CARBOXYLATION

作品数:60被引量:95H指数:6
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相关领域:生物学农业科学更多>>
相关作者:张文珍陆嘉星王欢吴志娟张新胜更多>>
相关机构:大连理工大学华东师范大学安庆师范大学华东理工大学更多>>
相关期刊:《Journal of Animal Science and Biotechnology》《Science China(Life Sciences)》《Regenerative Biomaterials》《Acta Pharmacologica Sinica》更多>>
相关基金:国家自然科学基金中国博士后科学基金中央高校基本科研业务费专项资金霍英东教育基金更多>>
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Electro-reductive carboxylation of C–Cl bonds in unactivated alkyl chlorides and polyvinyl chloride with CO_(2)
《Chinese Chemical Letters》2024年第12期411-415,共5页Li Li Zhi-Xin Yan Chuan-Kun Ran Yi Liu Shuo Zhang Tian-Yu Gao Long-Fei Dai Li-Li Liao Jian-Heng Ye Da-Gang Yu 
provided by the National Natural Science Foundation of China(Nos.22225106,22201027);Fundamental Research Funds for the Central Universities。
The carboxylation of readily available organo halides with CO_(2)represents a practical strategy to afford valuable carboxylic acids.However,efficient carboxylation of inexpensive unactivated alkyl chlorides is still ...
关键词:Carbon dioxide CARBOXYLATION ELECTROCHEMISTRY Unactivated alkyl chlorides Polyvinyl chloride 
A N-Heterocyclic Olefin Decorated Organic-Inorganic Dual-Site Catalyst Toward Multiple Component CO_(2)Fixation
《Renewables》2024年第6期405-413,共9页Zhong-Gao Zhou Jia Zhang Qian Xie Jing Li Ping-Ping Xu Xue-Feng Zhang Zi-Yi Du Chun-Ting He Xiao-Ming Chen 
financially supported by the National Natural Science Foundation of China(grant nos.22161021,22261002,21890382,and 22375079);the Key Project of Jiangxi Provincial Department of Science and Technology(grant nos.S2023ZRZDL0164,20232ACB203016,and S2023ZRMSL0668);the Key Laboratory of Jiangxi University for Functional Materials Chemistry(grant no.FMC21702);the Education Department of Jiangxi Province(grant nos.GJJ201427 and SZUGSHX2022-1043);C.-T.H.acknowledges the support of Jiangxi Province(grant no.20224ACB214001).
Converting low-concentration carbon dioxide(CO_(2))into value-added chemicals meets the demand of carbonneutral technologies,yet efficient and stable catalysts for CO_(2)absorption and activation are urgently desired....
关键词:single-atom catalysts CO_(2)conversion carboxylation-cyclization-cross-coupling tri-component reactions heterogeneous catalysts 
Organo-electroreduction enables arylcarboxylation of styrenes
《Science China Chemistry》2024年第11期3825-3832,共8页Yanwei Wang Qian Wang Zile Zhu Weikang Qi Youai Qiu 
supported by the National Key R&D Program of China (2022YFA1503200);the National Natural Science Foundation of China (22371149, 22301144, 22188101);the Fundamental Research Funds for the Central Universities (63223015);the Frontiers Science Center for New Organic Matter, Nankai University (63181206);Nankai University;the Haihe Laboratory of Sustainable Chemical Transformations for financial support。
Electroreduction offers an alternative to generate high active intermediates from electrophiles(halides, alkenes, etc.) in organic synthesis. However, it still remains challenge to enable the transformations in contro...
关键词:CO_(2)utilization reductive organo-mediator CARBOXYLATION ELECTROREDUCTION aryl halides 
Electro-reductive carboxylation of acyclic C(sp^(3))–C(sp^(3))bonds in aromatic hydrocarbons with CO_(2)
《Science China Chemistry》2024年第10期3366-3372,共7页Chuan-Kun Ran Quan Qu Yang-Yi Tao Yi-Fei Chen Li-Li Liao Jian-Heng Ye Da-Gang Yu 
supported by the National Natural Science Foundation of China(22225106,22201027);the Fundamental Research Funds for the Central Universities。
Despite the recent advances in the selective functionalization of C–C bonds in specific substrates,cleavage and functionalization of C–C bonds in acyclic substrates,such as ethane derivatives,remains challenging.In ...
