云南高校图书馆联盟文献共享服务平台- FLUOROALKYLATION

检索规则说明：AND代表“并且”；OR代表“或者”；NOT代表“不包含”；(注意必须大写,运算符两边需空一格)

检索范例：范例一： (K=图书馆学 OR K=情报学) AND A=范并思　　　　范例二：J=计算机应用与软件 AND (U=C++ OR U=Basic) NOT M=Visual

全部期刊核心期刊 EI来源期刊 SCI来源期刊 CA来源期刊 CSCD来源期刊 CSSCI来源期刊

Modular three-component radical fluoroalkyl-sulfuration of unactivated alkenes: 《Chinese Journal of Catalysis》2025年第2期249-258,共10页Gao-feng Yang Zhi Liu Kai Liu Xiaopeng Wu Chengjian Zhu Weipeng Li Jin Xie; 国家重点研发项目(2022YFA1503200,2021YFC2101901);国家自然科学基金(22122103,22101130,22001117,22271144);中央高校基本科研业务费(020514380304,020514380252,020514380272).; The accompanied forge of C(sp^(3))–S and C(sp^(3))–C(sp^(3))bonds across alkene frameworks serves as a potent strategy to construct biologically important compounds.Here,we report a metal-free,photochemically mediat...; 关键词：C(sp^(3))-S bond Unactivated alkenes Photoredox catalysis FLUOROALKYLATION Unsymmetrical thioethers

Transition-Metal-Mediated Fluoroalkylation of Carbon Electrophiles through Cross-Electrophile Couplings: 《Chinese Journal of Chemistry》2024年第24期3499-3517,共19页Yun-Cheng Luo Xingang Zhang; supported by the National Natural Science Foundation of China(21931013,21991122);the National Key R&D Program of China(2021YFF0701700);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0590000);the Science and Technology Commission of Shanghai Municipality(22JC1403500,21XD1404400).; Organofluorine compounds have attracted substantial interest in life and materials sciences due to the unique properties of fluorine atom(s)that often change the physicochemical and biological properties of organic mo...; 关键词：FLUOROALKYLATION Cross-electrophile coupling Dicarbofunctionalization Copper Nickel catalysis

Copper/Photoredox-Catalyzed Regioselective 1,4-Addition to 1,3-Enynes: A Convenient Access to Perfluoroalkylated Allenes: 《Chinese Journal of Chemistry》2024年第17期2023-2028,共6页Ya Chen Quanyuan Wang Keyi Peng Lilei Cheng Ziyi She Guo-Jun Deng; supported by the National Natural Science Foundation of China(Nos.22301256 and 22271244);the Hunan Provincial Natural Science Foundation of China(2023JJ40618);the Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University(2022c02);the Hunan Provincial Innovation Foundation for Postgraduate(CX20230644,XDCX2023Y162); A general and broadly applicable copper and photoredox dual-catalyzed multicomponent 1,4-perfluoroalkylcyanation of 1,3-enynes has been developed.This protocol enjoys success with high regioselectivity,mild reaction c...; 关键词：Fluorinated allenes 1 3-Enynes PHOTOREDOX FLUOROALKYLATION Multicomponent reactions Difunctionalization Radicals Regioselectivity

Recent progress in carbene-catalyzed fluoroalkylation: 《Science China Chemistry》2024年第8期2448-2460,共13页Bei Zhang Xuan Zhang Jian Wang; supported by the National Natural Science Foundation of China (21871160, 21672121, 22071130);the Bayer Investigator Fellow;the Fellowship of Tsinghua-Peking Center for Life Sciences (CLS)。; The fluoroalkyl fragment plays a vital role in various fields such as pharmaceuticals and materials science, and has a significant impact on human life not only on the present but also in the future. The insertion of ...; 关键词：N-heterocyclic carbene FLUOROALKYLATION radical catalysis

Pentacoordinate Phosphoranes as Versatile Reagents in Fluoroalkylation Reactions: 《CCS Chemistry》2024年第1期165-176,共12页Huanhuan Song Weihao Li Xiaoying Wang Kaiteng Wang Jingwen Li Shuai Liu Pin Gao Xin-Hua Duan Jinbo Hu Mingyou Hu; supported by National Natural Science Foundation of China(grant no.21901196);the Natural Science Basic Research Plan in Shaanxi Province of China(grant nos.2020JQ-016 and 2021GXLH-Z-096);the Fundamental Research Funds for the Central Universities(grant no.xhj032021007-01);Xi’an Jiaotong University(grant no.71211920000001).; A general method for the synthesis of bench-stable bis(difluoromethyl)pentacoordinate phosphoranes has been developed.The reaction is rapid,operationally simple,and easily scalable.The pentacoordinate phosphoranes can...; 关键词：pentacoordinate phosphorane difluoromethyl radical DIFLUOROCARBENE DIFLUOROMETHYLATION FLUOROALKYLATION

