Financial support from National Natural Science Foundation of China(Nos.22201202,22171206 and 22371201);Natural Science Foundation of Zhejiang Province(No.LZ23B020001);Open Foundation of Hunan Provincial Key Laboratory of Controllable Preparation and Functional Application of Fine Polymers(No.E22307);Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University(No.2020ZD04);Open Research Fund of Key Laboratory of the Ministry of Education for Advanced Catalysis Materials and Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces,Zhejiang Normal University。
A photoredox-catalyzed synthesis ofα,α-difluoromethyl sulfones from sulfur dioxide with readily available gem–difluoroalkenes is reported.This protocol features mild reaction conditions,broad substrate scope and go...
supported by grants from the Provincial Natural Science Foundation of Hunan(No.2023JJ60335)。
The first example of Nd@C_(3)N_(4)-photoredox/chlorine dual catalyzed alkylation with unactivated alkanes as the alkyl sources has been developed,which allows for the synthesis of various 4-alkylated cyclic sulfonyl k...
supported by the Fundamental Research Funds for the University of South China(No.220XQD08).
The direct reductive coupling of carbonyl compounds with propargyl halides is a powerful and reliable tool in the synthesis ofα-allenols.However,stoichiometric metal reductants,harsh reaction conditions and a variety...
the National Natural Science Foundation of China(No.22271245)for the financial support;the Yantai“Double Hundred Plan”;the Talent Induction Program for Youth Innovation Teams in Colleges and Universities of Shan-dong Province。
A new 1,4-amidocyanation of 1,3-enynes with N-amidopyridin-1-ium salts and TMSCN using a copper and photoredox synergetic catalysis for producingα-amido allenyl nitriles is developed.Employing N-amidopyridin-1-ium sa...
supported by National Natural Science Foundation of China (NSFC);Youth program (Grant No: 22101173);Fundamental Research Funds for the Central Universities (23X010301599);“Thousand Talents Plan, Youth project”;startup funding from Shanghai Jiao Tong University (SJTU)。
Based on rational design, benzoyl cyanide, a well-known ionic acylating reagent, has been developed as a general radical acylating reagent for benzylic site-selective acylation reactions for the first time. Using visi...
the National Natural Science Foundation of China (22171099, and 92256301);the National Key R&D Program of China (2023YFA1507203 and 2022YFA1506100);the Open Research Fund of School of Chemistry and Chemical Engineering;the Fundamental Research Funds for the Central Universities of China (CCNU24JCPT016);Henan Normal University (2021YB02);the Double-Thousand Talents Plan of Jiangxi Province (jxsq2023102004)。
Radical-involved allylation reactions have emerged as a powerful platform for construction of carbon-carbon and carbonheteroatom bonds, facilitating the strategic incorporation of diverse allyl moieties. Nevertheless,...
A photoredox-catalyzed cascade carbon/carboxylation of activated alkenes with malonates acetals and CO_(2) has been achieved,leading to a range of functionalized 1,1,3-tricarboxylates in good efficiency under mild rea...
provided by the Tsinghua University Dushi Program,China,the National Natural Science Foundation of China(grant nos.22031006,22193011,22373056,and 22393891);the Haihe Laboratory of Sustainable Chemical Transformations,China,and the National Science&Technology Fundamental Resource Investigation Program of China(grant no.2023YFA1500008).
Enamine-derived radicals are crucial intermediates in singly occupied molecular orbital(SOMO)catalysis.However,observing them directly is elusive and remains a long-standing challenge.Here,an advanced time-resolved el...
financial support by the National National Natural Science Foundation of China(22271148,22071100).
Unsymmetrical diarylamines are crucial components in many pharmaceuticals and functional materials.In this study,we introduce an efficient Chan-Lam cross-coupling method that utilizes phenylboronic acids and aryl azid...
supported by the National Natural Science Foundation of China(Nos.22301256 and 22271244);the Hunan Provincial Natural Science Foundation of China(2023JJ40618);the Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University(2022c02);the Hunan Provincial Innovation Foundation for Postgraduate(CX20230644,XDCX2023Y162)
A general and broadly applicable copper and photoredox dual-catalyzed multicomponent 1,4-perfluoroalkylcyanation of 1,3-enynes has been developed.This protocol enjoys success with high regioselectivity,mild reaction c...