关键词:carbon dioxide electrochemistry C(sp^(3))–C(sp^(3))bonds cleavage reductive carboxylation 
Advances in the Synthesis of Carboxylic Acid by Photochemical Conversion of CO_(2)
《有机化学》2024年第10期2997-3042,共46页Yuan Panfeng Zhu Canming Meng Qingyuan 
国家自然科学基金(No.22271293);中国科学院稳定支持基础研究领域青年团队计划(No.YSBR-050)资助项目.
The pursuit of cleanliness,energy efficiency,and resource preservation through photochemical reactions has led to the emergence of novel pathways and methodologies in synthetic chemistry,rendering it one of the most d...
关键词:carbon dioxide PHOTOCATALYSIS CARBOXYLATION 
Visible-Light Photoredox-Catalyzed Carbon/Carboxylation of Alkenes with Malonates and CO_(2)
《有机化学》2024年第10期3159-3168,共10页Zhang Aolong Yang Han Cheng Peidong Yao Yang Sun Song 
国家自然科学基金(No.21602019);环保功能吸附材料制备技术国地联合工程实验室开放基金(No.SDGC2125)资助项目.
A photoredox-catalyzed cascade carbon/carboxylation of activated alkenes with malonates acetals and CO_(2) has been achieved,leading to a range of functionalized 1,1,3-tricarboxylates in good efficiency under mild rea...
关键词:carbon dioxide CARBOXYLATION alkene difunctionalization visible-light catalyzed 
Advances in Dearomative Carboxylation of Aromatic Compounds with Carbon Dioxide
《有机化学》2024年第10期3136-3146,共11页Li Jiayuan Yi Yaping Xi Chanjuan 
国家自然科学基金(Nos.22071134,22371159)资助项目。
Dearomative carboxylation of aromatic compounds with carbon dioxide(CO_(2))could be utilized for the synthesis of cyclic carboxylative frameworks.The dearomative carboxylation exhibits advantages such as reconstitutio...
关键词:dearomative carboxylation aromatic compound carbon dioxide metal catalysis PHOTOCATALYSIS electropromoted chemistry 
Recent Advances in Photochemical/Electrochemical Carboxylation of Olefins with CO_(2)
《Chinese Journal of Chemistry》2024年第18期2249-2266,共18页Qian Wang Yanwei Wang Min Liu Ganghui Chu Youai Qiu 
Financial support from National Key R&D Program of China(2022YFA1503200);National Natural Science Foundation of China(Grant Nos.22371149,22188101,22301144);the Fundamental Research Funds for the Central Universities(No.63223015);Frontiers Science Center for New Organic Matter,Nankai University(Grant No.63181206)and Nankai University is gratefully acknowledged.
CO_(2) is an abundant,nontoxic,and renewable C1 feedstock in synthetic chemistry.Direct carboxylation of readily available olefins incorporating CO_(2) is regarded as a promising strategy to access high value-added ca...
关键词:CO_(2) CARBOXYLATION OLEFINS Photocatalysis ELECTROCATALYSIS RADICAL Reduction Difunctionalization 
Valorization of carbon dioxide with alcohols被引量:1
《Chinese Chemical Letters》2024年第7期54-58,共5页Daheng Wen Weiwei Fang Yongmei Liu Tao Tu 
Financial support from the National Natural Science Foundation of China(No.22271060);the Department of Chemistry at Fudan University;Nanjing Forestry University。
Utilizing CO_(2)for the production of bulky and valuable chemicals presents an attractive solution to address environmental and fossil energy crises.Among the various approaches,direct carboxylation of alcohols with C...
关键词:CARBOXYLATION Carbon dioxide ALCOHOL Carboxylic acid Transition metal catalysis 
Visible-light photoredox-catalyzed carboxylation of aryl epoxides with CO_(2)
《Chinese Chemical Letters》2024年第7期281-284,共4页Tian-Yu Gao Xiao-Yan Mo Shu-Rong Zhang Yuan-Xu Jiang Shu-Ping Luo Jian-Heng Ye Da-Gang Yu 
the National Natural Science Foundation of China (Nos. 22225106, 22301193);Fundamental Research Funds from Sichuan University (No. 2020SCUNL102);the Fundamental Research Funds for the Central Universities。
Herein, we report the first visible-light photoredox-catalyzed carboxylation of aryl epoxides with CO_(2)to synthesize hydroxy acid derivatives. A variety of valuable β-, γ-, δ-, ε–hydroxy acid derivatives are ob...
关键词:Carbon dioxide EPOXIDES Visible-light photoredox catalysis Hydroxy acid Sequential single electron transfer 
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