provided by the National Natural Science Foundation of China(Nos.22225106,22201027);Fundamental Research Funds for the Central Universities。
The carboxylation of readily available organo halides with CO_(2)represents a practical strategy to afford valuable carboxylic acids.However,efficient carboxylation of inexpensive unactivated alkyl chlorides is still ...
financially supported by the National Natural Science Foundation of China(grant nos.22161021,22261002,21890382,and 22375079);the Key Project of Jiangxi Provincial Department of Science and Technology(grant nos.S2023ZRZDL0164,20232ACB203016,and S2023ZRMSL0668);the Key Laboratory of Jiangxi University for Functional Materials Chemistry(grant no.FMC21702);the Education Department of Jiangxi Province(grant nos.GJJ201427 and SZUGSHX2022-1043);C.-T.H.acknowledges the support of Jiangxi Province(grant no.20224ACB214001).
Converting low-concentration carbon dioxide(CO_(2))into value-added chemicals meets the demand of carbonneutral technologies,yet efficient and stable catalysts for CO_(2)absorption and activation are urgently desired....
supported by the National Key R&D Program of China (2022YFA1503200);the National Natural Science Foundation of China (22371149, 22301144, 22188101);the Fundamental Research Funds for the Central Universities (63223015);the Frontiers Science Center for New Organic Matter, Nankai University (63181206);Nankai University;the Haihe Laboratory of Sustainable Chemical Transformations for financial support。
Electroreduction offers an alternative to generate high active intermediates from electrophiles(halides, alkenes, etc.) in organic synthesis. However, it still remains challenge to enable the transformations in contro...
supported by the National Natural Science Foundation of China(22225106,22201027);the Fundamental Research Funds for the Central Universities。
Despite the recent advances in the selective functionalization of C–C bonds in specific substrates,cleavage and functionalization of C–C bonds in acyclic substrates,such as ethane derivatives,remains challenging.In ...
The pursuit of cleanliness,energy efficiency,and resource preservation through photochemical reactions has led to the emergence of novel pathways and methodologies in synthetic chemistry,rendering it one of the most d...
A photoredox-catalyzed cascade carbon/carboxylation of activated alkenes with malonates acetals and CO_(2) has been achieved,leading to a range of functionalized 1,1,3-tricarboxylates in good efficiency under mild rea...
Dearomative carboxylation of aromatic compounds with carbon dioxide(CO_(2))could be utilized for the synthesis of cyclic carboxylative frameworks.The dearomative carboxylation exhibits advantages such as reconstitutio...
Financial support from National Key R&D Program of China(2022YFA1503200);National Natural Science Foundation of China(Grant Nos.22371149,22188101,22301144);the Fundamental Research Funds for the Central Universities(No.63223015);Frontiers Science Center for New Organic Matter,Nankai University(Grant No.63181206)and Nankai University is gratefully acknowledged.
CO_(2) is an abundant,nontoxic,and renewable C1 feedstock in synthetic chemistry.Direct carboxylation of readily available olefins incorporating CO_(2) is regarded as a promising strategy to access high value-added ca...
Financial support from the National Natural Science Foundation of China(No.22271060);the Department of Chemistry at Fudan University;Nanjing Forestry University。
Utilizing CO_(2)for the production of bulky and valuable chemicals presents an attractive solution to address environmental and fossil energy crises.Among the various approaches,direct carboxylation of alcohols with C...
the National Natural Science Foundation of China (Nos. 22225106, 22301193);Fundamental Research Funds from Sichuan University (No. 2020SCUNL102);the Fundamental Research Funds for the Central Universities。
Herein, we report the first visible-light photoredox-catalyzed carboxylation of aryl epoxides with CO_(2)to synthesize hydroxy acid derivatives. A variety of valuable β-, γ-, δ-, ε–hydroxy acid derivatives are ob...