Valorization of carbon dioxide with alcohols  

作　　者：Daheng Wen Weiwei Fang Yongmei Liu Tao Tu 

机构地区：[1]Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials,Department of Chemistry,Fudan University,Shanghai 200438,China [2]Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources,International Innovation Center for Forest Chemicals and Materials,College of Chemical Engineering,Nanjing Forestry University,Nanjing 210037,China [3]State Key Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China

出　　处：《Chinese Chemical Letters》2024年第7期54-58,共5页中国化学快报（英文版）

基　　金：Financial support from the National Natural Science Foundation of China(No.22271060);the Department of Chemistry at Fudan University;Nanjing Forestry University。

摘　　要：Utilizing CO_(2)for the production of bulky and valuable chemicals presents an attractive solution to address environmental and fossil energy crises.Among the various approaches,direct carboxylation of alcohols with CO_(2)stands out as an eco-friendly process capable of efficiently producing carboxylic acids in a sustainable manner.However,the high dissociation energy of the C–O bond poses a significant challenge in this process.Over the past few decades,several strategies have been developed to activate alcohols and establish efficient catalytic systems for carboxylation with CO_(2).Nevertheless,the sporadic nature of reported approaches makes it difficult to determine the most effective one.This perspective aims to provide an overview of the current state-of-the-art catalytic protocols for carboxylating alcohols with CO_(2),encompassing esterification,halogenation,and photocatalysis,while considering their respective advantages and limitations.We aim to discern the most promising avenues for future development in this field.The insights presented in this perspective will contribute to the advancement of efficient and sustainable carboxylation methods using CO_(2),leading to the production of valuable chemicals in future.

关 键 词：CARBOXYLATION Carbon dioxide ALCOHOL Carboxylic acid Transition metal catalysis 

分 类 号：X701[环境科学与工程—环境工程] TQ214[化学工程—有机化工]