Selective Ni-catalyzed cross-electrophile coupling of alkynes,fluoroalkyl halides,and vinyl halides: 《Chinese Chemical Letters》2022年第8期4074-4078,共5页Yubei Dai Fang Wang Shengqing Zhu Lingling Chu; financial support provided by the National Natural Science Foundation of China(Nos.21991123,21971036,21901036);the Shanghai Rising-Star Program(No.20QA1400200)。; We report a Ni-catalyzed three-component cross-electrophile coupling of alkynes with alkenyl halides and fluoroalkyl halides to generate fluoroalkyl-incorporated 1,3-dienes.This mild and operationally simple protocol ...; 关键词：FLUOROALKYLATION Cross-electrophile coupling Nickel catalysis Difunctionalization ALKYNES

A Fruitful Decade of Organofluorine Chemistry: New Reagents and Reactions被引量：6: 《CCS Chemistry》2022年第8期2518-2549,共32页Feng-Ling Qing Xin-Yuan Liu Jun-An Ma Qilong Shen Qiuling Song Pingping Tang; support from the National Natural Science Foundation of China(grant nos.21991121,21931013,21925105,22025103,and 21961142015);the National Key Research and Development Program of China(grant no.2021YFF0701700).; The development of synthetic methods for the introduction of the fluorine atom and fluoroalklyl groups into organic molecules has gained increased attention.Synthetic organic chemists have recently jumped into the fie...; 关键词：FLUORINATION FLUOROALKYLATION REAGENT REACTION fluorine chemistry

MnBr_(2)catalyzed regiospecific oxidative Mizoroki-Heck type reaction: 《Chinese Chemical Letters》2022年第5期2391-2396,共6页Xiang Chen Zhihong Zhu Shanshan Liu Yi-Hung Chen Xiao Shen; the National Natural Science Foundation of China (No. 21901191);the Fundamental Research Funds for the Central Universities and Wuhan University for financial support; Herein, we report an unprecedented regiospecific oxidative Mizoroki-Heck type reaction for the synthesis of α-difluoromethyl homoallylic alcohols. The reaction shows broad substrate scopes and high functional group t...; 关键词：FLUOROALKYLATION Mizoroki-Heck Mn catalysis Radical 1 2-silyl transfer Homoallylic alcohols

Computational insights into the effects of reagent structure and bases on nucleophilic monofluoromethylation of aldehydes被引量：1: 《Chinese Chemical Letters》2022年第5期2387-2390,共4页Meng-Meng Zheng Hao-Dong Tan Yueqian Sang Xiao-Song Xue Jin-Pei Cheng; supported by the Natural Science Foundation of China(Nos.22122104,21933004 and 21702098).; Although fluorobis(phenylsulfonyl)methane(FBSM)and its cyclic analog 2-fluoro-1,3-benzodithiole-1,1,3,3-tetraoxide(FBDT)possess similar physicochemical properties,Shibata et al.found that FBSM failed to undergo nucleo...; 关键词：Nucleophilic monofluoromethylation Fluoroalkylation reagent DFT calculations Thermodynamic effect Lone pair repulsion

Nucleophilic Difluoro(phenylsulfonimidoyl)methylation of Unactivated Alkyl Bromides with PhSO(NTBS)CF_(2)H: Facile Entry into gem-Difluoroalkenes: 《Chinese Journal of Chemistry》2014年第8期703-708,共6页Xiao Shen Qinghe Liu Chuanfa Ni Jinbo Hu; Support of our work by the National Basic Research Program of China(Nos.2012CB215500 and 2012CB821600);the NNSFC(No.21372246);Shanghai QMX program(No.13QH1402400);the Chinese Academy of Sciences is gratefully acknowledged.; An efficient nucleophilic difluoro(phenylsulfonimidoyl)methylation of unactivated primary alkyl bromides with PhSO(NTBS)CF_(2)H has been developed.It is particularly remarkable that,when 1.5 equiv.of alkyl bromides ar...; 关键词：nucleophilic fluoroalkylation β-elimination difluoroalkene SULFOXIMINE

高级检索 检索式检索

时间限定

期刊范围

学科限定全选

高级检索 检索式检索

时间限定

期刊范围

学科限定全选

FLUOROALKYLATION

检索结果分析

下载全文

高级检索检索式检索

时间限定

期刊范围

学科限定全选

高级检索 检索式检索

时间限定

期刊范围

学科限定全选

FLUOROALKYLATION

检索结果分析

下载全文

用户登录

高级检索检索式检索