jie-Lian Han Tao Ju Lei Song Jian-Heng Ye Jing Li Da-Gang Yu 
Herein, we report a novel synthesis of 1,3-oxazin-6-ones from enamides with CO2 through C--H carboxylation and one-pot cyclization. This transition-metal-free and redox-neutral process features broad substrate scope, ...
关键词:carbon dioxide transition-metal-free LACTONIZATION 1 3-oxazin-6-ones 
Unexpected Grob-type fragmentation of vinylogous β-silyloxy-cyclobutanone into γ-lactone
《Chinese Chemical Letters》2017年第5期968-970,共3页Xiang Wu Wei-Dong Z.Li 
financial support from National Natural Science Foundation of China(NSFC,Nos.21302177,21672049 and 21672030)
An unusual formal oxy transposition of vinylogous β-silyloxy-cyclobutanone 1(a 1,5-difunctionalized substrate) under mild acidic conditions(aqueous HF in CH3CN at 0℃) to the decalinic y-lactone 2 was described.A...
关键词:Grob fragmentation Vinylogous β-silyloxy-cyclobutanone Decalinic γ-lactone Oxy transposition Intramolecular γ-lactonization 
Synthetic Studies of Naphtho[2,3-b]furan Moiety Present in Diverse Bioactive Natural Products
《International Journal of Organic Chemistry》2015年第2期63-74,共12页Bidyut Kumar Senapati Dipakranjan Mal 
The preparation of several functionalized furan derivatives and attempts to transform them into a derivative containing 6H-furo[3,4-b]furanone skeleton towards the construction of naphtho[2,3-b] furan are described. A...
关键词:6H-Furo[3 4-b]furanone Naphtho[2 3-b]furan INTRAMOLECULAR Pummerer Reaction Desulfanylation LACTONIZATION 
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